97 research outputs found
An experimental study of charge distribution in crystalline and amorphous Si nanoclusters in thin silica films
Spontaneous alloying in binary metal microclusters - A molecular dynamics study -
Microcanonical molecular dynamics study of the spontaneous alloying(SA),
which is a manifestation of fast atomic diffusion in a nano-sized metal
cluster, is done in terms of a simple two dimensional binary Morse model.
Important features observed by Yasuda and Mori are well reproduced in our
simulation. The temperature dependence and size dependence of the SA phenomena
are extensively explored by examining long time dynamics. The dominant role of
negative heat of solution in completing the SA is also discussed. We point out
that a presence of melting surface induces the diffusion of core atoms even if
they are solid-like. In other words, the {\it surface melting} at substantially
low temperature plays a key role in attaining the SA.Comment: 15 pages, 12 fgures, Submitted to Phys.Rev.
Generalised Pose Estimation Using Depth
Estimating the pose of an object, be it articulated, deformable or rigid, is an important task, with applications ranging from Human-Computer Interaction to environmental understanding. The idea of a general pose estimation framework, capable of being rapidly retrained to suit a variety of tasks, is appealing. In this paper a solution isproposed requiring only a set of labelled training images in order to be applied to many pose estimation tasks. This is achieved bytreating pose estimation as a classification problem, with particle filtering used to provide non-discretised estimates. Depth information extracted from a calibrated stereo sequence, is used for background suppression and object scale estimation. The appearance and shape channels are then transformed to Local Binary Pattern histograms, and pose classification is performed via a randomised decision forest. To demonstrate flexibility, the approach is applied to two different situations, articulated hand pose and rigid head orientation, achieving 97% and 84% accurate estimation rates, respectively
ATP synthase: evolution, energetics, and membrane interactions
The synthesis of ATP, life's 'universal energy currency', is the most
prevalent chemical reaction in biological systems, and is responsible for
fueling nearly all cellular processes, from nerve impulse propagation to DNA
synthesis. ATP synthases, the family of enzymes that carry out this endless
task, are nearly as ubiquitous as the energy-laden molecule they are
responsible for making. The F-type ATP synthase (F-ATPase) is found in every
domain of life, and is believed to predate the divergence of these lineages
over 1.5 billion years ago. These enzymes have therefore facilitated the
survival of organisms in a wide range of habitats, ranging from the deep-sea
thermal vents to the human intestine. In this review, we present an overview of
the current knowledge of the structure and function of F-type ATPases,
highlighting several adaptations that have been characterized across taxa. We
emphasize the importance of studying these features within the context of the
enzyme's particular lipid environment: Just as the interactions between an
organism and its physical environment shape its evolutionary trajectory,
ATPases are impacted by the membranes within which they reside. We argue that a
comprehensive understanding of the structure, function, and evolution of
membrane proteins -- including ATP synthase -- requires such an integrative
approach.Comment: Review article; 29 pages, 6 figures/1 tabl
Effects of oxygen concentration on the proliferation and differentiation of mouse neural stem cells in vitro.
BACKGROUND AND PURPOSE: Cerebral ischemia is known to elicit the activation of neural stem cells (NSCs); however its mechanism is not fully determined. Although oxygen concentration is known to mediate many ischemic actions, there has been little attention given to the role of pathological oxygen changes under cerebral ischemia on the activation of NSCs. We investigated the effects of various oxygen concentrations on mouse neural stem cells in vitro. METHODS: NSCs were cultured from the ganglionic eminence of fetal ICR mice on embryonic day 15.5 using a neurosphere method. The effects of oxygen concentrations on proliferation, differentiation, and cell death of NSCs were evaluated by bromodeoxyuridine (BrdU) incorporation, immunocytochemistry, and TUNEL assay, respectively. RESULTS: The highest proliferation and the neuronal differentiation of the NSCs were observed in 2% oxygen, which yielded significantly higher proportions of both BrdU-labeled cells and Tuj1-positive cells when compared with 20% and 4% oxygen. On the other hand, the differentiation to the astrocytes was not affected by oxygen concentrations, except in the case of anoxia (0% oxygen). The cell death of the NSCs increased in lower oxygen conditions and peaked at anoxia. Furthermore, the switching of the neuronal subtype differentiation from GABA-positive to glutamate-positive neurons was observed in lower oxygen conditions. CONCLUSIONS: These findings raise the possibility that reduced oxygen levels occurring with cerebral ischemia enhance NSC proliferation and neural differentiation, and that mild hypoxia (2% oxygen), which is known to occur in the ischemic penumbra, is suitable for abundant neuronal differentiation
Electronic structure, magnetic properties, and microstructural analysis of thiol-functionalized Au nanoparticles: role of chemical and structural parameters in the ferromagnetic behaviour
Effect of H2O and SO2 on the activity of Pd/TiO2 catalysts in catalytic reduction of NO with methane in the presence of oxygen
Effect of H2O and SO2 on the NO reduction activity of the Pd/titania catalysts was examined in the NO+CH4+O-2 reaction. Steady-state and transient response experiments were performed using a tubular flow reactor. Isotopically labeled methane, (CH4)-C-13, was used in studying the transient behavior of the catalytic system. Reactor effluents were analyzed by using gas chromatography, mass spectrometry, and chemiluminescense techniques. Steady-state reaction experiments showed that the catalyst has a high activity for reduction of NO over a wide oxygen concentration range (0-9800 ppm at 500 degrees C). Higher N-2 selectivities (less NH3) and higher methane conversion values were obtained at higher O-2 concentrations. Experiments also showed that NO conversion was not affected by the presence of water (up to 6%), and higher nitrogen selectivities were obtained at higher H2O concentrations in the feed. On the other hand, significant and irreversible loss of activity was observed in the presence of SO2. The reaction experiments indicated the formation of SO3 and H2S over the catalyst. The post-reaction XPS analysis of the catalyst samples showed that sulfate species were formed on the surface and that the surface palladium was completely converted to pd(2+) State after being exposed to SO2
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