Photoluminescence properties of zinc white

Zinc white pigment has characterized artist’s palettes from the end of the eighteenth century up the twentieth century. It thus belongs to the modern pigments which were industrially produced by inorganic material (ZnO). This new category of pictorial materials interested conservators and scientists mainly for its behavour with aging. For this reason, this work focuses on the understanding of photo-physical behaviour of zinc white based on a time-resolved analysis of photoluminescence emission of historical samples. This study allowed the characterization of the decay kinetic properties of photoluminescence emissions. All historical samples showed near-band-edge and trap state emissions, typically occurring in semiconductors, that were modified by the interaction of the pigment with the surrounding organic binding material. The study further suggests that zinc carboxylates, detected in all historical samples, could be responsible for changes in emission mechanisms. Generally, data demonstrates how time-resolved photoluminescence spectroscopy is a powerful method for elucidating the nature of the mechanism processes in luminescent semiconductor pigments

Using Evidence-Based Criteria for Block Grant Funding of Collaborative Time for Educator Professional Development

This report was prepared by the Maine Education Policy Research Institute (MEPRI) at the request of the Maine State Legislature to provide recommendations for the development of a block grant program of supplemental funding to school districts to support evidence-based professional development for educators and/ or leaders or instructional coaching support in schools and classrooms. The report provides guidance to inform decisions on pending legislation, LD 1394, “An Act to Implement the Recommendations of the Commission to Strengthen the Adequacy and Equity of Certain Cost Components of the School Funding Formula”. The report builds on an earlier MEPRI report which reviewed the most rigorous empirical research literature on educator professional development, and uses the evidence-based findings to recommend criteria for a block grant funding program. Specifically, this report: 1) identifies evidence-based characteristics of effective professional development and criteria for evaluating block grants applications, 2) suggests possible funding priorities for awarding grants based on school district attributes, and 3) suggests evaluation measures that grant recipients could report annually as a requirement of continued funding. In addition, the report provides findings from data collected through a focus group with 12 curriculum coordinators/ school districts from the Penobscot region around professional development supports needed to implement proficiency-based education. Finally, the authors discuss some broader considerations for policy and suggest that more work is needed to develop a coherent infrastructure for educator professional development in Maine and support for the use of evidence-based practices and effective implementation at the local level

On the photoluminescence changes induced by ageing processes on zinc white paints

Recent research is focusing on the study of interaction mechanisms between pigments and binders, as they are crucial for understanding paint ageing and conservation issues. In this work, we investigate these mechanisms and follow the changes induced by ageing on zinc white paint by employing Fourier Transform Infrared (FTIR) and Time-Resolved Photoluminescence (TRPL) spectroscopies. The two techniques, applied on thermally aged mock-up samples and on a 19th oil painting, provide complementary information on the effect of the binder on the ZnO pigment particles. The characterization of the infrared absorption spectra confirms the well-known tendency of amorphous metal carboxylate formation in zinc white paint following ageing. At the same time, the ageing of paint film produces significant changes in the photoluminescence emission from defect centres of ZnO. The emission that is mostly affected by the changes of the micro-environment is the blue band (430 nm) – associated with surface defects – whereas the green emission (530 nm) is stable. The results demonstrate that the evolution of the pigment-binder system has detectable consequences on the crystalline structure of the pigment particles and we speculate that the main cause of these modifications is the functionalization of the pigment particle surfaces. The possibility to follow crystal structure changes with time-resolved photoluminescence can thus support chemical studies on metal carboxylate formation and paint deterioration by providing information about pigment-binder interactions

An exploratory study for the noninvasive detection of metal soaps in paintings through Optical Coherence Tomography

The formation and growth of metal soaps is of interest in heritage science, as soaps have been linked to a range of alteration and degradation phenomena potentially affecting works of art. However, current approaches detect metal soaps mainly in an invasive way or only at a late formation stage when the metal soaps are formed on the surface of the artwork. In contrast, Optical Coherence Tomography (OCT) has been proven to be a very suitable tool to obtain subsurface morphological information of complex multi-layered systems, such as paintings, in a non-invasive way. In this work, the capability of detecting metal soaps with an 810 nm ultra-high resolution (UHR) OCT in a selection of real and mock-up samples has been explored with OCT virtual cross-section images complemented with invasive structural and chemical analysis (SEMEDX and ATR-FTIR spectroscopy and imaging). Although the visualization of metal soaps with OCT was evident in some samples, we also show that this is not always the case. In addition, the results of this work show that extra care is needed when interpreting OCT cross-section images to avoid the risk of misinterpreting features present in the paint stratigraphy

Is diet partly responsible for differences in COVID-19 death rates between and within countries?

Correction: Volume: 10 Issue: 1 Article Number: 44 DOI: 10.1186/s13601-020-00351-w Published: OCT 26 2020Reported COVID-19 deaths in Germany are relatively low as compared to many European countries. Among the several explanations proposed, an early and large testing of the population was put forward. Most current debates on COVID-19 focus on the differences among countries, but little attention has been given to regional differences and diet. The low-death rate European countries (e.g. Austria, Baltic States, Czech Republic, Finland, Norway, Poland, Slovakia) have used different quarantine and/or confinement times and methods and none have performed as many early tests as Germany. Among other factors that may be significant are the dietary habits. It seems that some foods largely used in these countries may reduce angiotensin-converting enzyme activity or are anti-oxidants. Among the many possible areas of research, it might be important to understand diet and angiotensin-converting enzyme-2 (ACE2) levels in populations with different COVID-19 death rates since dietary interventions may be of great benefit.Peer reviewe

Nrf2-interacting nutrients and COVID-19 : time for research to develop adaptation strategies

There are large between- and within-country variations in COVID-19 death rates. Some very low death rate settings such as Eastern Asia, Central Europe, the Balkans and Africa have a common feature of eating large quantities of fermented foods whose intake is associated with the activation of the Nrf2 (Nuclear factor (erythroid-derived 2)-like 2) anti-oxidant transcription factor. There are many Nrf2-interacting nutrients (berberine, curcumin, epigallocatechin gallate, genistein, quercetin, resveratrol, sulforaphane) that all act similarly to reduce insulin resistance, endothelial damage, lung injury and cytokine storm. They also act on the same mechanisms (mTOR: Mammalian target of rapamycin, PPAR gamma:Peroxisome proliferator-activated receptor, NF kappa B: Nuclear factor kappa B, ERK: Extracellular signal-regulated kinases and eIF2 alpha:Elongation initiation factor 2 alpha). They may as a result be important in mitigating the severity of COVID-19, acting through the endoplasmic reticulum stress or ACE-Angiotensin-II-AT(1)R axis (AT(1)R) pathway. Many Nrf2-interacting nutrients are also interacting with TRPA1 and/or TRPV1. Interestingly, geographical areas with very low COVID-19 mortality are those with the lowest prevalence of obesity (Sub-Saharan Africa and Asia). It is tempting to propose that Nrf2-interacting foods and nutrients can re-balance insulin resistance and have a significant effect on COVID-19 severity. It is therefore possible that the intake of these foods may restore an optimal natural balance for the Nrf2 pathway and may be of interest in the mitigation of COVID-19 severity

Cabbage and fermented vegetables : From death rate heterogeneity in countries to candidates for mitigation strategies of severe COVID-19

Large differences in COVID-19 death rates exist between countries and between regions of the same country. Some very low death rate countries such as Eastern Asia, Central Europe, or the Balkans have a common feature of eating large quantities of fermented foods. Although biases exist when examining ecological studies, fermented vegetables or cabbage have been associated with low death rates in European countries. SARS-CoV-2 binds to its receptor, the angiotensin-converting enzyme 2 (ACE2). As a result of SARS-CoV-2 binding, ACE2 downregulation enhances the angiotensin II receptor type 1 (AT(1)R) axis associated with oxidative stress. This leads to insulin resistance as well as lung and endothelial damage, two severe outcomes of COVID-19. The nuclear factor (erythroid-derived 2)-like 2 (Nrf2) is the most potent antioxidant in humans and can block in particular the AT(1)R axis. Cabbage contains precursors of sulforaphane, the most active natural activator of Nrf2. Fermented vegetables contain many lactobacilli, which are also potent Nrf2 activators. Three examples are: kimchi in Korea, westernized foods, and the slum paradox. It is proposed that fermented cabbage is a proof-of-concept of dietary manipulations that may enhance Nrf2-associated antioxidant effects, helpful in mitigating COVID-19 severity.Peer reviewe

Recent advances in protective coatings for cultural heritage-an overview

In the last decades, the interest in the development of protective coatings for movable and immovable Cultural Heritage (CH) assets has decidedly increased. This has been mainly prompted by the raising consciousness on preservation requirements for cultural artefacts and monuments, which has consequently determined the development of new protective products. From acrylic resins used at the end of the last century to the up-to-date biomaterials and nanoparticles employed nowadays, the research has made a giant step forward. This article reviews the progresses, the technical challenges, and the most recent advances in protective coatings for archaeological metal, glass, and stone artefacts. It aims at offering a comprehensive and critical overview of the progressions in conservation science and displaying how research has optimized polymers in order to solve deterioration problems. Attention is given to recently developed materials, hybrid coatings, and corrosion inhibitors. This work seeks to provide a reference point for future research and to offer a wide-ranging introduction on the newly available material technologies to restorers and conservators

Experimental study on the link between optical emission, crystal defects and photocatalytic activity of artist pigments based on zinc oxide

The historical knowledge inherited from house paint documents and the experimental research on synthetic pigments show that production methods have an important role in the performance of paint. In this regard, this work investigates the links existing between the optical emission, crystal defects and photocatalytic activity of zinc white pigment from different contemporary factories, with the aim of elucidating the effects of these characteristics onto the tendency of the pigment to induce paint failures. The analysed samples display highly similar crystallite structure, domain size, and specific surface area, whilst white pigments differ from pure ZnO in regards to the presence of zinc carbonate hydrate that is found as a foreign compound. In contrast, the photoluminescence measurements categorize the analysed samples into two groups, which display different trap-assisted emissions ascribed to point crystal defects introduced during the synthesis process, and associated to Zn or O displacement. The photocatalytic degradation tests infer that the emerged defective structure and specific surface area of ZnO-based samples influence their tendency to oxidize organic molecules under light irradiation. In particular, the results indicate that the zinc interstitial defects may be able to promote the photogenerated electron-hole couples separation with a consequent increase of the overall ZnO photocatalytic activity, negatively affecting the binding medium stability. This groundwork paves the way for further studies on the link between the photoluminescence emission of the zinc white pigment and its tendency to decompose organic components contained in the binding medium

Beam-Shape Effects and Noise Removal From THz Time-Domain Images in Reflection Geometry in the 0.25 - 6 THz Range

The increasing need of restoring high-resolution hyper-spectral (HS) images is determining a growing reliance on computer vision-based processing to enhance the clarity of the image content. HS images can, in fact, suffer from degradation effects or artefacts caused by instrument limitations. This article focuses on a procedure aimed at reducing the degradation effects, frequency-dependent blur and noise, in Terahertz time-domain spectroscopy (THz-TDS) images in reflection geometry. It describes the application of a joint deblurring and denoising approach that had been previously proved to be effective for the restoration of THz-TDS images in transmission geometry, but that had never been tested in reflection modality. This mode is often the only one that can be effectively used in most cases, for example, when analyzing objects that are either opaque in the THz range, or that cannot be displaced from their location (e.g., museums), such as those of cultural interest. Compared to transmission mode, reflection geometry introduces, however, further distortion to THz data, usually neglected in existing literature. In this work, we successfully implement image deblurring and denoising of both uniform-shape samples (a contemporary 1 Euro cent coin and an inlaid pendant) and samples with the uneven reliefs and corrosion products on the surface, which make the analysis of the object particularly complex (an ancient Roman silver coin). The study demonstrates the ability of image processing to restore data in the 0.25–6 THz range, spanning over more than four octaves, and providing the foundation for future analytical approaches of cultural heritage using the far-infrared spectrum still not sufficiently investigated in the literature