Solar heating of the oceans-diurnal, seasonal and meridional variation

Solar heating is an important factor in modelling the upper boundary layer of the ocean. It influences not only the temperature, but also the depth of the mixed layer and must be taken into account in circulation dynamics. The study reported in this paper was designed to reveal the principal features of the global climatology of solar heating in the ocean, with such applications in mind. The meridional, seasonal and diurnal variations of the vertical distribution of solar heating inside the ocean, expressed in terms of I(z), the rate of heat accumulation below depth z, and †(z) = (1/c). dzI(z), the rate of temperature rise, are calculated for given values of cloud cover and seawater turbidity (expressed in terms of Jerlov's water types) using a model that incorporates a new parametrization of I(z)/I(0), which is shown to be more accurate than previous versions. At present there exist no reliable global climatologies of cloud cover and seawater turbidity, so the values of the corresponding parameters are held constant in each computation, which is then repeated using parameter sets covering the full ranges from clear to overcast sky, clear to turbid ocean water. It is found that uncertainty in cloud cover is more important in the mixed layer, and uncertainty in seawater turbidity is more important below. The results presented in this paper are mainly concerned with solar heating below the mixed layer. It is calculated that the annual temperature rise can exceed 1 K and the annual heat accumulation can exceed 100 MJ/m2 below the mixed layer in the tropics. At higher latitudes solar heating produces similar heating rates in summer, but the stored heat is extracted locally in winter when the mixed layer depth exceeds the maximum depth of solar heating, defined here by a daily temperature rise of 1 mK or a heat flux of 86.4 KJ/m2d (=1 W/m2). The sensitivity of the seasonal and meridional variations of the maximum depth of solar heating to cloud cover and seawater turbidity is investigated. The actual change of temperature due to solar heating in the seasonal thermocline at Ocean Weather Station ‘C’ is calculated using Bunker's monthly mean cloud cover and Jerlov's seawater turbidity. Extension of such calculations to the whole of the World Ocean must await the publication of global climatologies of cloud cover and seawater turbidity, which are expected to be derived from satellite observations during the next decade. A solar heating climatology is a prerequisite for computation of the thermal response of the ocean to CO2 pollution of the atmosphere. The implications of the results obtained from the present study are discussed. An early rise in tropical sea surface temperature seems likely, but exact prediction will be hindered by uncertainty in the turbidity of the tropical ocean

Patterns and Drivers of UV Absorbing Chromophoric Dissolved Organic Matter in the Euphotic Layer of the Open Ocean

The global distribution of chromophoric dissolved organic matter (CDOM) in the euphotic layer of the Atlantic, Indian, and Pacific oceans (between 35 N and 40 S) was analyzed by absorption spectroscopy during the Malaspina 2010 circumnavigation. Absorption coefficients at 254 nm (a254) and 325 nm (a325), indices (a254/a365) and spectral slopes (between 275 and 295 nm, S275--295) were calculated from the dissolved fraction of the UV absorption spectra to describe the amount and quality of CDOM. Generalized Additive Models (GAMs) were applied to evaluate the relevance of physical and biogeochemical drivers for the variability of CDOM. Besides the low CDOM values, a first division of our data following the Longhurst’s biogeographic classification showed significant differences in CDOM levels among provinces. The lowest values of a254 and a325 were found in the oligotrophic gyres, particularly in the Indian Ocean, and the highest in the upwelling areas, particularly in the Equatorial Pacific. Opposite distributions were obtained for S275--295 and a254/a365, indicative of higher photobleaching in the gyres. The GAM analysis also shows that a254/a365 and S275--295 exhibited inverse relationships with solar radiation, indicating that the biological production of CDOM counteracts photodegradation as solar radiation increases. In summary, whereas photobleaching dictates the vertical distribution of CDOM, Chl a explains the CDOM differences among the photic layer of the tropical and subtropical ocean provinces visited during the circumnavigation.This study was funded by the Ingenio-Consolider project Malaspina 2010 Circumnavigation Expedition (MICINN CSD2008-00077). FI and JO were supported by a fellowship from the “Junta para la Ampliación de Estudios” (JAE-preDOC and JAE-postDOC programs 2011, respectively) from the CSIC