Petrological and chronological considerations on the hercynian granitic rocks from Galicia (NW Spain)

[Resumen] Se realiza un estudio sobre más de 600 análisis químicos correspondientes a los diversos grupos de granitoides hercínicos de Galicia, y se establecen valores medios representativos para la composición química mayoritaria de estos grupos. La comparación con las medias previamente establecidas para el N. O. de Galicia, permite observar un desplazamiento hacia términos composicionales más ácidospara el conjunto de los granitoides sincinemáticos más profundos, que resulta notablemente más acentuado en el grupo de los granitoides sincinemáticos predominantemente biotíticos. Para los granitoides postcinemáticos, las desviaciones observadas son en cambio poco significativas. El examen de los datos normativos medios, pone en evidencia un carácter peralumínico generalizado para todo el conjunto, apreciándose no obstante un drástico descenso en el contenido en corindón para los granitoides postcinemáticos, que marca una distribución bimodal para este componente normativo. La clasificación petrológica con base en la mineralogía normativa pone de manifiesto un espectro composicional que fluctúa esencialmente entre granitos y monzogranitos, con muy escasa representación de los términos granodior1ticos. La variabilidad observada para los elementos mayores más signiflcativos presenta pautas poco dispersivas. Los espectros de tierras raras tienen una configuración muy similar para los granitoides precoces predominantemente biotíticos, los granitos de dos micas sincinemáticos y los granitoides inhomogéneos, con anomalías negativas de Eu poco acentuadas. Por el contrario, los granitoides tardicinemáticos someros y los granitoides post-cinemáticos, presentan también espectros bastante similares entre sí, con anomalís negativas de Eu que pueden ser considerables. Las dataciones cronológicas efectuadas por el método de Rb-Sr en roca total en algunos de los plutones post-cinemáticos se encuentran en un intervalo aproximado de 275-287 m. a., mientras que la mayoría de las dataciones sobre unidades sincinemáticas de dos micas y predominantemente biotíticas fluctúan entre 295 y 323 m. a., aunque se encuentran algunos datos fuera de este entorno, que precisan futuras verificaciones..[Abstract] A survey over more than 600 chemical analysis of Hercynian granitic rocks from Galicia is presented, and a new set of representative mean compositional values of the main groups is calculated. In general, these new mean values are richer in Si02 than the previously available ones. This difference is more conspicous in the biotite rich synkinematic group, and is minium in the postkynematic granitoids. The average normative compostion, shows a systematic peraluminous character for aH the granitoids. However, the group of postkynematic granitoids, are poorer in normative corundum than the other groups, which results in a bimodal distribution of this normative component. The normative petrological c1assification shows a compositional spectrúm ranging mainly from granites to monzogranites. The Granodioritic rocks are very scarce. The variation trends for the main mayor elements display patterns with little dispersion. The REE spectra for the biotite rich synkinematic granites, two mica synkinematic granites and inhomogenous granites are very similar, and show negligible Eu anomalies. By contrast, the shaHow level intrusion late-kynematic and postkynematic granites, display conspicous Eu anomalies and have similar spectra patterns, but different from the previously referred ones. Whole-rock-Rb-Sr ages for the postkynematic plutons range from 287 to 275 M. y. The majority of the data the synkinematic units range from 323 to 295 M. y. However, sorne chronological data faH out of these intervals, showing the need of further studies

Petrological and geochronological study of the postkinematic pluton of Neira (Lugo, Spain)

[Resumen] El plutón granítico de Neira intruye discordantemente en metasedimentos precámbricos y cámbricos y en granitoides sincinemáticos de dos micas, con posterioridad al desarrollo de las fases deformativas hercínicas principales. En este macizo plutónico se distinguen dos unidades intrusivas principales y el espectro litológico fundamental fluctua entre granodioritas biotíticas y leucogranitos moscovíticos-biotíticos, con predominio de las variedades graníticas (adamellíticas). Estos términos petrol6gicos están relacionados entre sí a través de un proceso evolutivo controlado fundamentalmente por cristalización fraccionada, desempeñando un importante papel los minerales accesorios. La datación de esta unidad plutónica por el procedimiento Rb-Sr en roca total, proporciona una edad de 287 ± 5 Ma, con una relaci6n inicial 87 Sr /86 Sr de 0.7074 ± 0.0004, que corresponde a un episodio intrusivo Estefaniense[Abstract] Neira granitic pluton intrudes in cambrian and precambrian metasediments and in synkinematic two mica granites after the development of the two main hercynian tectonic phases. Two intrusive units are distinguished in this pluton and its petrological composition ranges from biotitic granodiorites to two mica leucogranites, predominating biotitic adamellites. This suite of rocks is related by an evolution process mainly ruled by crystal fractionation. The accesory minerals play an important role in this process. Rb-Sr dating of this plutonic unit gives and age of 287 ± 5 M y and an initial 87 Sr/86 Sr = 0.7074 ± 0.0004

Four-dimensional distribution of the 2010 Eyjafjallajökull volcanic cloud over Europe observed by EARLINET

© Author(s) 2013. This work is distributed under the Creative Commons Attribution 3.0 License.The eruption of the Icelandic volcano Eyjafjallaj ökull in April-May 2010 represents a "natural experiment" to study the impact of volcanic emissions on a continental scale. For the first time, quantitative data about the presence, altitude, and layering of the volcanic cloud, in conjunction with optical information, are available for most parts of Europe derived from the observations by the European Aerosol Research Lidar NETwork (EARLINET). Based on multi-wavelength Raman lidar systems, EARLINET is the only instrument worldwide that is able to provide dense time series of high-quality optical data to be used for aerosol typing and for the retrieval of particle microphysical properties as a function of altitude. In this work we show the four-dimensional (4-D) distribution of the Eyjafjallajökull volcanic cloud in the troposphere over Europe as observed by EARLINET during the entire volcanic event (15 April-26 May 2010). All optical properties directly measured (backscatter, extinction, and particle linear depolarization ratio) are stored in the EARLINET database available at www.earlinet.org. A specific relational database providing the volcanic mask over Europe, realized ad hoc for this specific event, has been developed and is available on request at www.earlinet.org. During the first days after the eruption, volcanic particles were detected over Central Europe within a wide range of altitudes, from the upper troposphere down to the local planetary boundary layer (PBL). After 19 April 2010, volcanic particles were detected over southern and south-eastern Europe. During the first half of May (5-15 May), material emitted by the Eyjafjallajökull volcano was detected over Spain and Portugal and then over the Mediterranean and the Balkans. The last observations of the event were recorded until 25 May in Central Europe and in the Eastern Mediterranean area. The 4-D distribution of volcanic aerosol layering and optical properties on European scale reported here provides an unprecedented data set for evaluating satellite data and aerosol dispersion models for this kind of volcanic events.Peer reviewe

2014 iAREA campaign on aerosol in Spitsbergen – Part 2: Optical properties from Raman-lidar and in-situ observations at Ny-Ålesund

In this work multi wavelength Raman lidar data from Ny-Ålesund, Spitsbergen have been analysed for the spring 2014 Arctic haze season, as part of the iAREA campaign. Typical values and probability distributions for aerosol backscatter, extinction and depolarisation, the lidar ratio and the color ratio for 4 different altitude intervals within the troposphere are given. These quantities and their dependencies are analysed and the frequency of altitude-dependent observed aerosol events are given. A comparison with ground-based size distribution and chemical composition is performed. Hence the aim of this paper is to provide typical and statistically meaningful properties of Arctic aerosol, which may be used in climate models or to constrain the radiative forcing. We have found that the 2014 season was only moderately polluted with Arctic haze and that sea salt and sulphate were the most dominant aerosol species. Moreover the drying of an aerosol layer after cloud disintegration has been observed. Hardly any clear temporal evolution over the 4 week data set on Arctic haze is obvious with the exception of the extinction coefficient and the lidar ratio, which significantly decreased below 2 km altitude by end April. In altitudes between 2 and 5 km the haze season lasted longer and the aerosol properties were generally more homogeneous than closer to the surface. Above 5 km only few particles were found. The variability of the lidar ratio is discussed. It was found that knowledge of the aerosol’s size and shape does not determine the lidar ratio. Contrary to shape and lidar ratio, there is a clear correlation between size and backscatter: larger particles show a higher backscatter coefficient

Dosage effect on uropathogenic Escherichia coli anti-adhesion activity in urine following consumption of cranberry powder standardized for proanthocyanidin content: a multicentric randomized double blind study

International audienc

EARLINET instrument intercomparison campaigns: Overview on strategy and results

This paper introduces the recent European Aerosol Research Lidar Network (EARLINET) quality-assurance efforts at instrument level. Within two dedicated campaigns and five single-site intercomparison activities, 21 EARLINET systems from 18 EARLINET stations were intercompared between 2009 and 2013. A comprehensive strategy for campaign setup and data evaluation has been established. Eleven systems from nine EARLINET stations participated in the EARLINET Lidar Intercomparison 2009 (EARLI09). In this campaign, three reference systems were qualified which served as traveling standards thereafter. EARLINET systems from nine other stations have been compared against these reference systems since 2009. We present and discuss comparisons at signal and at product level from all campaigns for more than 100 individual measurement channels at the wavelengths of 355, 387, 532, and 607 nm. It is shown that in most cases, a very good agreement of the compared systems with the respective reference is obtained. Mean signal deviations in predefined height ranges are typically below ±2 %. Particle backscatter and extinction coefficients agree within ±2  ×  10−4 km−1 sr−1 and ± 0.01 km−1, respectively, in most cases. For systems or channels that showed larger discrepancies, an in-depth analysis of deficiencies was performed and technical solutions and upgrades were proposed and realized. The intercomparisons have reinforced confidence in the EARLINET data quality and allowed us to draw conclusions on necessary system improvements for some instruments and to identify major challenges that need to be tackled in the future

Tropospheric and stratospheric smoke over Europe as observed within EARLINET/ACTRIS in summer 2017

For several weeks in summer 2017, strong smoke layers were observed over Europe at numerous EARLINET stations. EARLINET is the European research lidar network and part of ACTRIS and comprises more than 30 ground-based lidars. The smoke layers were observed in the troposphere as well as in the stratosphere up to 25 km from Northern Scandinavia over whole western and central Europe to the Mediterranean regions. Backward trajectory analysis among other tools revealed that these smoke layers originated from strong wild fires in western Canada in combination with pyrocumulus convection. An extraordinary fire event in the mid of August caused intense smoke layers that were observed across Europe for several weeks starting on 18 August 2017. Maximum aerosol optical depths up to 1.0 at 532 nm were observed at Leipzig, Germany, on 22 August 2017 during the peak of this event. The stratospheric smoke layers reached extinction coefficient values of more than 600 Mm−1 at 532 nm, a factor of 10 higher than observed for volcanic ash after the Pinatubo eruption in the 1990s. First analyses of the intensive optical properties revealed low particle depolarization values at 532 nm for the tropospheric smoke (spherical particles) and rather high values (up to 20%) in the stratosphere. However, a strong wavelength dependence of the depolarization ratio was measured for the stratospheric smoke. This indicates irregularly shaped stratospheric smoke particles in the size range of the accumulation mode. This unique depolarization feature makes it possible to distinguish clearly smoke aerosol from cirrus clouds or other aerosol types by polarization lidar measurements. Particle extinction-to-backscatter ratios were rather low in the order of 40 to 50 sr at 355 nm, while values between 70-90 sr were measured at higher wavelengths. In the western and central Mediterranean, stratospheric smoke layers were most prominent in the end of August at heights between 16 and 20 km. In contrast, stratospheric smoke started to occur in the eastern Mediterranean (Cyprus and Israel) in the beginning of September between 18 and 23 km. Stratospheric smoke was still visible in the beginning of October at certain locations (e.g. Evora, Portugal), while tropospheric smoke was mainly observed until the end of August within Europe. An overview of the smoke layers measured at several EARLINET sites will be given. The temporal development of these layers as well as their geometrical and optical properties will be presented

EARLINET instrument intercomparison campaigns: overview on strategy and results

This paper introduces the recent European Aerosol Research Lidar Network (EARLINET) quality-assurance efforts at instrument level. Within two dedicated campaigns and five single-site intercomparison activities, 21 EARLINET systems from 18 EARLINET stations were intercompared between 2009 and 2013. A comprehensive strategy for campaign setup and data evaluation has been established. Eleven systems from nine EARLINET stations participated in the EARLINET Lidar Intercomparison 2009 (EARLI09). In this campaign, three reference systems were qualified which served as traveling standards thereafter. EARLINET systems from nine other stations have been compared against these reference systems since 2009. We present and discuss comparisons at signal and at product level from all campaigns for more than 100 individual measurement channels at the wavelengths of 355, 387, 532, and 607¿nm. It is shown that in most cases, a very good agreement of the compared systems with the respective reference is obtained. Mean signal deviations in predefined height ranges are typically below ±2¿%. Particle backscatter and extinction coefficients agree within ±2¿¿×¿¿10-4¿km-1¿sr-1 and ±¿0.01¿km-1, respectively, in most cases. For systems or channels that showed larger discrepancies, an in-depth analysis of deficiencies was performed and technical solutions and upgrades were proposed and realized. The intercomparisons have reinforced confidence in the EARLINET data quality and allowed us to draw conclusions on necessary system improvements for some instruments and to identify major challenges that need to be tackled in the future.Peer ReviewedPostprint (published version