311 research outputs found

    Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions

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    This document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy Fuels, copyright © American Chemical Society after peer review and technical editing by the publisher.[EN] The present work includes findings from proof-of-principle feasibility studies on iron nanopowder combustion under idealized, enginelike, and real engine conditions. The study was conducted under the scope of recent interest in metallic nanoparticles as alternative fuels for internal combustion engines. More specifically, Fe nanoparticles with different morphologies and average primary particle sizes ranging from 25 to 85 nm were studied with respect to their oxidation characteristics via thermogravimetric analysis as well as in customized shock tube, constant-volume vessel, and compression-ignition (CI) engine configurations. Combusted powder samples were in all cases examined via in situ and ex situ techniques for the identification of combustion products and their morphologies. The findings facilitated the determination of the main phenomena involved during oxidation. The results verified that combustion of Fe nanoparticles in a slightly modified CI engine is feasible, albeit with various technological challenges related to ignition and scavenging that inhibit combustion quality.The authors thank the European Commission for partial funding of this work through the Project “COMETNANO” (FP7-NMP4-SL-2009-229063).Mandilas, C.; Karagiannakis, G.; Konstandopoulos, AG.; Beatrice, C.; Lazzaro, M.; Di Blasio, G.; Molina, S.... (2016). Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions. Energy and Fuels. 30(5):4318-4330. https://doi.org/10.1021/acs.energyfuels.6b00121S4318433030

    Evolution of faint radio sources in the VIDEO-XMM3 field

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    © 2013 The Authors Published by Oxford University Press on behalf of the Royal Astronomical SocietyIt has been speculated that low-luminosity radio-loud active galactic nuclei (AGN) have the potential to serve as an important source of AGN feedback, and may be responsible for suppressing star formation activity in massive elliptical galaxies at late times. As such the cosmic evolution of these sources is vitally important to understand the significance of such AGN feedback processes and their influence on the global star formation history of the Universe. In this paper, we present a new investigation of the evolution of faint radio sources out to z ~ 2.5. We combine a 1 square degree Very Large Array radio survey, complete to a depth of 100 μJy, with accurate 10 band photometric redshifts from the following surveys: Visible and Infrared Survey Telescope for Astronomy Deep Extragalactic Observations and Canada-France-Hawaii Telescope Legacy Survey. The results indicate that the radio population experiences mild positive evolution out to z ~ 1.2 increasing their space density by a factor of ~3, consistent with results of several previous studies. Beyond z = 1.2, there is evidence of a slowing down of this evolution. Star-forming galaxies drive the more rapid evolution at low redshifts, z 1.2. The evolution is best fitted by pure luminosity evolution with star-forming galaxies evolving as (1 + z)2.47 ± 0.12 and AGN as (1 + z)1.18 ± 0.21M.Peer reviewe

    Effects of low pressure exhaust gas recirculation on regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine

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    Regulated and unregulated gaseous emissions with high pressure and low pressure EGR (exhaust gas recirculation) system were tested in a 4-cylinder, light-duty diesel EURO IV engine typically used in European vehicles. Four different engine calibrations with the low pressure EGR system were studied. Regulated emissions of NOX, CO, HC and CO2 were measured for each configuration. Unburned Hydrocarbon Speciation, HCHO (formaldehyde), HCOOH (formic acid) and N2O (nitrous oxide) were also measured in order to determine the MIR (maximum incremental reactivity) of the gaseous emissions. Pollutants were measured without the DOC (diesel oxidation catalyst) to gather data about raw emissions. When the low pressure EGR system was used, decreases in NOX, N2O and fuel consumption were observed and significant increases HC, CO and unregulated emissions; this is the result of a lower intake manifold temperature, which provides a higher gas density which modifies the combustion process. The potential of tropospheric ozone production was higher in all cases when the low pressure EGR was used. © 2011 Elsevier Ltd.Bermúdez, V.; Luján, JM.; Pla Moreno, B.; Linares Rodríguez, WG. (2011). Effects of low pressure exhaust gas recirculation on regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine. Energy. 36(9):5655-5665. doi:10.1016/j.energy.2011.06.061S5655566536

    Quantum Locality

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    It is argued that while quantum mechanics contains nonlocal or entangled states, the instantaneous or nonlocal influences sometimes thought to be present due to violations of Bell inequalities in fact arise from mistaken attempts to apply classical concepts and introduce probabilities in a manner inconsistent with the Hilbert space structure of standard quantum mechanics. Instead, Einstein locality is a valid quantum principle: objective properties of individual quantum systems do not change when something is done to another noninteracting system. There is no reason to suspect any conflict between quantum theory and special relativity.Comment: Introduction has been revised, references added, minor corrections elsewhere. To appear in Foundations of Physic

    The Bristol Method: Green Capital Student Capital - The power of student sustainability engagement

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    THE BRISTOL METHODThe Bristol Method is a knowledge-transfer programme aimed at helping people in other cities understand and apply the lessons that Bristol has learned in becoming a more sustainable city, not just in 2015 but in the last decade. Each module of the Bristol Method is presented as an easy-to-digest ‘how to’ guide on a particular topic, which use Bristol’s experiences as a case study. The modules contain generic advice and recommendations that each reader can tailor to their own circumstances.This module focusses on the Green Capital: Student Capital project, and explains how the University of the West of England, Bristol (UWE) and the University of Bristol – with their respective students’ unions – have been working in partnership with the city and local communities, using Higher Education Funding Council for England Catalyst funding to promote student involvement in Green Capital activities across Greater Bristol.Student Capital created a broad programme of citywide impact during European Green Capital. It delivered a programme of student and staff engagement in enhancing sustainability within the city and has developed student and staff engagement with sustainability action. Through action research approaches it is also providing lessons for how institutions can collaborate across cities and communities to have internal and external impacts for sustainability. This report is for anyone seeking to increase sustainability engagement. In it we tell the story of the Student Capital project, explaining the processes and the outcomes, and suggesting pieces of advice and lessons for what went well, and what could have been done better or differently

    Design of synthetic EGR and simulation study of the effect of simplified formulations on the ignition delay of isooctane and n-heptane

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    [EN] A method to create synthetic mixtures that simulate the Exhaust Gas Recirculation (EGR) of an internal combustion engine, using O2, N2, CO2, H2O and Ar, has been designed. Different simplifications of this synthetic EGR have been validated in order to reproduce ignition delays. To do this, a parametric study has been carried out with CHEMKIN. The ignition delay of each simplified mixture and the ignition delay of the complete mixture have been simulated for different initial pressures, temperatures, equivalence ratios, oxygen mass fractions and for two different fuels, isooctane and n-heptane. The results obtained with each simplification have been compared with the results obtained with the complete EGR, and based on this comparison the errors in ignition delay have been calculated. The behavior of the errors in ignition delay with the variation of the different parameters of the simulations has been studied. In summary, it can be seen that the relative error increases with temperature and decreases with pressure, equivalence ratio and oxygen mass fraction. Finally, the limit oxygen mass fractions for the use of each simplification have been obtained. Based on these results, it can be concluded that the only gas that can be obviated to keep the error in ignition delay under 1% is ArThe authors would like to thank different members of the CMT-Motores Termicos team of the Universitat Politecnica de Valencia for their contribution to this work. The authors would also like to thank the Spanish Ministry of Education for financing the PhD. Studies of Dario Lepez-Pintor (Grant FPU13/02329). This work was partly founded by the Generalitat Valenciana, project PROMETEOII/2014/043.Desantes, J.; López, JJ.; Molina, S.; López Pintor, D. (2015). Design of synthetic EGR and simulation study of the effect of simplified formulations on the ignition delay of isooctane and n-heptane. Energy Conversion and Management. 96:521-531. https://doi.org/10.1016/j.enconman.2015.03.003S5215319

    Using statistical and artificial neural networks to predict the permeability of loosely packed granular materials

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    Well-known analytical equations for predicting permeability are generally reported to overestimate this important property of porous media. In this work, more robust models developed from statistical (multivariable regression) and Artificial Neural Network (ANN) methods utilised additional particle characteristics [‘fines ratio’ (x50/x10) and particle shape] that are not found in traditional analytical equations. Using data from experiments and literature, model performance analyses with average absolute error (AAE) showed error of ~40% for the analytical models (Kozeny–Carman and Happel–Brenner). This error reduces to 9% with ANN model. This work establishes superiority of the new models, using experiments and mathematical techniques

    Utilisation of an operative difficulty grading scale for laparoscopic cholecystectomy

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    Background A reliable system for grading operative difficulty of laparoscopic cholecystectomy would standardise description of findings and reporting of outcomes. The aim of this study was to validate a difficulty grading system (Nassar scale), testing its applicability and consistency in two large prospective datasets. Methods Patient and disease-related variables and 30-day outcomes were identified in two prospective cholecystectomy databases: the multi-centre prospective cohort of 8820 patients from the recent CholeS Study and the single-surgeon series containing 4089 patients. Operative data and patient outcomes were correlated with Nassar operative difficultly scale, using Kendall’s tau for dichotomous variables, or Jonckheere–Terpstra tests for continuous variables. A ROC curve analysis was performed, to quantify the predictive accuracy of the scale for each outcome, with continuous outcomes dichotomised, prior to analysis. Results A higher operative difficulty grade was consistently associated with worse outcomes for the patients in both the reference and CholeS cohorts. The median length of stay increased from 0 to 4 days, and the 30-day complication rate from 7.6 to 24.4% as the difficulty grade increased from 1 to 4/5 (both p < 0.001). In the CholeS cohort, a higher difficulty grade was found to be most strongly associated with conversion to open and 30-day mortality (AUROC = 0.903, 0.822, respectively). On multivariable analysis, the Nassar operative difficultly scale was found to be a significant independent predictor of operative duration, conversion to open surgery, 30-day complications and 30-day reintervention (all p < 0.001). Conclusion We have shown that an operative difficulty scale can standardise the description of operative findings by multiple grades of surgeons to facilitate audit, training assessment and research. It provides a tool for reporting operative findings, disease severity and technical difficulty and can be utilised in future research to reliably compare outcomes according to case mix and intra-operative difficulty
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