1,706 research outputs found
Enhanced Photoresponse of FeSâ Films: The Role of Marcasite-Pyrite Phase Junctions
The beneficial role of marcasite in iron-sulfide-based photo-electrochemical applications is reported for the first time. A spectacular improvement of the photoresponse observed experimentally for mixed pyrite/marcasite-FeS2 films can be ascribed to the presence of p/m phase junctions at the interface. Density functional theory calculations show that the band alignment at the phase boundary contributes to enhanced charge separation and transfer across the interface
Tubular structures of GaS
In this Brief Report we demonstrate, using density-functional tight-binding theory, that gallium sulfide (GaS) tubular nanostructures are stable and energetically viable. The GaS-based nanotubes have a semiconducting direct gap which grows towards the value of two-dimensional hexagonal GaS sheet and is in contrast to carbon nanotubes largely independent of chirality. We further report on the mechanical properties of the GaS-based nanotubes
Multiexcitons confined within a sub-excitonic volume: Spectroscopic and dynamical signatures of neutral and charged biexcitons in ultrasmall semiconductor nanocrystals
The use of ultrafast gating techniques allows us to resolve both spectrally
and temporally the emission from short-lived neutral and negatively charged
biexcitons in ultrasmall (sub-10 nm) CdSe nanocrystals (nanocrystal quantum
dots). Because of forced overlap of electronic wave functions and reduced
dielectric screening, these states are characterized by giant interaction
energies of tens (neutral biexcitons) to hundreds (charged biexcitons) of meV.
Both types of biexcitons show extremely short lifetimes (from sub-100
picoseconds to sub-picosecond time scales) that rapidly shorten with decreasing
nanocrystal size. These ultrafast relaxation dynamics are explained in terms of
highly efficient nonradiative Auger recombination.Comment: 5 pages, 4 figures, to be published in Phys. Rev.
Preparation of colloidal organosilica spheres through spontaneous emulsification
Biological and Soft Matter Physic
The effect of local crystalline environment on hydrogen atom behavior in molecular complexes of a proton sponge
Proton behavior within the hydrogen
bond (HB) networks of five
molecular complexes of the proton sponge DMAN and different organic
acids is investigated by single-crystal neutron diffraction. The complexes
form with either 2:1 (acid:DMAN) or 1:1 stoichiometric ratios and
contain common structural motifs. All show proton transfer from an
acid to DMAN, forming a DMANH<sup>+</sup> moiety and hydrogen-bonded
acid dimers; complexes with halobenzoic acids have acid molecules
linked by short, strong, charge-assisted HBs, while all complexes
contain a short, strong, intramolecular NâH¡¡¡N
HB in DMANH<sup>+</sup>. The hydrogen atom behavior within the short,
strong HBs, accurately described from the neutron data, is rationalized
in terms of weak interactions in the local crystal environment, with
the position of the proton within both sets of short, strong HBs affected
by a combination of the weak interactions in the vicinity of the HBs.
A correlation is also found between the thermal motion of the bound
proton in the NâH¡¡¡N HB of DMANH<sup>+</sup> and nearby oxygen atoms when they are sufficiently close to one
another. This work shows that all interactions in the local environment
combine to determine the behavior of protons within short, strong
HBs and that, by taking these interactions into account, further control
over the crystal structure and properties may be achievable
Comparative study of deuterium retention and vacancy content of self-ion irradiated tungsten
Self-ion irradiation of pure tungsten with 2 MeV W ions provides a way of simulating microstructures generated by neutron irradiation in tungsten components of a fusion reactor. Transmission electron microscopy (TEM) has been used to characterize defects formed in tungsten samples by ion irradiation. It was found that tungsten irradiated to 0.85 dpa at relatively low temperatures develops a characteristic microstructure dominated by dislocation loops and black dots. The density and size distribution of these defects were estimated. Some of the samples exposed to self-ion irradiation were then implanted with deuterium. Thermal Desorption Spectrometry (TDS) analysis was performed to estimate the deuterium inventory as a function of irradiation damage and deuterium release as a function of temperature. Increase of inventory with increasing irradiation dose followed by slight decrease above 0.1 dpa was found. Application of Positron Annihilation Spectroscopy (PAS) to self-irradiated but not deuterium implanted samples enabled an assessment of the density of irradiation defects as a function of exposure to highenergy ions. The PAS results show that the density of defects saturates at doses in the interval from 0.085 to 0.425 displacements per atom (dpa). These results are discussed in the context of recent theoretical simulations exhibiting the saturation of defect microstructure in the high irradiation exposure limit. The saturation of damage found in PAS agrees with the simulation data described in the paper. (c) 2021 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ )Peer reviewe
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A Search for Dark Higgs Bosons
Recent astrophysical and terrestrial experiments have motivated the proposal
of a dark sector with GeV-scale gauge boson force carriers and new Higgs
bosons. We present a search for a dark Higgs boson using 516 fb-1 of data
collected with the BABAR detector. We do not observe a significant signal and
we set 90% confidence level upper limits on the product of the Standard
Model-dark sector mixing angle and the dark sector coupling constant.Comment: 7 pages, 5 postscript figures, published version with improved plots
for b/w printin
Search for the standard model Higgs boson in the H to ZZ to 2l 2nu channel in pp collisions at sqrt(s) = 7 TeV
A search for the standard model Higgs boson in the H to ZZ to 2l 2nu decay
channel, where l = e or mu, in pp collisions at a center-of-mass energy of 7
TeV is presented. The data were collected at the LHC, with the CMS detector,
and correspond to an integrated luminosity of 4.6 inverse femtobarns. No
significant excess is observed above the background expectation, and upper
limits are set on the Higgs boson production cross section. The presence of the
standard model Higgs boson with a mass in the 270-440 GeV range is excluded at
95% confidence level.Comment: Submitted to JHE
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