20 research outputs found

    Centrality evolution of the charged-particle pseudorapidity density over a broad pseudorapidity range in Pb-Pb collisions at root s(NN)=2.76TeV

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    Machine Learning Methods Applied for Modeling the Process of Obtaining Bricks Using Silicon-Based Materials

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    Most of the time, industrial brick manufacture facilities are designed and commissioned for a particular type of manufacture mix and a particular type of burning process. Productivity and product quality maintenance and improvement is a challenge for process engineers. Our paper aims at using machine learning methods to evaluate the impact of adding new auxiliary materials on the amount of exhaust emissions. Experimental determinations made in similar conditions enabled us to build a database containing information about 121 brick batches. Various models (artificial neural networks and regression algorithms) were designed to make predictions about exhaust emission changes when auxiliary materials are introduced into the manufacture mix. The best models were feed-forward neural networks with two hidden layers, having MSE 2 > 0.82 and, as regression model, kNN with error < 0.6. Also, an optimization procedure, including the best models, was developed in order to determine the optimal values for the parameters that assure the minimum quantities for the gas emission. The Pareto front obtained in the multi-objective optimization conducted with grid search method allows the user the chose the most convenient values for the dry product mass, clay, ash and organic raw materials which minimize gas emissions with energy potential

    Evaluation of the Sublimation Process of Some Purine Derivatives: Sublimation Rate, Activation Energy, Mass Transfer Coefficients and Phenomenological Models

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    Caffeine and theophylline are compounds with important applications in the pharmaceutical industry and other fields of the chemical industry. These purine derivatives have simple chemical structures, therefore, the evaluation of their sublimation process contributes to the development of mass transfer analysis methods that can later be applied to other compounds with more complex structures. With the help of thermogravimetric analysis in isothermal conditions, the kinetic study of the sublimation of caffeine and theophylline, along with the evaluation of kinetic parameters (activation energy and the pre-exponential factor), was carried out. Global mass transfer coefficients were determined, which vary for caffeine between 53 &times; 10&minus;8 and 631 &times; 10&minus;8 mol/s&middot;m2&middot;Pa, and for theophylline between 68 &times; 10&minus;8 and 441 &times; 10&minus;8 mol/s&middot;m2&middot;Pa. The dimensionless equations of the form: Sh=a+b&middot;Rec&middot;Scd have been proposed, which allow the determination of individual mass transfer coefficients at temperatures between 130 and 160 &deg;C for caffeine and between 170 and 200 &deg;C for theophylline

    Viscosity Deviation Modeling for Binary and Ternary Mixtures of Benzyl Alcohol-N-Hexanol-Water

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    Knowing the thermodynamic and transport properties of liquid systems is very important in engineering for the development of theoretical models and for the design of new technologies. Models that allow accurate predictions of thermodynamic and transport properties are needed in chemical engineering calculations involving fluid, heat, and mass transfer. In this study, the modeling of viscosity deviation for binary and ternary systems containing benzyl alcohol, n-hexanol, and water, less studied in the literature, was carried out using Redlich and Kister (R-L) models, multiple linear regression (MLR) models and artificial neural networks (ANN). The viscosity of the binary and ternary systems was experimentally determined at the following temperatures: 293.15, 303.15, 313.15, and 323.15 K. Viscosity deviation was calculated and then correlated with mole fractions, normalized temperature, and refractive index. The neural model that led to the best performance in the testing and validation stages contains 4 neurons in the input layer, 12 neurons in the hidden layer, and one neuron in the output layer. In the testing stage for this model, the standard deviation is 0.0067, and the correlation coefficient is 0.999. In the validation stage, a deviation of 0.0226 and a correlation coefficient of 0.996 were obtained. The MLR model led to worse results than those obtained with the neural model and also with the R-L models. The standard deviation for this model is 0.099, and the correlation coefficient is 0.898. Its advantage over the R-L type models is that the influence of both composition and temperature are included in a single equation

    Obtaining Bricks Using Silicon-Based Materials: Experiments, Modeling and Optimization with Artificial Intelligence Tools

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    In the brick manufacturing industry, there is a growing concern among researchers to find solutions to reduce energy consumption. An industrial process for obtaining bricks was approached, with the manufacturing mix modified via the introduction of sunflower seed husks and sawdust. The process was analyzed with artificial intelligence tools, with the goal of minimizing the exhaust emissions of CO and CH4. Optimization algorithms inspired by human and virus behaviors were applied in this approach, which were associated with neural network models. A series of feed-forward neural networks have been developed, with 6 inputs corresponding to the working conditions, one or two intermediate layers and one output (CO or CH4, respectively). The results for ten biologically inspired algorithms and a search grid method were compared successfully within a single objective optimization procedure. It was established that by introducing 1.9% sunflower seed husks and 0.8% sawdust in the brick manufacturing mix, a minimum quantity of CH4 emissions was obtained, while 0% sunflower seed husks and 0.5% sawdust were the minimum quantities for CO emissions

    Assessing Changes in Diabetic Retinopathy Caused by Diabetes Mellitus and Glaucoma Using Support Vector Machines in Combination with Differential Evolution Algorithm

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    The aim of this study is to evaluate the changes related to diabetic retinopathy (DR) (no changes, small or moderate changes) in patients with glaucoma and diabetes using artificial intelligence instruments: Support Vector Machines (SVM) in combination with a powerful optimization algorithm—Differential Evolution (DE). In order to classify the DR changes and to make predictions in various situations, an approach including SVM optimized with DE was applied. The role of the optimizer was to automatically determine the SVM parameters that lead to the lowest classification error. The study was conducted on a sample of 52 patients: particularly, 101 eyes with glaucoma and diabetes mellitus, in the Ophthalmology Clinic I of the “St. Spiridon” Clinical Hospital of IaƟi. The criteria considered in the modelling action were normal or hypertensive open-angle glaucoma, intraocular hypertension and associated diabetes. The patients with other types of glaucoma pseudoexfoliation, pigment, cortisone, neovascular and primitive angle-closure, and those without associated diabetes, were excluded. The assessment of diabetic retinopathy changes were carried out with Volk lens and Fundus Camera Zeiss retinal photography on the dilated pupil, inspecting all quadrants. The criteria for classifying the DR (early treatment diabetic retinopathy study—ETDRS) changes were: without changes (absence of DR), mild forma nonproliferative diabetic retinopathy (the presence of a single micro aneurysm), moderate form (micro aneurysms, hemorrhages in 2–3 quadrants, venous dilatations and soft exudates in a quadrant), severe form (micro aneurysms, hemorrhages in all quadrants, venous dilatation in 2–3 quadrants) and proliferative diabetic retinopathy (disk and retinal neovascularization in different quadrants). Any new clinical element that occurred in subsequent checks, which led to their inclusion in severe nonproliferative or proliferative forms of diabetic retinopathy, was considered to be the result of the progression of diabetic retinopathy. The results obtained were very good; in the testing phase, a 95.23% accuracy has been obtained, only one sample being wrongly classified. The effectiveness of the classification algorithm (SVM), developed in optimal form with DE, and used in predictions of retinal changes related to diabetes, was demonstrated

    Measurement of electrons from semileptonic heavy-flavour hadron decays at midrapidity in pp and Pb–Pb collisions at √sNN = 5.02 TeV

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    The differential invariant yield as a function of transverse momentum (pT) of electrons from semileptonic heavy-flavour hadron decays was measured at midrapidity in central (0–10%), semi-central (30–50%) and peripheral (60–80%) lead–lead (Pb–Pb) collisions at √sNN = 5.02 TeV in the pT intervals 0.5–26 GeV/c (0–10% and 30–50%) and 0.5–10 GeV/c (60–80%). The production cross section in proton–proton (pp) collisions at √s = 5.02 TeV was measured as well in 0.5 < pT < 10 GeV/c and it lies close to the upper band of perturbative QCD calculation uncertainties up to pT = 5 GeV/c and close to the mean value for larger pT. The modification of the electron yield with respect to what is expected for an incoherent superposition of nucleon–nucleon collisions is evaluated by measuring the nuclear modification factor RAA. The measurement of the RAA in different centrality classes allows in-medium energy loss of charm and beauty quarks to be investigated. The RAA shows a suppression with respect to unity at intermediate pT, which increases while moving towards more central collisions. Moreover, the measured RAA is sensitive to the modification of the parton distribution functions (PDF) in nuclei, like nuclear shadowing, which causes a suppression of the heavy-quark production at low pT in heavy-ion collisions at LHC

    HΛ3 and H‟Λ‟3 lifetime measurement in Pb–Pb collisions at √sNN=5.02 TeV via two-body decay

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    An improved value for the lifetime of the (anti-)hypertriton has been obtained using the data sample of Pb–Pb collisions at √sNN = 5.02 TeV collected by the ALICE experiment at the LHC. The (anti-)hypertriton has been reconstructed via its charged two-body mesonic decay channel and the lifetime has been determined from an exponential fit to the dN/d(ct) spectrum. The measured value, τ = 242+34 −38 (stat.) ± 17 (syst.) ps, is compatible with representative theoretical predictions, thus contributing to the solution of the longstanding hypertriton lifetime puzzle

    Study of the Λ–Λ interaction with femtoscopy correlations in pp and p–Pb collisions at the LHC

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    This work presents new constraints on the existence and the binding energy of a possible – bound state, the H-dibaryon, derived from – femtoscopic measurements by the ALICE collaboration. The results are obtained from a new measurement using the femtoscopy technique in pp collisions at √s = 13 TeV and p–Pb collisions at √sNN = 5.02 TeV, combined with previously published results from pp collisions at √s = 7 TeV. The – scattering parameter space, spanned by the inverse scattering length f −1 0 and the effective range d0, is constrained by comparing the measured – correlation function with calculations obtained within the LednickĂœ model. The data are compatible with hypernuclei results and lattice computations, both predicting a shallow attractive interaction, and permit to test different theoretical approaches describing the – interaction. The region in the (f −1 0 ,d0) plane which would accommodate a – bound state is substantially restricted compared to previous studies. The binding energy of the possible – bound state is estimated within an effective-range expansion approach and is found to be B = 3.2+1.6 −2.4(stat)+1.8 −1.0(syst) MeV

    Measuring KS0K± interactions using Pb–Pb collisions at √sNN=2.76 TeV

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    We present the first ever measurements of femtoscopic correlations between the K0 S and K± particles. The analysis was performed on the data from Pb–Pb collisions at √sNN = 2.76 TeV measured by the ALICE experiment. The observed femtoscopic correlations are consistent with final-state interactions proceeding via the a0(980) resonance. The extracted kaon source radius and correlation strength parameters for K0 SK− are found to be equal within the experimental uncertainties to those for K0 SK+. Comparing the results of the present study with those from published identical-kaon femtoscopic studies by ALICE, mass and coupling parameters for the a0 resonance are tested. Our results are also compatible with the interpretation of the a0 having a tetraquark structure instead of that of a diquar
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