Biodegradability standards for carrier bags and plastic films in aquatic environments: a critical review

Plastic litter is encountered in aquatic ecosystems across the globe, including polar environments and the deep sea. To mitigate the adverse societal and ecological impacts of this waste, there has been debate on whether ‘biodegradable’ materials should be granted exemptions from plastic bag bans and levies. However, great care must be exercised when attempting to define this term, due to the broad and complex range of physical and chemical conditions encountered within natural ecosystems. Here, we review existing international industry standards and regional test methods for evaluating the biodegradability of plastics within aquatic environments (wastewater, unmanaged freshwater and marine habitats). We argue that current standards and test methods are insufficient in their ability to realistically predict the biodegradability of carrier bags in these environments, due to several shortcomings in experimental procedures and a paucity of information in the scientific literature. Moreover, existing biodegradability standards and test methods for aquatic environments do not involve toxicity testing or account for the potentially adverse ecological impacts of carrier bags, plastic additives, polymer degradation products or small (microscopic) plastic particles that can arise via fragmentation. Successfully addressing these knowledge gaps is a key requirement for developing new biodegradability standard(s) for lightweight carrier bags

Rationale for Replacement of the Destructive Test by Non-Destructive One in Medical Devices Manufacturing

Due to expanding demand for the level of testing on one side and reduction of costs on the other side, the question how to replace expensive destructive testing of medical devices without compromising the quality of final product arising urgently. This situation is common within all highly regulated industries - in this article is addressed the problem from medical device manufacturing industry. Based on real data containing testing and validation datasets, logit model and classification tree model are estimated for establishing the relationship between result of destructive test and measurements of explored device. Results point to possibility of replacing destructive test by non-destructive one in our case.O

Role of Titanium in Thin Wall Vermicular Graphite Iron Castings Production

In this paper the effects of titanium addition in an amount up to 0.13 wt.% have been investigated to determine their effect on the microstructure and mechanical properties of Thin Wall Vermicular Graphite Iron Castings (TWVGI). The study was performed for thinwalled iron castings with 3-5 mm wall thickness and for the reference casting with 13 mm. Microstructural changes were evaluated by analyzing quantitative data sets obtained by image analyzer and also using scanning electron microscope (SEM). Metallographic examinations show that in thin-walled castings there is a significant impact of titanium addition to vermicular graphite formation. Thinwalled castings with vermicular graphite have a homogeneous structure, free of chills, and good mechanical properties. It may predispose them as a potential use as substitutes for aluminum alloy castings in diverse applications

The Effect of Distribution on Product Temperature Profile in Thermally Insulated Containers for Express Shipments

An uninterrupted cold chain is a continual series of storage and distribution activities that maintain a specific temperature or temperature range. Cold chain solutions typically involve excessive packaging to ensure that the desired product temperature is maintained through the distribution process, thereby increasing the logistics-related costs. There is a myriad of solutions available for shipping temperature-sensitive products, including those constructed with a variety of packaging materials as well as refrigerants. Although static characteristics for thermally insulated packaging solutions such as the R-values of package systems as well as the melting points and heat absorption rates of various refrigerants have been studied in the past, none of the past studies have evaluated the effect of comprehensive distribution on the reliability of the cold chain packaging solutions. This research was undertaken to study the temperature profiles for factors such as different densities for a given thickness of thermally insulating material, wall thicknesses and distribution environments for four different types of materials—polyurethane, virgin expanded polystyrene, recycled content expanded polystyrene and vacuum-insulated panels. The temperature range of 2 °C–8 °C, critical for pharmaceutical drugs and vaccines, was targeted. An interesting regression-based finding was that the interaction between the R-value and the wall thickness significantly influenced the length of time the thermally insulated packages stayed in the desired range of 2 °C–8 °C . The findings of this study will be decisive in designing cost-efficient and practical single-use cold chain transportation solutions for temperature-sensitive products. Copyright © 2012 John Wiley & Sons, Ltd

Corrosion polarization behavior and microstructuralanalysis of AA1070 aluminium silicon carbide matrix composites in acid chloride concentrations

The effect of SiC content and NaCl concentration on the corrosion resistance of AA1070 aluminium in 2 M H2SO4 was evaluated with potentiodynamic polarization technique, open circuit potential measurement (OCP) and optical microscopy. Results showed SiC increased the corrosion susceptibility of the alloy at lower NaCl concentrations compared to results obtained at 0% NaCl which showed significant decrease in corrosion rates, with maximum inhibition efficiency of 90.84% at 20% SiC content. The corrosion rates decreased at higher NaCl concentration,with maximum inhibition efficiency of 94.12 and 77.27% at 20% SiC. Alloy samples in 2 M H2SO4/0% NaCl at 0 and 20% SiC visibly decreased in OCP value over wide variation compared to samples with varying NaCl concentration due to loss of passivity. OCP values for alloys at varying NaCl concentration decreased over a very short variation due to repassivation. Statistical data showed silicon carbide to be the only relevant variable responsible for the corrosion rate values with F-values of 8.85 corresponding to a percentage significance of 54.8%. Optical images showed the presence of corrosion pits of smaller dimension, yet deeper on the morphology of the alloy without silicon carbide compared the alloy containing it, whose corrosion pits, seems wider but very shallo

Aluminum slurry coatings to replace cadmium for aeronautic applications

Cadmium has been widely used as a coating to provide protection against galvanic corrosion for steels and for its natural lubricity on threaded applications. However, it is a toxic metal and a known carcinogenic agent, which is plated from an aqueous bath containing cyanide salts. For these reasons, the use of cadmium has been banned in Europe for most industrial applications. However, the aerospace industry is still exempt due to the stringent technical and safety requirements associated with aeronautical applications, as an acceptable replacement is yet to be found. Al slurry coatings have been developed as an alternative to replace cadmium coatings. The coatings were deposited on AISI 4340 steel and have been characterized by optical and electron microscopy. Testing included salt fog corrosion exposure, fluid corrosion exposure (immersion), humidity resistance, coating-substrate and paint-coating adhesion, electric conductivity, galvanic corrosion, embrittlement and fatigue. The results indicated that Al slurry coatings are an excellent alternative for Cd replacement

Influence of the microstructure on fatigue and fracture toughness properties of large heat-treated mold steels

The standard ISO 1.2738 medium-carbon low-alloy steel has long been used to fabricate plastic molds for injection molding of large automotive components, such as bumpers and dashboards. These molds are usually machined from large pre-hardened steel blooms. Due to the bloom size, the heat treatment yields mixed microstructures, continuously varying from surface to core. Negative events (such as microcracks due to improper weld bed deposition or incomplete extraction of already formed plastic objects) or too large thermal/mechanical stresses can conceivably cause mold failure during service due to the low fracture toughness and fatigue resistance typically encountered in large slack quenched and tempered ISO 1.2738 steel blooms. Alternative steel grades, including both non-standard microalloyed steels, designed for the same production process, and precipitation hardening steels, have recently been proposed by steelworks. However, the fracture toughness and the fatigue properties of these steels, and hence their response during the service, are not well known. Results of an experimental campaign to assess the fracture toughness and fatigue properties, as well as the basic mechanical properties, of a microalloyed and a precipitation hardening plastic mold steel blooms are presented and commented, also in respect to the results previously obtained by two commercial ISO 1.2738 ones. Experimental results show that these steels generally exhibit low fracture toughness values; in the traditional quenched and tempered bloom steels the brittleness may be caused both by the presence of mixed microstructures and by grain boundaries segregation, while in the precipitation hardened one the brittleness probably stems from the precipitation phenomena. This study suggests that microalloyed and precipitation hardening steels may be used to produce large plastic mold, yet the fracture toughness still remains the most critical propert

Sensory profiles of breast meat from broilers reared in an organic niche production system and conventional standard broilers

BACKGROUND: Breast meat from broilers produced in very different production systems may vary considerable in sensory profile, which may affect consumer interests. In this study the aim was to evaluate differences in the sensory profiles of breast meat from five broiler products: two conventional standard products (A and B) and three organic niche genotypes (I657, L40 and K8) reared in an apple orchard. RESULTS: Thirteen out of 22 sensory attributes differed significantly between the products. The aroma attributes ‘chicken’, ‘bouillon’ and ‘fat’ scored highest and the ‘iron/liver’ aroma lowest for the niche products. The meat was more ‘tender’, ‘short’ and ‘crumbly’ and less ‘hard’ and ‘stringy’ in the standard products than in one or more of the niche products. Product ‘I 657’ was less ‘juicy’ than the rest. Products ‘I 657’ and ‘L 40’ were more ‘cohesive’ and tasted more ‘sourish’ and less of ‘sweet/maize’ than the standard products. The ‘overall liking’ score was significantly higher for the ‘K 8’ product than for the ‘Standard A’ and ‘L 40’ products. The ‘overall liking’ score was significantly correlated with the scores for aroma and taste of ‘chicken’, ‘umami/bouillon’, ‘iron/liver’ and ‘fat’ aroma. CONCLUSION: The sensory profiles differed particularly between conventional standard broilers and organic niche broilers, although differences were also found between breeds. The present study indicates that aroma and taste attributes were more important for the assessors than meat ‘tenderness’ for the overall liking of broiler meat. �c 2011 Society of Chemical Industry

Experimental and numerical investigation of footing behaviour on multi-layered rubber-reinforced soil

This paper describes the beneficial effects of multiple layers of rubber–sand mixture (RSM). The plate load tests, using circular plate of 300 mm diameter, were performed at an outdoor test pit, dug in natural ground with dimensions of 2000 × 2000 mm in plan and 720 mm in depth to facilitate realistic test conditions. The rubber used in the RSM layers was granulated rubber, produced from waste tires. The optimum thickness of the RSM layer was determined to be approximately 0.4 times the footing diameter. By increasing the number of RSM layers, the bearing capacity of the foundation can be increased and the footing settlement reduced. The influence of the number of RSM layers on bearing capacity and settlement become almost insignificant beyond three layers of RSM, particularly at low settlement ratios. At a ratio of settlement to plate diameter of 4%, the values of bearing pressure for the installation with one, two, three and four layers of RSM were about 1.26, 1.47, 1.52 and 1.54 times greater, respectively, than that for the unreinforced installation. Layers of the RSM reduced the vertical stress transferred through the foundation depth by distributing the load over a wider area. For example, at an applied footing pressure of 560 kPa, the transferred pressure at a depth of 570 mm was about 58, 45 and 35% for one, two and three layers of RSM, respectively, compared to the transferred stress in the unreinforced bed. By numerical analysis, it was found that the presence of soil-rubber layers resulted in expansion of passive zones in the foundation due to the effectiveness of the confinement provided by the rubber inclusions, and this tends to make the bed deflect less. On the basis of this study, the concept of using multiple RSM layers has not only been shown to improve the performance of foundations under heavy loading, but also, the environmental impacts of waste tires are attenuated by re-using their rubber as part of a composite soil material in civil engineering works

A quick approach for rheological evaluation of warm asphalt binders using response surface method

This paper describes a quick approach for quantification of the effects of a chemical warm named Rediset, and its interactions with temperature and aging on the rheological properties of asphalt binders using Response Sur-face Method. The central composite method was applied to design experimental programs for three test temperature conditions, namely; very high temperature (120–180 °C), high temperature (46–82 °C), and intermediate temperature (19–31 °C). Rotational viscosity, G*/sin δ and G*sin δ were selected as parameters to assess the effects of the chemical warm additive on the rheological properties of asphalt binders for different aging conditions. Evaluation of the effects of this additive on the transformed value of G*/sin δ at high temperatures indicates that additive content has significant effect on Ln(G*/sin δ). The results for intermediate temperatures show that this additive has a positive effect on G*sin δ of asphalt binders