Tailoring nanostructured surfaces with plasmonic/magnetic multifunctional response

IIn this work, we present an innovative way to functionalize large surfaces combining both plasmonic and magnetic nanoparticles on a substrate, by the growth of bilayers and a subsequent single annealing. In particular, we show here the formation of Au and gamma- Fe₂O₃ nanoparticles using this route. Thermal treatments promote the nanostructuration of the film plus a partial oxidation of Fe to form ferrimagnetic oxides. For this purpose, annealing conditions and the structure of the bilayer must be selected to achieve an optimal nanostructuration, avoiding the full oxidation of Fe to form antiferromagnetic hematite. Published by AIP Publishing

Experimental study of non-inductive current in Heliotron J

It is important to control non-inductive current for generation and steady-state operation of highperformance plasmas in toroidal fusion devices. Helical devices allow dynamic control of non-inductivecurrent through a wide variety of magnetic configurations. The reversal of non-inductive current consisting of bootstrap current and electron cyclotron driven current in electron cyclotron heating plasmas has been observed in a specific configuration at low density in Heliotron J device. By analyzing thenon-inductive current for normal and reversed magnetic fields, we present experimental evidence for the reversal of bootstrap current. Our experiments and calculations suggest that the reversal is caused bya positive radial electric field of about 10 kV/m. Moreover, we show that the typical electron cyclotron current drive efficiency in Heliotron J plasma is about 1.0 × 1017 AW?1m?2, which is comparable to other helical devices. We have found that the value is about 10 times lower than that of tokamak devices. This might be due to an enhanced Ohkawa effect by trapped particles

Elliptic flow of charged particles in Pb-Pb collisions at 2.76 TeV

We report the first measurement of charged particle elliptic flow in Pb-Pb collisions at 2.76 TeV with the ALICE detector at the CERN Large Hadron Collider. The measurement is performed in the central pseudorapidity region (|$\eta$|<0.8) and transverse momentum range 0.2< $p_{\rm T}$< 5.0 GeV/$c$. The elliptic flow signal v$_2$, measured using the 4-particle correlation method, averaged over transverse momentum and pseudorapidity is 0.087 $\pm$ 0.002 (stat) $\pm$ 0.004 (syst) in the 40-50% centrality class. The differential elliptic flow v$_2(p_{\rm T})$ reaches a maximum of 0.2 near $p_{\rm T}$ = 3 GeV/$c$. Compared to RHIC Au-Au collisions at 200 GeV, the elliptic flow increases by about 30%. Some hydrodynamic model predictions which include viscous corrections are in agreement with the observed increase.Comment: 10 pages, 4 captioned figures, published version, figures at http://aliceinfo.cern.ch/ArtSubmission/node/389

A precise measurement of the Z -boson double-differential transverse momentum and rapidity distributions in the full phase space of the decay leptons with the ATLAS experiment at √s = 8 TeV

This paper presents for the first time a precise measurement of the production properties of the Z boson in the full phase space of the decay leptons. This is in contrast to the many previous precise unfolded measurements performed in the fiducial phase space of the decay leptons. The measurement is obtained from proton–proton collision data collected by the ATLAS experiment in 2012 at s=8 TeV at the LHC and corresponding to an integrated luminosity of 20.2 fb-1. The results, based on a total of 15.3 million Z-boson decays to electron and muon pairs, extend and improve a previous measurement of the full set of angular coefficients describing Z-boson decay. The double-differential cross-section distributions in Z-boson transverse momentum pT and rapidity y are measured in the pole region, defined as 80&lt;mℓℓ&lt;100 GeV, over the range |y|&lt;3.6. The total uncertainty of the normalised cross-section measurements in the peak region of the pT distribution is dominated by statistical uncertainties over the full range and increases as a function of rapidity from 0.5–1.0% for |y|&lt;2.0 to 2-7% at higher rapidities. The results for the rapidity-dependent transverse momentum distributions are compared to state-of-the-art QCD predictions, which combine in the best cases approximate N4LL resummation with N3LO fixed-order perturbative calculations. The differential rapidity distributions integrated over pT are even more precise, with accuracies from 0.2–0.3% for |y|&lt;2.0 to 0.4–0.9% at higher rapidities, and are compared to fixed-order QCD predictions using the most recent parton distribution functions. The agreement between data and predictions is quite good in most cases

The heterogeneous flexible periodic vehicle routing problem: Mathematical formulations and solution algorithms

The aim of this paper is to introduce the Flexible Periodic Vehicle Routing Problem with Heterogeneous Fleet, a variant of the Periodic Vehicle Routing Problem. Flexibility is introduced in service schedules and delivered quantities, heterogeneity comes from different vehicles capacities and speeds. Three Mixed-Integer Linear Programming formulations and a matheuristic, based on Kernel Search, are proposed. Computational tests are made to evaluate the performance of the three formulations and to assess the quality of the solutions provided by the matheuristic

Complete Analyticity of the 2D Potts Model above the Critical Temperature

We investigate the complete analyticity (CA) of the two-dimensional q-state Potts model for large values of q. We are able to prove it for every temperature T > Tcr(q), provided we restrict ourselves to nice subsets, their niceness depending on the temperature T. Contrary to this restricted complete analyticity (RCA), the full CA is known to fail for some values of the temperature above Tcr(q). Our proof is based on Pirogov-Sinai theory and cluster expansions for the Fortuin-Kasteleyn representation, which are available for the Potts model at all temperatures, provided q is large enough.

Continuous process for the epoxidation of terpenes using mesoscale oscillatory baffled reactors

Continuous epoxidation of terpenes with H2O2 was carried out using mesoscale oscillatory baffled reactors (meso-OBRs) in a solvent-free environment. The performance of the new 3D-printed single, tri- and multi-orifice baffles was compared with helical and integral baffles. The performance investigated includes mixing intensity, induction period, steady-state attainment, and heat removal capability of the meso-OBR. Moreover, passive isothermalisation was also investigated using meso-OBR in a heat pipe assembly. The tri- and multi-orifice baffles were able to overcome mixing limitations and achieved a comparable rate of reaction to batch at mixing conditions of Reo > 850 and Reo > 500, respectively. Both baffles exhibited rapid steady-state attainment, shorter induction period (t = 1.5τ) and better reproducibility with product variation of ∼1.3%. The meso-OBR designs demonstrated effective heat transfer capability, allowing the reaction to being operated isothermally with ±1 °C temperature variation in solvent-free conditions. This removes the need for a solvent, thus reducing reaction volume by a 5-fold. The timescale for the reaction was reduced from ∼8 h in a conventional process to 30 min in the multi-orifice meso-OBR, a 16-fold reduction. A better process has been developed for a continuous epoxidation of terpenes with H2O2 using multi-orifice meso-OBRs, with a potential intensification factor of ∼80

Site-selective chemoenzymatic construction of synthetic glycoproteins using endoglycosidases †

Combined chemical tagging followed by Endo-A catalysed elongation allows access to homogeneous, elaborated glycoproteins. A survey of different linkages and sugars demonstrated not only that unnatural linkages can be tolerated but they can provide insight into the scope of Endo-A transglycosylation activity. S-linked GlcNAc-glycoproteins are useful substrates for Endo-A extensions and display enhanced stability to hydrolysis at exposed sites. O-CH 2 -triazole-linked GlcNAc-glycoproteins derived from azidohomoalanine-tagged protein precursors were found to be optimal at sterically demanding sites