145 research outputs found

    Planetary Boundaries and Sustainability Indicators. A Survey of Corporate Reporting Boundaries

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    The aim of this research is two fold: (a) to inquire into the methodological foundations of boundary setting for improved sustainability reporting and (b) to explore current corporate practice in this area, with a particular emphasis on environmental indicators. The paper contends that the boundaries of significant sustainability indicators should encompass all entities over which there is sustainability control, together with indirect impacts arising from activities across the supply chain, and not merely direct impacts caused by entities within boundaries based on financial control. The paper explores, through an empirical study of the sustainability reports disclosed by some of the top FT500 companies, how corporations are setting environmental boundaries in practice. Results show a lack of ambition in the practice of setting organizational and operational boundaries. Most reporting entities define organizational boundaries restricted to financial control, and most of the indirect environmental impacts sought remain undisclose

    A new evaluation of the uncertainty associated with CDIAC estimates of fossil fuel carbon dioxide emission

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    Three uncertainty assessments associated with the global total of carbon dioxide emitted from fossil fuel use and cement production are presented. Each assessment has its own strengths and weaknesses and none give a full uncertainty assessment of the emission estimates. This approach grew out of the lack of independent measurements at the spatial and temporal scales of interest. Issues of dependent and independent data are considered as well as the temporal and spatial relationships of the data. The result is a multifaceted examination of the uncertainty associated with fossil fuel carbon dioxide emission estimates. The three assessments collectively give a range that spans from 1.0 to 13% (2 σ). Greatly simplifying the assessments give a global fossil fuel carbon dioxide uncertainty value of 8.4% (2 σ). In the largest context presented, the determination of fossil fuel emission uncertainty is important for a better understanding of the global carbon cycle and its implications for the physical, economic and political world

    The emergence of circular economy: a new framing around prolonging resource productivity

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    In this article we use Hirsch and Levin’s (1999) notion of ‘umbrella concepts’ as an analytical lens, in order to articulate the valuable catalytic function the circular economy concept could perform in the waste and resource management debate. We realize this goal by anchoring the circular economy concept in this broader debate through a narrative approach. This leads to the insight that while the various resource strategies grouped under circular economy’s banner are not new individually, the concept offers a new framing of these strategies by drawing attention to their capacity of prolonging resource use as well as to the relationship between these strategies. As such, circular economy offers a new perspective on waste and resource management and provides a new cognitive unit and discursive space for debate. We conclude by discussing research opportunities for the IE community relating to the concept’s theoretical development and its implementation. Specifically, we pose that reinvigorating and growing the social science aspects of IE is required for both. After all, it is the wide adoption and collective implementation of an idea that shapes our material future

    Effect of feed pressure and long-term separation performance of Pebax-ionic liquid membranes for the recovery of difluoromethane (R32) from refrigerant mixture R410A

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    The R410A refrigerant blend (GWP = 2088), a near azeotropic and equimass mixture of difluoromethane (R32, GWP = 675) and pentafluoroethane (R125, GWP = 3500), has been included in the HFC phase down road map established worldwide. In this context, the recovery of value-added R32 from R410A using membrane technology would be a breakthrough in the refrigeration and air conditioning sector, given that conventional distillation cannot be applied to this separation. For the first time, this work has taken advantage of the combination of ionic liquids and polymeric membranes for the separation of the constituents of the R410A mixture. Results show a remarkable improvement in terms of R32 permeability and R32/R125 selectivity in the composite membranes containing 40 wt % [C2mim][SCN] (αR32/R125 up to 14.5) and [C2mim][BF4] (αR32/R125 up to 11.0) with respect to the neat polymer membranes (αR32/R125 up to 6.9). Besides, the long-term stability was successfully tested for 25 days under high pressure conditions (7 and 12 bar), which makes these composite membranes excellent candidates for the development of membrane-based R32 separation and recovery processes.This research is supported by Project KET4F-Gas – SOE2/P1/P0823, which is co-financed by the European Regional Development Fund within the framework of Interreg Sudoe Programme, and Project PID2019-105827RB-I00, Ministerio de Ciencia e Innovación (Spain). The authors acknowledge the collaboration of Dr. Rosario Benavente (Institute of Polymer Science and Technology-CSIC) to perform the DSC experiments. Dr. Fernando Pardo, acknowledges the post-doctoral fellowship (FJCI-2017-32884, ‘Juan de la Cierva Formación’) from the Spanish Ministry of Science, Innovation and Universities

    Exploring the planetary boundary for chemical pollution

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    Application of a comprehensive extraction technique for the determination of poly- and perfluoroalkyl substances (PFASs) in Great Lakes Region sediments.

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    A comprehensive method to extract perfluoroalkane sulfonic acids (PFSAs), perfluoroalkyl carboxylic acids (PFCAs), polyfluoroalkyl phosphoric acid diesters (diPAPs), perfluoroalkyl phosphinic acids (PFPiAs) and perfluoroalkyl phosphonic acids (PFPAs) from sediment and analysis by liquid chromatography tandem mass spectrometry (LC-MS/MS) was developed and applied to sediment cores from three small isolated lakes (Plastic Lake, Lake 442, Lake Tettegouche) and Lake Ontario in the Great Lakes Region. Recoveries of the target compounds using the optimized acetonitrile/sodium hydroxide extraction ranged from 73% to 120%. The greatest concentrations of per- and polyfluorinated alkyl substances (PFASs) were recorded in sediment from Lake Ontario (ΣPFASs 13.1 ng/g), where perfluorooctane sulfonic acid (PFOS) contributed over 80% of the total. Concentrations in Lake Ontario were approximately 1-2 orders of magnitude greater than the more remote lakes subject to primarily atmospheric inputs. Whilst the PFAS contribution in Lake Ontario was dominated by PFOS, the more remote lakes contained sediment with higher proportions of PFCAs. Trace amounts of emerging PFASs (diPAPs and PFPiAs) were found in very recent surface Lake Ontario and remote lake sediments

    Lessons from the removal of lead from gasoline for controlling other environmental pollutants: A case study from New Zealand

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    <p>Abstract</p> <p>Background</p> <p>It took over two decades to achieve the removal of leaded gasoline in this country. This was despite international evidence and original research conducted in New Zealand on the harm to child cognitive function and behaviour from lead exposure.</p> <p>Objective</p> <p>To identify lessons from the New Zealand experience of removing leaded gasoline that are potentially relevant to the control of other environmental pollutants.</p> <p>Discussion</p> <p>From the available documentation, we suggest a number of reasons for the slow policy response to the leaded gasoline hazard. These include: (1) industry power in the form of successful lobbying by the lead additive supplier, Associated Octel; (2) the absence of the precautionary principle as part of risk management policy; and (3) weak policymaking machinery that included: (a) the poor use of health research evidence (from both NZ and internationally), as well as limited use of expertise in academic and non-governmental organisations; (b) lack of personnel competent in addressing technically complex issues; and (c) diffusion of responsibility among government agencies.</p> <p>Conclusion</p> <p>There is a need for a stronger precautionary approach by policymakers when considering environmental pollutants. Politicians, officials and health workers need to strengthen policymaking processes and effectively counter the industry tactics used to delay regulatory responses.</p
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