Selective nitrogen adsorption via backbonding in a metal-organic framework with exposed vanadium sites.

Industrial processes prominently feature π-acidic gases, and an adsorbent capable of selectively interacting with these molecules could enable important chemical separations1-4. Biological systems use accessible, reducing metal centres to bind and activate weakly π-acidic species, such as N2, through backbonding interactions5-7, and incorporating analogous moieties into a porous material should give rise to a similar adsorption mechanism for these gaseous substrates8. Here, we report a metal-organic framework featuring exposed vanadium(II) centres capable of back-donating electron density to weak π acids to successfully target π acidity for separation applications. This adsorption mechanism, together with a high concentration of available adsorption sites, results in record N2 capacities and selectivities for the removal of N2 from mixtures with CH4, while further enabling olefin/paraffin separations at elevated temperatures. Ultimately, incorporating such π-basic metal centres into porous materials offers a handle for capturing and activating key molecular species within next-generation adsorbents

Measuring the non-thermal pressure in early type galaxy atmospheres: A comparison of X-ray and optical potential profiles in M87 and NGC1399

We compare the gravitational potential profiles of the elliptical galaxies NGC 4486 (M87) and NGC 1399 (the central galaxy in the Fornax cluster) derived from X-ray and optical data. This comparison suggests that the combined contribution of cosmic rays, magnetic fields and micro-turbulence to the pressure is ~10% of the gas thermal pressure in the cores of NGC 1399 and M87, although the uncertainties in our model assumptions (e.g., spherical symmetry) are sufficiently large that the contribution could be consistent with zero. In the absence of any other form of non-thermal pressure support, these upper bounds translate into upper limits on the magnetic field of ~10-20 muG at a distance of 1'-2' from the centers of NGC1399 and M87. We show that these results are consistent with the current paradigm of cool cluster cores, based on the assumption that AGN activity regulates the thermal state of the gas by injecting energy into the intra-cluster medium. The limit of ~10-20% on the energy density in the form of relativistic protons applies not only to the current state of the gas, but essentially to the entire history of the intra-cluster medium, provided that cosmic ray protons evolve adiabatically and that their spatial diffusion is suppressed.Comment: Accepted for MNRAS. 19 pages; 14 figures; expanded version in response to comments from the refere

Scalable and effective multi-level entangled photon states: a promising tool to boost quantum technologies

Multi-level (qudit) entangled photon states are a key resource for both fundamental physics and advanced applied science, as they can significantly boost the capabilities of novel technologies such as quantum communications, cryptography, sensing, metrology, and computing. The benefits of using photons for advanced applications draw on their unique properties: photons can propagate over long distances while preserving state coherence, and they possess multiple degrees of freedom (such as time and frequency) that allow scalable access to higher dimensional state encoding, all while maintaining low platform footprint and complexity. In the context of out-of-lab use, photon generation and processing through integrated devices and off-the-shelf components are in high demand. Similarly, multi-level entanglement detection must be experimentally practical, i.e., ideally requiring feasible single-qudit projections and high noise tolerance. Here, we focus on multi-level optical Bell and cluster states as a critical resource for quantum technologies, as well as on universal witness operators for their feasible detection and entanglement characterization. Time- and frequency-entangled states are the main platform considered in this context. We review a promising approach for the scalable, cost-effective generation and processing of these states by using integrated quantum frequency combs and fiber-based devices, respectively. We finally report an experimentally practical entanglement identification and characterization technique based on witness operators that is valid for any complex photon state and provides a good compromise between experimental feasibility and noise robustness. The results reported here can pave the way toward boosting the implementation of quantum technologies in integrated and widely accessible photonic platform

Workshop on PIDs within NFDI: Report of the Working Group “Persistent Identifiers (PID)” of the Section Common Infrastructures of the NFDI

In order to gain an overview of the current state of the discussion on PIDs and for the identification of use cases for the initiation phase of a PID service within the NFDI basic services, the working group Persistent Identifier of the Section Common Infrastructures of the NFDI hosted an online workshop in January 2023. In the course of the workshop, members of nine different NFDI consortia presented the current application of PIDs in their consortia

Constraining the population of cosmic ray protons in cooling flow clusters with gamma-ray and radio observations: Are radio mini-halos of hadronic origin?

We wish to constrain the cosmic-ray proton (CRp) population in galaxy clusters. By hadronic interactions with the thermal gas of the intra-cluster medium (ICM), the CRp produce gamma-rays for which we develop an analytic formalism to deduce their spectral distribution. Assuming the CRp-to-thermal energy density ratio X_CRp and the CRp spectral index to be spatially constant, we derive an analytic relation between the gamma-ray and bolometric X-ray fluxes, F_gamma and F_X. Based on our relation, we compile a sample of suitable clusters which are promising candidates for future detection of gamma-rays resulting from hadronic CRp interactions. Comparing to EGRET upper limits, we constrain the CRp population in the cooling flow clusters Perseus and Virgo to X_CRp < 20%. Assuming a plausible value for the CRp diffusion coefficient kappa, we find the central CRp injection luminosity of M 87 to be limited to 10^43 erg s^-1 kappa/(10^29 cm^2 s^-1). The synchrotron emission from secondary electrons generated in CRp hadronic interactions allows even tighter limits to be placed on the CRp population using radio observations. We obtain excellent agreement between the observed and theoretical radio brightness profiles for Perseus, but not for Coma without a radially increasing CRp-to-thermal energy density profile. Since the CRp and magnetic energy densities necessary to reproduce the observed radio flux are very plausible, we propose synchrotron emission from secondary electrons as an attractive explanation of the radio mini-halos found in cooling flow clusters. This model can be tested with future sensitive gamma-ray observations of the accompanying pi0-decays. We identify Perseus (A 426), Virgo, Ophiuchus, and Coma (A 1656) as the most promising candidate clusters for such observations.Comment: 20 pages, 8 figures. Corrected Figure 3 to match the erratum accepted by A&

Consensus Guidelines for Advancing Coral Holobiont Genome and Specimen Voucher Deposition

Coral research is being ushered into the genomic era. To fully capitalize on the potential discoveries from this genomic revolution, the rapidly increasing number of high-quality genomes requires effective pairing with rigorous taxonomic characterizations of specimens and the contextualization of their ecological relevance. However, to date there is no formal framework that genomicists, taxonomists, and coral scientists can collectively use to systematically acquire and link these data. Spurred by the recently announced “Coral symbiosis sensitivity to environmental change hub” under the “Aquatic Symbiosis Genomics Project” - a collaboration between the Wellcome Sanger Institute and the Gordon and Betty Moore Foundation to generate gold-standard genome sequences for coral animal hosts and their associated Symbiodiniaceae microalgae (among the sequencing of many other symbiotic aquatic species) - we outline consensus guidelines to reconcile different types of data. The metaorganism nature of the coral holobiont provides a particular challenge in this context and is a key factor to consider for developing a framework to consolidate genomic, taxonomic, and ecological (meta)data. Ideally, genomic data should be accompanied by taxonomic references, i.e., skeletal vouchers as formal morphological references for corals and strain specimens in the case of microalgal and bacterial symbionts (cultured isolates). However, exhaustive taxonomic characterization of all coral holobiont member species is currently not feasible simply because we do not have a comprehensive understanding of all the organisms that constitute the coral holobiont. Nevertheless, guidelines on minimal, recommended, and ideal-case descriptions for the major coral holobiont constituents (coral animal, Symbiodiniaceae microalgae, and prokaryotes) will undoubtedly help in future referencing and will facilitate comparative studies. We hope that the guidelines outlined here, which we will adhere to as part of the Aquatic Symbiosis Genomics Project sub-hub focused on coral symbioses, will be useful to a broader community and their implementation will facilitate cross- and meta-data comparisons and analyses.CV acknowledges funding from the German Research Foundation (DFG), grants 433042944 and 458901010. Open Access publication fees are covered by an institutional agreement of the University of Konstanz