59 research outputs found

    Magnetic Field Dependent Behavior of the CDW ground state in Per2M(mnt)2 (M = Au, Pt)

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    The Per2M(mnt)2 class of organic conductors exhibit a charge density wave (CDW) ground state below about 12 K, which may be suppressed in magnetic fields of order 20 to 30 T. However, for both cases of counter ion M(mnt)2 species studied (M = Au (zero spin) and M = Pt (spin 1/2)), new high field ground states evolve for further increases in magnetic field. We report recent investigations where thermopower, Hall effect, high pressure and additional transport measurements have been carried out to explore these new high field phases.Comment: 6 pages, 10 figures, 27 reference

    Magnetic aerogels from FePt and CoPt3 directly from organic solution

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    Here the synthesis of magnetic aerogels from iron platinum and cobalt platinum nanoparticles is presented. The use of hydrazine monohydrate as destabilizing agent triggers the gelation directly from organic solution, and therefore a phase transfer to aqueous media prior to the gelation is not necessary. The aerogels were characterized through Transmission Electron Microscopy, Scanning Electron Microscopy, Powder X-Ray Diffraction Analysis and Argon Physisorption measurements to prove the formation of a porous network and define their compositions. Additionally, magnetization measurements in terms of hysteresis cycles at 5 K and 300 K (M-H-curves) as well as zero field cooled-field cooled measurements (ZFC-FC measurements) of the dried colloids and the respective xero- and aerogels were performed, in order to analyze the influence of the gelation process and the network structure on the magnetic properties

    Fredholm determinants and the statistics of charge transport

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    Using operator algebraic methods we show that the moment generating function of charge transport in a system with infinitely many non-interacting Fermions is given by a determinant of a certain operator in the one-particle Hilbert space. The formula is equivalent to a formula of Levitov and Lesovik in the finite dimensional case and may be viewed as its regularized form in general. Our result embodies two tenets often realized in mesoscopic physics, namely, that the transport properties are essentially independent of the length of the leads and of the depth of the Fermi sea.Comment: 30 pages, 2 figures, reference added, credit amende

    Geographical and temporal distribution of SARS-CoV-2 clades in the WHO European Region, January to June 2020

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    We show the distribution of SARS-CoV-2 genetic clades over time and between countries and outline potential genomic surveillance objectives. We applied three available genomic nomenclature systems for SARS-CoV-2 to all sequence data from the WHO European Region available during the COVID-19 pandemic until 10 July 2020. We highlight the importance of real-time sequencing and data dissemination in a pandemic situation. We provide a comparison of the nomenclatures and lay a foundation for future European genomic surveillance of SARS-CoV-2.Peer reviewe

    From chemical documentation to chemoinformatics: fifty years of chemical information science

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    This paper summarises the historical development of the discipline that is now called ‘chemoinformatics’. It shows how this has evolved, principally as a result of technological developments in chemistry and biology during the past decade, from long-established techniques for the modelling and searching of chemical molecules. A total of 30 papers, the earliest dating back to 1957, are briefly summarised to highlight some of the key publications and to show the development of the discipline

    Infrared investigations of the one-dimensional organic conductors (perylene) 2 M (mnt) 2, M=Au, Pt

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    The optical properties of the one-dimensional organic conductor (perylene)2Pt(mnt)2 and its Au analogue have been investigated at ambient and low temperatures. The spectra along the stacks of the molecules show a simple Drude behavior with no detectable influence of electron-electron interactions. Basing on the spectra for different polarizations an assignment of the vibrational modes is made. Perpendicular to the stacks, a wide band observed in the mid-infrared range evidences a charge transfer between perylene and anion stacks. The electronic properties are discussed in comparison with other quasi-one-dimensional synthetic metals
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