35 research outputs found

    Flexible jobshop scheduling problem with resource recovery constraints.

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    Objectives and methods of study: The general objective of this research is to study a scheduling problem found in a local brewery. The main problem can be seen as a parallel machine batch scheduling problem with sequence-dependent setup times, resource constraints, precedence relationships, and capacity constraints. In the first part of this research, the problem is characterized as a Flexible Job-shop Scheduling Problem with Resource Recovery Constraints. A mixed integer linear formulation is proposed and a large set of instances adapted from the literatura of the Flexible Job-shop Scheduling Problem is used to validate the model. A solution procedure based on a General Variable Neighborhood Search metaheuristic is proposed, the performance of the procedure is evaluated by using a set of instances adapted from the literature. In the second part, the real problem is addressed. All the assumptions and constraints faced by the decision maker in the brewery are taken into account. Due to the complexity of the problem, no mathematical formulation is presented, instead, a solution method based on a Greedy Randomize Adaptive Search Procedure is proposed. Several real instances are solved by this algorithm and a comparison is carried out between the solutions reported by our GRASP and the ones found through the procedure followed by the decision maker. The computational results reveal the efficiency of our method, considering both the processing time and the completion time of the scheduling. Our algorithm requires less time to generate the production scheduling (few seconds) while the decision maker takes a full day to do it. Moreover, the completion time of the production scheduling generated by our algorithm is shorter than the one generated through the process followed by the decision maker. This time saving leads to an increase of the production capacity of the company. Contributions: The main contributions of this thesis can be summarized as follows: i) the introduction of a variant of the Flexible Job-shop Scheduling Problem, named as the Flexible Job-shop Scheduling Problem with Resource Recovery Constraints (FRRC); ii) a mixed integer linear formulation and a General Variable Neighborhood Search for the FRRC; and iii) a case study for which a Greedy Randomize Adaptive Search Procedure has been proposed and tested on real and artificial instances. The main scientific products generated by this research are: i) an article already published: SÃĄenz-Alanís, CÃĐsar A., V. D. Jobish, M. AngÃĐlica Salazar-Aguilar, and Vincent Boyer. “A parallel machine batch scheduling problem in a brewing company”. The International Journal of Advanced Manufacturing Technology 87, no. 1-4 (2016): 65-75. ii) another article submitted to the International Journal of Production Research for its possible publication; and iii) Scientific presentations and seminars

    Carbon Nanotubes Reinforced Natural Rubber Composites

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    Several advanced methods have been introduced to disperse CNTs in the NR matrix. Various aspects highlighted in this chapter include the mixing processes such as melt mixing and latex mixing methods. As well as, formations of functional groups on the surfaces of CNT using silane coupling agents (i.e., ex-situ and in-situ functionalization). Moreover, hybrid CNT are beneficial to achieve better electrical conductivity of NR/CNT composites. These efforts are aimed to reduce the percolation threshold concentration in the NR composites for application as conducting composites based on electrically insulating rubber matrix. Sensor application is developed based on conducting NR composites. NR composites showed changing of resistivity during elongation termed as piezoresistivity. The most commonly used rubber matrices such as NR, ENR and IR are mixed with a combination of CNT and CB fillers as hybrid filler. The presence of linkages in the ENR composites results in the least loss of conductivity during external strain. It is found that the conductivity becomes stable after 3000 cycles. This is found to be similar to the NR-CNT/CB composite, while a few cycles are needed for IR-CNT/CB owing to the higher filler agglomeration and poor filler-rubber interactions. This is attributed to the polar chemical interactions between ENR and the functional groups on the surfaces of CNT/CB

    Towards Industry 5.0: Intelligent Reflecting Surface (IRS) in smartmanufacturing

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    Industry 5.0 envisions close cooperation between humans and machines requiring ultra-reliable and low latency communications (URLLC). The Intelligent Reflecting Surface (IRS) has the potential to play a crucial role in realizing wireless URLLC for Industry 5.0. IRS is forecast to be a key enabler of 6G wireless communication networks as it can significantly improve wireless network performance by creating a controllable radio environment. In this paper, we first provide an overview of IRS technology and then conceptualize the potential for IRS implementation in a future smart manufacturing environment to support the emergence of Industry 5.0 with a series of applications. Finally, to stimulate future research in this area, we discuss the strength, open challenges, and opportunities of IRS technology in modern smart manufacturing

    The effect of cross-linking on the molecular dynamics of the segmental and Îē Johari–Goldstein processes in polyvinylpyrrolidone-based copolymers

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    The effect of the cross-link density on the molecular dynamics of copolymers composed of vinylpyrrolidone (VP) and butyl acrylate (BA) was studied using differential scanning calorimetry (DSC) and dielectric relaxation spectroscopy (DRS). A single glass transition was detected by DSC measurements. The dielectric spectra exhibit conductive processes and three dipolar relaxations labeled as a, b and g in the decreasing order of temperatures. The cross-linker content affects both a and b processes, but the fastest g process is relatively unaffected. An increase of cross-linking produces a typical effect on the a process dynamics: (i) the glass transition temperature is increased, (ii) the dispersion is broadened, (iii) its strength is decreased and (iv) the relaxation times are increased. However, the b process, which possesses typical features of a pure Johari Goldstein relaxation, unexpectedly loses the intermolecular character for the highest cross-linker content.B.R.F., M.J.S., P.O.S. and M.C. gratefully acknowledge CICYT for grant MAT2012-33483. F.G. and J.M.G. acknowledge the Spanish Ministerio de Economia y Competitividad-FEDER (MAT2014-54137-R) and the Junta de Castilla y Leon (BU232U13).Redondo Foj, MB.; Sanchis SÃĄnchez, MJ.; Ortiz Serna, MP.; Carsí Rosique, M.; García, JM.; García, FC. (2015). The effect of cross-linking on the molecular dynamics of the segmental and Îē Johari–Goldstein processes in polyvinylpyrrolidone-based copolymers. Soft Matter. 11:7171-7180. https://doi.org/10.1039/c5sm00714cS7171718011V. BÞhler , Polyvinylpyrrolidone Excipients for Pharmaceuticals: Povidone, Crospovidone and Copovidone , Springer , Berlin , 2005Haaf, F., Sanner, A., & Straub, F. (1985). Polymers of N-Vinylpyrrolidone: Synthesis, Characterization and Uses. Polymer Journal, 17(1), 143-152. doi:10.1295/polymj.17.143Gallardo, A., Rocío Lemus, A., San RomÃĄn, J., Cifuentes, A., & Díez-Masa, J.-C. (1999). Micellar Electrokinetic Chromatography Applied to Copolymer Systems with Heterogeneous Distribution. Macromolecules, 32(3), 610-617. doi:10.1021/ma981144pDevine, D. M., & Higginbotham, C. L. (2005). Synthesis and characterisation of chemically crosslinked N-vinyl pyrrolidinone (NVP) based hydrogels. European Polymer Journal, 41(6), 1272-1279. doi:10.1016/j.eurpolymj.2004.12.022Devine, D. M., Devery, S. M., Lyons, J. G., Geever, L. M., Kennedy, J. E., & Higginbotham, C. L. (2006). Multifunctional polyvinylpyrrolidinone-polyacrylic acid copolymer hydrogels for biomedical applications. International Journal of Pharmaceutics, 326(1-2), 50-59. doi:10.1016/j.ijpharm.2006.07.008Jin, S., Gu, J., Shi, Y., Shao, K., Yu, X., & Yue, G. (2013). Preparation and electrical sensitive behavior of poly (N-vinylpyrrolidone-co-acrylic acid) hydrogel with flexible chain nature. European Polymer Journal, 49(7), 1871-1880. doi:10.1016/j.eurpolymj.2013.04.022Borns, M. A., Kalakkunnath, S., Kalika, D. S., Kusuma, V. A., & Freeman, B. D. (2007). Dynamic relaxation characteristics of crosslinked poly(ethylene oxide) copolymer networks: Influence of short chain pendant groups. Polymer, 48(25), 7316-7328. doi:10.1016/j.polymer.2007.10.020Qazvini, N. T., & Mohammadi, N. (2005). Dynamic mechanical analysis of segmental relaxation in unsaturated polyester resin networks: Effect of styrene content. Polymer, 46(21), 9088-9096. doi:10.1016/j.polymer.2005.06.118Cook, W. D., Scott, T. F., Quay-Thevenon, S., & Forsythe, J. S. (2004). Dynamic mechanical thermal analysis of thermally stable and thermally reactive network polymers. Journal of Applied Polymer Science, 93(3), 1348-1359. doi:10.1002/app.20569Viciosa, M. T., RouzÃĐ, N., Dionísio, M., & GÃģmez Ribelles, J. L. (2007). Dielectric and mechanical relaxation processes in methyl acrylate/tri-ethyleneglycol dimethacrylate copolymer networks. European Polymer Journal, 43(4), 1516-1529. doi:10.1016/j.eurpolymj.2007.01.043Jobish, J., Charoen, N., & Praveen, P. (2012). Dielectric properties and AC conductivity studies of novel NR/PVA full-interpenetrating polymer networks. Journal of Non-Crystalline Solids, 358(8), 1113-1119. doi:10.1016/j.jnoncrysol.2012.02.003Bekin, S., Sarmad, S., GÞrkan, K., Keçeli, G., & GÞrdağ, G. (2014). Synthesis, characterization and bending behavior of electroresponsive sodium alginate/poly(acrylic acid) interpenetrating network films under an electric field stimulus. Sensors and Actuators B: Chemical, 202, 878-892. doi:10.1016/j.snb.2014.06.051F. Kremer and A.SchÃķnhals , Broadband Dielectric Spectroscopy , Springer-Verlag , Berlin Heidelberg, New York , 2003Roland, C. M. (1994). Constraints on Local Segmental Motion in Poly(vinylethylene) Networks. Macromolecules, 27(15), 4242-4247. doi:10.1021/ma00093a027Patil, P. N., Rath, S. K., Sharma, S. K., Sudarshan, K., Maheshwari, P., Patri, M., â€Ķ Pujari, P. K. (2013). Free volumes and structural relaxations in diglycidyl ether of bisphenol-A based epoxy–polyether amine networks. Soft Matter, 9(13), 3589. doi:10.1039/c3sm27525fCasalini, R., & Roland, C. M. (2010). Effect of crosslinking on the secondary relaxation in polyvinylethylene. Journal of Polymer Science Part B: Polymer Physics, 48(5), 582-587. doi:10.1002/polb.21925Carsi, M., Sanchis, M. J., Diaz-Calleja, R., Riande, E., & Nugent, M. J. D. (2012). Effect of Cross-Linking on the Molecular Motions and Nanodomains Segregation in Polymethacrylates Containing Aliphatic Alcohol Ether Residues. Macromolecules, 45(8), 3571-3580. doi:10.1021/ma202811pCarsí, M., Sanchis, M. J., Díaz-Calleja, R., Riande, E., & Nugent, M. J. D. (2013). Effect of slight crosslinking on the mechanical relaxation behavior of poly(2-ethoxyethyl methacrylate) chains. European Polymer Journal, 49(6), 1495-1502. doi:10.1016/j.eurpolymj.2012.12.012Kalakkunnath, S., Kalika, D. S., Lin, H., Raharjo, R. D., & Freeman, B. D. (2007). Molecular Dynamics of Poly(ethylene glycol) and Poly(propylene glycol) Copolymer Networks by Broadband Dielectric Spectroscopy. Macromolecules, 40(8), 2773-2781. doi:10.1021/ma070016aSabater i Serra, R., Escobar Ivirico, J. L., Meseguer DueÃąas, J. M., Balado, A. A., GÃģmez Ribelles, J. L., & SalmerÃģn SÃĄnchez, M. (2009). Segmental dynamics in poly(Îĩ-caprolactone)/poly(L-lactide) copolymer networks. Journal of Polymer Science Part B: Polymer Physics, 47(2), 183-193. doi:10.1002/polb.21629Nogales, A., Sanz, A., Ezquerra, T. A., Quintana, R., & MuÃąoz-Guerra, S. (2006). Molecular dynamics of poly(butylene tert-butyl isophthalate) and its copolymers with poly(butylene terephthalate) as revealed by broadband dielectric spectroscopy. Polymer, 47(20), 7078-7084. doi:10.1016/j.polymer.2006.07.044Sanz, A., Nogales, A., Ezquerra, T. A., Lotti, N., & Finelli, L. (2004). Cooperativity of theÎē-relaxations in aromatic polymers. Physical Review E, 70(2). doi:10.1103/physreve.70.021502Johari, G. P., & Goldstein, M. (1970). Viscous Liquids and the Glass Transition. II. Secondary Relaxations in Glasses of Rigid Molecules. The Journal of Chemical Physics, 53(6), 2372-2388. doi:10.1063/1.1674335Johari, G. P., & Smyth, C. P. (1972). Dielectric Relaxation of Rigid Molecules in Supercooled Decalin. The Journal of Chemical Physics, 56(9), 4411-4418. doi:10.1063/1.1677882Paluch, M., Pawlus, S., Hensel-Bielowka, S., Kaminska, E., Prevosto, D., Capaccioli, S., â€Ķ Ngai, K. L. (2005). Two secondary modes in decahydroisoquinoline: Which one is the true Johari Goldstein process? The Journal of Chemical Physics, 122(23), 234506. doi:10.1063/1.1931669Ngai, K. L. (1998). Relation between some secondary relaxations and the Îą relaxations in glass-forming materials according to the coupling model. The Journal of Chemical Physics, 109(16), 6982-6994. doi:10.1063/1.477334Ngai, K. L., & Paluch, M. (2004). Classification of secondary relaxation in glass-formers based on dynamic properties. The Journal of Chemical Physics, 120(2), 857-873. doi:10.1063/1.1630295Casalini, R., Ngai, K. L., & Roland, C. M. (2003). Connection between the high-frequency crossover of the temperature dependence of the relaxation time and the change of intermolecular coupling in glass-forming liquids. Physical Review B, 68(1). doi:10.1103/physrevb.68.014201Ngai, K. L., & Tsang, K. Y. (1999). Similarity of relaxation in supercooled liquids and interacting arrays of oscillators. Physical Review E, 60(4), 4511-4517. doi:10.1103/physreve.60.4511Donth, E. (1996). Characteristic length of the glass transition. Journal of Polymer Science Part B: Polymer Physics, 34(17), 2881-2892. doi:10.1002/(sici)1099-0488(199612)34:173.0.co;2-uWilliams, G. (s. f.). Molecular aspects of multiple dielectric relaxation processes in solid polymers. Electric Phenomena in Polymer Science, 59-92. doi:10.1007/3-540-09456-3_3Ngai, K., & Capaccioli, S. (2004). Relation between the activation energy of the Johari-Goldstein Îē relaxation and T_{g} of glass formers. Physical Review E, 69(3). doi:10.1103/physreve.69.031501Casalini, R., & Roland, C. M. (2003). Pressure Evolution of the Excess Wing in a Type-BGlass Former. Physical Review Letters, 91(1). doi:10.1103/physrevlett.91.015702Redondo-Foj, B., Carsí, M., Ortiz-Serna, P., Sanchis, M. J., García, F., & García, J. M. (2013). Relaxational study of poly(vinylpyrrolidone-co-butyl acrylate) membrane by dielectric and dynamic mechanical spectroscopy. Journal of Physics D: Applied Physics, 46(29), 295304. doi:10.1088/0022-3727/46/29/295304Redondo-Foj, B., Carsí, M., Ortiz-Serna, P., Sanchis, M. J., Vallejos, S., García, F., & García, J. M. (2014). Effect of the Dipole–Dipole Interactions in the Molecular Dynamics of Poly(vinylpyrrolidone)-Based Copolymers. Macromolecules, 47(15), 5334-5346. doi:10.1021/ma500800aBershtein, V. A., Egorova, L. M., Yakushev, P. N., Pissis, P., Sysel, P., & Brozova, L. (2002). Molecular dynamics in nanostructured polyimide-silica hybrid materials and their thermal stability. Journal of Polymer Science Part B: Polymer Physics, 40(10), 1056-1069. doi:10.1002/polb.10162Alves, N. M., GÃģmez Ribelles, J. L., & Mano, J. F. (2005). Enthalpy relaxation studies in polymethyl methacrylate networks with different crosslinking degrees. Polymer, 46(2), 491-504. doi:10.1016/j.polymer.2004.11.016Scott, T. F., Cook, W. D., & Forsythe, J. S. (2002). Kinetics and network structure of thermally cured vinyl ester resins. European Polymer Journal, 38(4), 705-716. doi:10.1016/s0014-3057(01)00244-0Wagner, K. W. (1914). ErklÃĪrung der dielektrischen NachwirkungsvorgÃĪnge auf Grund Maxwellscher Vorstellungen. Archiv fÞr Elektrotechnik, 2(9), 371-387. doi:10.1007/bf01657322Hodge, I. M., Ngai, K. L., & Moynihan, C. T. (2005). Comments on the electric modulus function. Journal of Non-Crystalline Solids, 351(2), 104-115. doi:10.1016/j.jnoncrysol.2004.07.089Williams, G., & Watts, D. C. (1970). Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function. Transactions of the Faraday Society, 66, 80. doi:10.1039/tf9706600080Williams, G., Watts, D. C., Dev, S. B., & North, A. M. (1971). Further considerations of non symmetrical dielectric relaxation behaviour arising from a simple empirical decay function. Transactions of the Faraday Society, 67, 1323. doi:10.1039/tf9716701323Havriliak, S., & Negami, S. (1967). A complex plane representation of dielectric and mechanical relaxation processes in some polymers. Polymer, 8, 161-210. doi:10.1016/0032-3861(67)90021-3Havriliak, S., & Negami, S. (2007). A complex plane analysis of Îą-dispersions in some polymer systems. Journal of Polymer Science Part C: Polymer Symposia, 14(1), 99-117. doi:10.1002/polc.5070140111S. Havriliak and S.Negami , Dielectric and Mechanical Relaxation in Materials , Hanser , Munich , 1997 , p. 57Glatz-Reichenbach, J. K. W., Sorriero, L., & Fitzgerald, J. J. (1994). Influence of Crosslinking on the Molecular Relaxation of an Amorphous Copolymer Near Its Glass-Transition Temperature. Macromolecules, 27(6), 1338-1343. doi:10.1021/ma00084a010Cole, K. S., & Cole, R. H. (1941). Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics. The Journal of Chemical Physics, 9(4), 341-351. doi:10.1063/1.1750906Boyd, R. H. (1985). Relaxation processes in crystalline polymers: experimental behaviour — a review. Polymer, 26(3), 323-347. doi:10.1016/0032-3861(85)90192-2Laredo, E., Grimau, M., SÃĄnchez, F., & Bello, A. (2003). Water Absorption Effect on the Dynamic Properties of Nylon-6 by Dielectric Spectroscopy. Macromolecules, 36(26), 9840-9850. doi:10.1021/ma034954wHuo, P., & Cebe, P. (1992). Dielectric relaxation of poly(phenylene sulfide) containing a fraction of rigid amorphous phase. Journal of Polymer Science Part B: Polymer Physics, 30(3), 239-250. doi:10.1002/polb.1992.090300303Noda, N., Lee, Y.-H., Bur, A. J., Prabhu, V. M., Snyder, C. R., Roth, S. C., & McBrearty, M. (2005). Dielectric properties of nylon 6/clay nanocomposites from on-line process monitoring and off-line measurements. Polymer, 46(18), 7201-7217. doi:10.1016/j.polymer.2005.06.046Ryabov, Y. E., Nuriel, H., Marom, G., & Feldman, Y. (2002). Relaxation peak broadening and polymer chain dynamics in aramid-fiber-reinforced nylon-66 microcomposites. Journal of Polymer Science Part B: Polymer Physics, 41(3), 217-223. doi:10.1002/polb.10384Janik, P., Paluch, M., Ziolo, J., Sulkowski, W., & Nikiel, L. (2001). Low-frequency dielectric relaxation in rubber. Physical Review E, 64(4). doi:10.1103/physreve.64.042502Feldman, Y., Puzenko, A., & Ryabov, Y. (2002). Non-Debye dielectric relaxation in complex materials. Chemical Physics, 284(1-2), 139-168. doi:10.1016/s0301-0104(02)00545-1Ortiz-Serna, P., DiĖaz-Calleja, R., Sanchis, M. J., Floudas, G., Nunes, R. C., Martins, A. F., & Visconte, L. L. (2010). Dynamics of Natural Rubber as a Function of Frequency, Temperature, and Pressure. A Dielectric Spectroscopy Investigation. Macromolecules, 43(11), 5094-5102. doi:10.1021/ma1004869Ortiz-Serna, P., Díaz-Calleja, R., Sanchis, M. J., Riande, E., Nunes, R., Martins, A., & Visconte, L. (2011). Dielectric spectroscopy of natural rubber-cellulose II nanocomposites. Journal of Non-Crystalline Solids, 357(2), 598-604. doi:10.1016/j.jnoncrysol.2010.06.044E. Riande and R.Díaz-Calleja , Electrical Properties of Polymers , Marcel Dekker , New York , 2004Fulcher, G. S. (1925). ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES. Journal of the American Ceramic Society, 8(6), 339-355. doi:10.1111/j.1151-2916.1925.tb16731.xTammann, G., & Hesse, W. (1926). Die AbhÃĪngigkeit der ViscositÃĪt von der Temperatur bie unterkÞhlten FlÞssigkeiten. Zeitschrift fÞr anorganische und allgemeine Chemie, 156(1), 245-257. doi:10.1002/zaac.19261560121Lunkenheimer, P., Schneider, U., Brand, R., & Loid, A. (2000). Glassy dynamics. Contemporary Physics, 41(1), 15-36. doi:10.1080/001075100181259Angell, C. A. (1995). Formation of Glasses from Liquids and Biopolymers. Science, 267(5206), 1924-1935. doi:10.1126/science.267.5206.1924C. A. Angell , Complex Behavior of Glassy Systems; Proceedings of the XIV Sitges Conference , Sitges, Barcelona, Spain, 1996F. J. Bermejo , H. E.Fischer , M. A.Ramos , A.de AndrÃĐs , J.Dawidowski and V.Fayos , in Complex Behaviour of Glassy Systems , Springer Lecture Notes in Physics , ed. M. Rubí and C. PÃĐrez-Vicente , Springer , Berlin-Heidelberg , 1997BÃķhmer, R., Ngai, K. L., Angell, C. A., & Plazek, D. J. (1993). Nonexponential relaxations in strong and fragile glass formers. The Journal of Chemical Physics, 99(5), 4201-4209. doi:10.1063/1.466117BÃķhmer, R., & Angell, C. A. (1992). Correlations of the nonexponentiality and state dependence of mechanical relaxations with bond connectivity in Ge-As-Se supercooled liquids. Physical Review B, 45(17), 10091-10094. doi:10.1103/physrevb.45.10091BÃķhmer, R., & Angell, C. A. (1993). Elastic and viscoelastic properties of amorphous selenium and identification of the phase transition between ring and chain structures. Physical Review B, 48(9), 5857-5864. doi:10.1103/physrevb.48.5857Merino, E. G., Atlas, S., Raihane, M., Belfkira, A., Lahcini, M., Hult, A., â€Ķ Correia, N. T. (2011). Molecular dynamics of poly(ATRIF) homopolymer and poly(AN-co-ATRIF) copolymer investigated by dielectric relaxation spectroscopy. European Polymer Journal, 47(7), 1429-1446. doi:10.1016/j.eurpolymj.2011.04.006Angell, C. . (1991). Relaxation in liquids, polymers and plastic crystals — strong/fragile patterns and problems. Journal of Non-Crystalline Solids, 131-133, 13-31. doi:10.1016/0022-3093(91)90266-9Qin, Q., & McKenna, G. B. (2006). Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids. Journal of Non-Crystalline Solids, 352(28-29), 2977-2985. doi:10.1016/j.jnoncrysol.2006.04.014Kohlrausch, R. (1854). Theorie des elektrischen RÞckstandes in der Leidener Flasche. Annalen der Physik und Chemie, 167(2), 179-214. doi:10.1002/andp.18541670203Zorn, R. (1999). Applicability of distribution functions for the Havriliak-Negami spectral function. Journal of Polymer Science Part B: Polymer Physics, 37(10), 1043-1044. doi:10.1002/(sici)1099-0488(19990515)37:103.0.co;2-hNgai, K. L., & Roland, C. M. (1993). Intermolecular cooperativity and the temperature dependence of segmental relaxation in semicrystalline polymers. Macromolecules, 26(11), 2688-2690. doi:10.1021/ma00063a008K. L. Ngai , Relaxation and diffusion in complex systems , Springer , Berlin , 2011Ikeda, M., & Aniya, M. (2010). Correlation between fragility and cooperativity in bulk metallic glass-forming liquids. Intermetallics, 18(10), 1796-1799. doi:10.1016/j.intermet.2010.01.009Patkowski, A., Paluch, M., & Gapiński, J. (2003). Relationship between T0, Tg and their pressure dependence for supercooled liquids. Journal of Non-Crystalline Solids, 330(1-3), 259-263. doi:10.1016/j.jnoncrysol.2003.09.002Delpouve, N., Delbreilh, L., Stoclet, G., Saiter, A., & Dargent, E. (2014). Structural Dependence of the Molecular Mobility in the Amorphous Fractions of Polylactide. Macromolecules, 47(15), 5186-5197. doi:10.1021/ma500839

    Effect of Thermal Aging and Chemical Treatment on Tensile Properties of Coir Fiber

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    Effect of thermal aging and chemical treatment on the physical properties of coir fiber was investigated. Coir fibers were treated with sodium hydroxide and glutaraldehyde for 2 h. The influence of alkali and aldehyde treatment on tensile strength and elongation at break was studied in detail. Enhancement in tensile strength of coir fiber was observed up to five days of aging at 50°C and further decreased. Thermal cross linking of cellulose present in the fiber may be the reason for the increase in tensile strength and thermal degradation due to the chain scission of cellulose reduced the tensile strength. Sodium-hydroxide-treated samples showed an increase in tensile strength and reduction in elongation at break. The removal of impurities such as waxy and fatty acid residues from the coir fiber by reacting with strong base solution improved the strength of fiber. Cross linking of cellulose with glutaraldehyde in the fiber reduced the elasticity and enhances the strength of the material. Scanning electron microscopy was employed to analyze the change in surface morphology upon chemical treatment. Improvement in the tensile strength suggests that NaOH and glutaraldehyde can be effectively used to modify coir fiber with excellent physical properties
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