Étude comparative de l’électrocoagulation et de la coagulation floculation vis-à-vis de la déstabilisation d’une émulsion d’huile de coupe

Ce travail a porté sur la déstabilisation d’une émulsion d’huile de coupe algérienne (Tasfalout 22/B) par électrocoagulation (EC) en batch en utilisant des électrodes de fer. L’efficacité du procédé est évaluée par la mesure de la turbidité. Une meilleure efficacité de déstabilisation est obtenue par une augmentation de la densité de courant de 50 à 350 A•m‑2 pour un temps d’électrolyse de 15 min et des concentrations en huile de coupe de 1 % (p/p), 2 % (p/p) et 4 %(p/p). Un rendement d’élimination en turbidité de 99 % a été obtenu pour une émulsion à 4 % (p/p), une densité de courant de 150 A•m‑2 et un temps d’électrolyse de 120 min.Le suivi de la cinétique de dissolution de l’électrode de fer sur une période de 120 minutes a montré qu’une même efficacité du procédé peut être obtenue par une diminution du temps d’électrolyse et une augmentation de la densité de courant.Une étude comparative des performances de l’électrocoagulation et de la coagulation-floculation au chlorure ferrique hydraté (FeCl3•6H2O), vis-à-vis de la déstabilisation d’une émulsion d’huile de coupe, a été réalisée. Elle a mis en évidence l’avantage de la coagulation-floculation pour l’émulsion à 1 % (p/p), pour les différentes densités de courant testées en électrocoagulation. Par contre, les rendements d’élimination pour les deux procédés sont sensiblement similaires pour les émulsions plus concentrées (2 % (p/p) et 4 % (p/p)), pour une densité de courant de 150 A•m‑2. Le pH des émulsions obtenu par les deux procédés après le traitement est différent. Le milieu reste alcalin dans l’électrocoagulation et il devient acide dans la coagulation floculation.This work focuses on the breakdown of an Algerian cutting oil emulsion (Tasfalout 22/B) by batch electrocoagulation (EC) using iron electrodes. The efficiency of the process was estimated from turbidity measurements. An improved efficiency of destabilization was obtained by increasing the current density from 50 to 350 A•m‑2, over an electrolysis time of 15 min and using cutting oil concentrations of 1% (w/w), 2% (w/w) and 4% (w/w). Monitoring of the kinetics of the electrode dissolution over a period of 120 min showed that a similar process efficiency was obtained by decreasing the electrolysis time and by increasing the current density. A 99% removal of turbidity was obtained for an emulsion of 4% (w/w) with a current density of 150 A•m‑2 and an electrolysis time of 120 min.A comparison of the performances of electrocoagulation and of coagulation-flocculation with hydrated ferric chloride (FeCl3•6H2O) processes was carried out, with respect to the destabilization of cutting oil emulsion. This comparison highlighted the advantage of the coagulation-flocculation process for the of 1% (w/w) emulsion at different electrocoagulation current densities. However, for a current density of 150 A•m‑2, the removal efficiency of both processes was similar for the emulsion with higher cutting oil concentrations (2% (w/w) and 4% (w/w)). The pH of the emulsion obtained by the two processes following treatment varied. The medium remained alkaline during the electrocoagulation process and became acidic during the coagulation-flocculation process

A Classification Table for Achondrites

Classifying chondrites is relatively easy and the criteria are well documented. It is based on mineral compositions, textural characteristics and more recently, magnetic susceptibility. It can be more difficult to classify achondrites, especially those that are very similar to terrestrial igneous rocks, because mineralogical, textural and compositional properties can be quite variable. Achondrites contain essentially olivine, pyroxenes, plagioclases, oxides, sulphides and accessory minerals. Their origin is attributed to differentiated parents bodies: large asteroids (Vesta); planets (Mars); a satellite (the Moon); and numerous asteroids of unknown size. In most cases, achondrites are not eye witnessed falls and some do not have fusion crust. Because of the mineralogical and magnetic susceptibility similarity with terrestrial igneous rocks for some achondrites, it can be difficult for classifiers to confirm their extra-terrestrial origin. We -as classifiers of meteorites- are confronted with this problem with every suspected achondrite we receive for identification. We are developing a "grid" of classification to provide an easier approach for initial classification. We use simple but reproducible criteria based on mineralogical, petrological and geochemical studies. We presented the classes: acapulcoites, lodranites, winonaites and Martian meteorites (shergottite, chassignites, nakhlites). In this work we are completing the classification table by including the groups: angrites, aubrites, brachinites, ureilites, HED (howardites, eucrites, and diogenites), lunar meteorites, pallasites and mesosiderites. Iron meteorites are not presented in this abstract

The Meteoritical Bulletin, No. 92, 2007 September

Abstract— In this edition of The Meteoritical Bulletin, 1394 recognized meteorites are reported, 27 from specific locations within Africa, 133 from Northwest Africa, 1227 from Antarctica (from ANSMET, PNRA, and PRIC expeditions), and 7 from Asia. The Meteoritical Bulletin announces the approval of four new names series by the Nomenclature Committee of the Meteoritical Society, two from Africa and one from Asia, including Al Haggounia, from Al Haggounia, Morocco, which is projected to be on the order of 3 metric tons of material related to enstatite chondrites and aubrites. Approved are two falls from Africa, Bassikounou (Mauritania) and Gashua (Nigeria). Approved from areas other than Antarctica are one lunar, two Martian, 32 other achondrites, three mesosiderites, two pallasites, one CM, two CK, one CR2, two CV3, one CR2, and four R chondrites. The Nomenclature Committee of the Meteoritical Society announces 48 newly approved relict meteorites from two new name series, Österplana and Gullhögen (both from Sweden)

Terrestrial exposure of a fresh Martian meteorite causes rapid changes in hydrogen isotopes and water concentrations

Determining the hydrogen isotopic compositions and H2O contents of meteorites and their components is important for addressing key cosmochemical questions about the abundance and source(s) of water in planetary bodies. However, deconvolving the effects of terrestrial contamination from the indigenous hydrogen isotopic compositions of these extraterrestrial materials is not trivial, because chondrites and some achondrites show only small deviations from terrestrial values such that even minor contamination can mask the indigenous values. Here we assess the effects of terrestrial weathering and contamination on the hydrogen isotope ratios and H2O contents of meteoritic minerals through monitored terrestrial weathering of Tissint, a recent Martian fall. Our findings reveal the rapidity with which this weathering affects nominally anhydrous phases in extraterrestrial materials, which illustrates the necessity of sampling the interiors of even relatively fresh meteorite falls and underlines the importance of sample return missions

Cold-Atmospheric Plasma Induces Tumor Cell Death in Preclinical In Vivo and In Vitro Models of Human Cholangiocarcinoma

Through the last decade, cold atmospheric plasma (CAP) has emerged as an innovative therapeutic option for cancer treatment. Recently, we have set up a potentially safe atmospheric pressure plasma jet device that displays antitumoral properties in a preclinical model of cholangiocarcinoma (CCA), a rare and very aggressive cancer emerging from the biliary tree with few efficient treatments. In the present study, we aimed at deciphering the molecular mechanisms underlying the antitumor effects of CAP towards CCA in both an in vivo and in vitro context. In vivo, using subcutaneous xenografts into immunocompromised mice, CAP treatment of CCA induced DNA lesions and tumor cell apoptosis, as evaluated by 8-oxoguanine and cleaved caspase-3 immunohistochemistry, respectively. The analysis of the tumor microenvironment showed changes in markers related to macrophage polarization. In vitro, the incubation of CCA cells with CAP-treated culture media (i.e., plasma-activated media, PAM) led to a dose response decrease in cell survival. At molecular level, CAP treatment induced double-strand DNA breaks, followed by an increased phosphorylation and activation of the cell cycle master regulators CHK1 and p53, leading to cell cycle arrest and cell death by apoptosis. In conclusion, CAP is a novel therapeutic option to consider for CCA in the future

LANDSLIDE SUSCEPTIBILITY MAPPING IN THE MUNICIPALITY OF OUDKA, NORTHERN MOROCCO: A COMPARISON BETWEEN LOGISTIC REGRESSION AND ARTIFICIAL NEURAL NETWORKS MODELS

The Rif is among the areas of Morocco most susceptible to landslides, because of the existence of relatively young reliefs marked by a very important dynamics compared to other regions. These landslides are one of the most serious problems on many levels: social, economic and environmental. The increase in the frequency and impact of landslides over the past decade has demonstrated the need for an in-depth study of these phenomena, allowing the identification of areas susceptible to landslides. The main objective of this study is to identify the optimal method for the mapping of the area susceptible to landslides in municipality of Oudka. This area has been marked by the largest landslide in the region, caused by heavy rainfall in 2013. Two Statistical Methods i) Regression Logistics (LR) ii) Artificial Neural Networks (ANN), were used to create a landslide susceptibility map. The realization of this susceptibility map required, first, the mapping of old landslides by the aerial photography, the data of the geological map and by the data obtained using field surveys using GPS. A total of 105 landslides were mapped from these various sources. 50% of this database was used for model building and 50% for validation. Eight independent landslide factors are exploited to detect the most sensitive areas: altitude, slope, aspect, distance of faults, distance streams, distance from roads, lithology and vegetation index (NDVI). The results of the landslide susceptibility analysis were verified using success and prediction rates. The success rate (AUC&thinsp;=&thinsp;0.918) and the prediction rate (AUC&thinsp;=&thinsp;0.901) of the LR model is higher than that of the ANN model (success rate (AUC&thinsp;=&thinsp;0.886) and prediction rate (AUC&thinsp;=&thinsp;0.877). These results indicate that the Regression Logistic (LR) model is the best model for determining landslide susceptibility in the study area.</p

Lack of CC chemokine ligand 2 differentially affects inflammation and fibrosis according to the genetic background in a murine model of steatohepatitis

Expression of CCL2 (CC chemokine ligand 2) (or monocyte chemoattractant protein-1) regulates inflammatory cell infiltration in the liver and adipose tissue, favouring steatosis. However, its role in the pathogenesis of steatohepatitis is still uncertain. In the present study, we investigated the development of non-alcoholic steatohepatitis induced by an MCD diet (methionine/choline-deficient diet) in mice lacking the CCL2 gene on two different genetic backgrounds, namely Balb/C and C57/Bl6J. WT (wild-type) and CCL2-KO (knockout) mice were fed on a lipid-enriched MCD diet or a control diet for 8 weeks. In Balb/C mice fed on the MCD diet, a lack of CCL2 was associated with lower ALT (alanine transaminase) levels and reduced infiltration of inflammatory cells, together with a lower generation of oxidative-stress-related products. Sirius Red staining demonstrated pericellular fibrosis in zone 3, and image analysis showed a significantly lower matrix accumulation in CCL2-KO mice. This was associated with reduced hepatic expression of TGF-β (transforming growth factor-β), type I procollagen, TIMP-1 (tissue inhibitor of metalloproteinases-1) and α-smooth muscle actin. In contrast, in mice on a C57Bl/6 background, neither ALT levels nor inflammation or fibrosis were significantly different comparing WT and CCL2-KO animals fed on an MCD diet. In agreement, genes related to fibrogenesis were expressed to comparable levels in the two groups of animals. Comparison of the expression of several genes involved in inflammation and repair demonstrated that IL (interleukin)-4 and the M2 marker MGL-1 (macrophage galactose-type C-type lectin 1) were differentially expressed in Balb/C and C57Bl/6 mice. No significant differences in the degree of steatosis were observed in all groups of mice fed on the MCD diet. We conclude that, in experimental murine steatohepatitis, the effects of CCL2 deficiency are markedly dependent on the genetic background

Effects of shock and Martian alteration on Tissint hydrogen isotope ratios and water content

publisher: Elsevier articletitle: Effects of shock and Martian alteration on Tissint hydrogen isotope ratios and water content journaltitle: Geochimica et Cosmochimica Acta articlelink: http://dx.doi.org/10.1016/j.gca.2016.12.035 content_type: article copyright: © 2017 The Authors. Published by Elsevier Ltd.© 2017 The Authors. Published by Elsevier Ltd. This is an open access article, available to all readers online, published under a creative commons licensing (https://creativecommons.org/licenses/by/4.0/). The attached file is the published version of the article

A Global Fireball Observatory

The world's meteorite collections contain a very rich picture of what the early Solar System would have been made of, however the lack of spatial context with respect to their parent population for these samples is an issue. The asteroid population is equally as rich in surface mineralogies, and mapping these two populations (meteorites and asteroids) together is a major challenge for planetary science. Directly probing asteroids achieves this at a high cost. Observing meteorite falls and calculating their pre-atmospheric orbit on the other hand, is a cheaper way to approach the problem. The Global Fireball Observatory (GFO) collaboration was established in 2017 and brings together multiple institutions (from Australia, USA, Canada, Morocco, Saudi Arabia, the UK, and Argentina) to maximise the area for fireball observation time and therefore meteorite recoveries. The members have a choice to operate independently, but they can also choose to work in a fully collaborative manner with other GFO partners. This efficient approach leverages the experience gained from the Desert Fireball Network (DFN) pathfinder project in Australia. The state-of-the art technology (DFN camera systems and data reduction) and experience of the support teams is shared between all partners, freeing up time for science investigations and meteorite searching. With all networks combined together, the GFO collaboration already covers 0.6% of the Earth's surface for meteorite recovery as of mid-2019, and aims to reach 2% in the early 2020s. We estimate that after 5 years of operation, the GFO will have observed a fireball from virtually every meteorite type. This combined effort will bring new, fresh, extra-terrestrial material to the labs, yielding new insights about the formation of the Solar System.Comment: Accepted in PSS. 19 pages, 9 figure