Graphite-Conjugated Pyrazines as Molecularly Tunable Heterogeneous Electrocatalysts

Condensation of ortho-phenylenediamine derivatives with ortho-quinone moieties at edge planes of graphitic carbon generates graphite-conjugated pyrazines (GCPs) that are active for oxygen reduction electrocatalysis in alkaline aqueous electrolyte. Catalytic rates of oxygen reduction are positively correlated with the electrophilicity of the active site pyrazine unit and can be tuned by over 70-fold by appending electron-withdrawing substituents to the phenylenediamine precursors. Discrete molecular analogs containing pyrazine moieties display no activity above background under identical conditions. This simple bottom up method for constructing molecularly well-defined active sites on ubiquitous graphitic solids enables the rational design of tunable heterogeneous catalysts.Japan Society for the Promotion of Science (Postdoctoral Fellowship)United States. Dept. of Energy. Office of Basic Energy Sciences (Award number DE-SC0014176)Massachusetts Institute of Technology. Department of Chemistry (Junior Faculty Funds

Detecting and mapping the ‘ephemeral’: magnetometric survey of a Pastoral Neolithic settlement at Luxmanda, Tanzania

Common assumptions about the ephemeral archaeological signature of pastoralist settlements have limited the application of geophysical techniques in the investigation of past herding societies. Here, the authors present a geophysical survey of Luxmanda, Tanzania, the largest-known settlement documented for the Pastoral Neolithic era in eastern Africa (c. 5000–1200 BP). The results demonstrate the value and potential of fluxgate gradiometry for the identification of magnetic anomalies relating to archaeological features, at a category of site where evidence for habitation was long thought to be undetectable. The study provides comparative data to enable archaeologists to identify loci for future investigations of mobile populations in eastern Africa and elsewhere

Pastoral Neolithic Settlement at Luxmanda, Tanzania

The later Holocene spread of pastoralism throughout eastern Africa profoundly changed socio-economic and natural landscapes. During the Pastoral Neolithic (ca. 5000–1200 B.P.), herders spread through southern Kenya and northern Tanzania—areas previously occupied only by hunter-gatherers—eventually developing the specialized forms of pastoralism that remain vital in this region today. Research on ancient pastoralism has been primarily restricted to rockshelters and special purpose sites. This paper presents results of surveys and excavations at Luxmanda, an open-air habitation site located farther south in Tanzania, and occupied many centuries earlier, than previously expected based upon prior models for the spread of herding. Technological and subsistence patterns demonstrate ties to northerly sites, suggesting that Luxmanda formed part of a network of early herders. The site is thus unlikely to stand alone, and further surveys are recommended to better understand the spread of herding into the region, and ultimately to southern Africa

Global Research Alliance N2O chamber methodology guidelines : Summary of modeling approaches

Acknowledgements Funding for this publication was provided by the New Zealand Government to support the objectives of the Livestock Research Group of the Global Research Alliance on Agricultural Greenhouse Gases. Individual authors work contribute to the following projects for which support has been received: Climate smart use of Norwegian organic soils (MYR, 2017-2022) project funded by the Research Council of Norway (decision no. 281109); Scottish Government's Strategic Research Programme, SuperG (under EU Horizon 2020 programme); DEVIL (NE/M021327/1), Soils-R-GRREAT (NE/P019455/1) and the EU H2020 project under Grant Agreement 774378—Coordination of International Research Cooperation on Soil Carbon Sequestration in Agriculture (CIRCASA); to project J-001793, Science and Technology Branch, Agriculture and Agri-Food Canada; and New Zealand Ministry of Business, Innovation and Employment (MBIE) core funding. Thanks to Alasdair Noble and the anonymous reviewers for helpful comments on a draft of this paper and to Anne Austin for editing services.Peer reviewedPublisher PD

High intensity neutrino oscillation facilities in Europe

The EUROnu project has studied three possible options for future, high intensity neutrino oscillation facilities in Europe. The first is a Super Beam, in which the neutrinos come from the decay of pions created by bombarding targets with a 4 MW proton beam from the CERN High Power Superconducting Proton Linac. The far detector for this facility is the 500 kt MEMPHYS water Cherenkov, located in the Fréjus tunnel. The second facility is the Neutrino Factory, in which the neutrinos come from the decay of μ+ and μ− beams in a storage ring. The far detector in this case is a 100 kt magnetized iron neutrino detector at a baseline of 2000 km. The third option is a Beta Beam, in which the neutrinos come from the decay of beta emitting isotopes, in particular He6 and Ne18, also stored in a ring. The far detector is also the MEMPHYS detector in the Fréjus tunnel. EUROnu has undertaken conceptual designs of these facilities and studied the performance of the detectors. Based on this, it has determined the physics reach of each facility, in particular for the measurement of CP violation in the lepton sector, and estimated the cost of construction. These have demonstrated that the best facility to build is the Neutrino Factory. However, if a powerful proton driver is constructed for another purpose or if the MEMPHYS detector is built for astroparticle physics, the Super Beam also becomes very attractive

The Grizzly, November 3, 1992

Senior Party Success • Keith Strunk Rallies Student Support • Vote: Our Future Depends on Us • Smoking Danger Update • Blue Eyes, Brown Eyes • Phi Psi Clothes Drive • Truth About Tomatoes • Coffee House: Good to the Last Drop! • Coffee Talk • Singles Review • Fresh Brewed, Mountain Grown, 70\u27s Rock • New Berman Endowment to Preserve Outdoor Art • Another Dark Hit Brewed by Waters • Choir Percolates a Performance • In Search of Purpose • Letters to the Editor • Intramural Football Culminates in Thriller • Field Hockey Struggles; Season Ends This Week • Volleyball Finished Season with Split • Football Battles Ranked W.P.I.https://digitalcommons.ursinus.edu/grizzlynews/1303/thumbnail.jp

A Long Baseline Neutrino Oscillation Experiment Using J-PARC Neutrino Beam and Hyper-Kamiokande

Document submitted to 18th J-PARC PAC meeting in May 2014. 50 pages, 41 figuresDocument submitted to 18th J-PARC PAC meeting in May 2014. 50 pages, 41 figuresDocument submitted to 18th J-PARC PAC meeting in May 2014. 50 pages, 41 figuresHyper-Kamiokande will be a next generation underground water Cherenkov detector with a total (fiducial) mass of 0.99 (0.56) million metric tons, approximately 20 (25) times larger than that of Super-Kamiokande. One of the main goals of Hyper-Kamiokande is the study of $CP$ asymmetry in the lepton sector using accelerator neutrino and anti-neutrino beams. In this document, the physics potential of a long baseline neutrino experiment using the Hyper-Kamiokande detector and a neutrino beam from the J-PARC proton synchrotron is presented. The analysis has been updated from the previous Letter of Intent [K. Abe et al., arXiv:1109.3262 [hep-ex]], based on the experience gained from the ongoing T2K experiment. With a total exposure of 7.5 MW $\times$ 10$^7$ sec integrated proton beam power (corresponding to $1.56\times10^{22}$ protons on target with a 30 GeV proton beam) to a $2.5$-degree off-axis neutrino beam produced by the J-PARC proton synchrotron, it is expected that the $CP$ phase $\delta_{CP}$ can be determined to better than 19 degrees for all possible values of $\delta_{CP}$, and $CP$ violation can be established with a statistical significance of more than $3\,\sigma$ ($5\,\sigma$) for $76$ ($58$) of the $\delta_{CP}$ parameter space

Long-Baseline Neutrino Facility (LBNF) and Deep Underground Neutrino Experiment (DUNE) Conceptual Design Report Volume 2: The Physics Program for DUNE at LBNF

The Physics Program for the Deep Underground Neutrino Experiment (DUNE) at the Fermilab Long-Baseline Neutrino Facility (LBNF) is described