Effect of Rare Earth on M7C3 Eutectic Carbide in 13% Chromium Alloy Cast Iron

The crystallization process of hypoeutectic white cast iron consists of the first secreted austenite branch after the reaction of the austenite -carbide crystal is formed, and the phase crystal fills in the middle of the austenite branches. If the austenite branches are small and smooth, the crystals carbide are fine. The cast iron with 13% chromium which has 3 – 3.2% carbon, have the carbide crystalline as M7C3. The elements in rare earth have a strong affinity for oxygen and sulfur to produce rare earth oxides. These rare earth oxides can create heterogeneous germ center for austenite phases and smooth down these phases. The effect of rare earth on the M7C3 and crystals of 13% chrome white iron has been elucidated. Along with the increase of rare earth content, the microstructure of M7C3 with fine finely graded, more uniformly distributed, dispersed throughout the sample surface. When the carbide is fine and dispersion, will contribute to improving the properties of cast iron especially the impact strength as well as the abrasion resistance of the alloy. The research results show that in the presence of rare earth, rare earth elements created with oxygen and form La2O3 and Ce2O3 as the nucleation for the solidification process and create the small fineness of phases. The orientation of the crystal structure of these oxides is similar to the crystal structure orientation of Fe-γ phase. Finding and proving the oxides of rare earth has crystal structure with phase γ which will be small smooth exogenous minds that the microstructure has a smooth, small size

RESEARCH ON THE MANUFACTURING MAGNESIUM FROM THANHHOA DOLOMITE BY PIDGEON PROCESS

The magnesium and magnesium alloys has applied widely in different industrial aspects in Vietnam in the modern life. Especially, the products from magnesium alloys implementing in the automotive have increased rapidly since the car elements tend to be generated by the light alloys in order to save the fuel. However, in the current time, Vietnam has no factories to produce the magnesium to adapt the domestic demand although it owns an enrich resource of raw materials. This research indicates the possibility of using the dolomite ore in Thanhhoa – Vietnam to make the magnesium as well as evaluate the primary factors like recovering temperature, reducing agent rate, recovering time having effect on the reduction efficiency of Thanhhoa dolomite by metallothermic method in vacuum (Pidgeon Process). This is basic process, low investment and suitable for the small and medium scales in Vietnam. The experiment includes heating, indicating the chemical ingredients and recovering experiment on the dolomite after calcination (dolime) by using ferrosilicon. The thermodynamic model is created to estimate the recovering efficiency in the Pidgeon. The result shows that the CaO/MgO molar ratio of calcination dolomite in Thanhhoa is nearly 1.5 which is suitable to produce magnesium in the case of highly-required efficiency and pureness. Besides, the result from the furnace of the experiment is lower than the one in the model. The samples are set up to check the influence of the rate of ferrosilicon in the compound. The result indicates that the ideal efficiency reaches 85 % with 30 % ferrosilicon. Moreover, the study confirms that the optimal operating conditions in this process are recovering during three hours at 1200 °C and 100 Pa pressure. This result proves the potential application of Thanhhoa dolomite in the industry suitable with the current condition in Vietna

The results of deep magnetotelluric sounding for studying the Nha Trang - Tanh Linh fault

The profile of deep magnetotelluric sounding (MT) from Duc Trong - Tuy Phong has been carried out in Lam Dong and Binh Thuan  provinces. The length of the Duc Trong - Tuy Phong profile is about 80 km with 15 stations and the distance between the stations measures about 5 km. Two-dimensional MT inversion was used to find a resistivity model that fits the data. The 2D resistivity model allows determining position and development formation of the Nha Trang - Tanh Linh  fault. This is the deep fault, which is showed by the boundaries of remarkable change of resistivity. In the near surface of the Earth (from ground to the depth of 6 km), the angle of inclination of this fault is about 60o; in the next part, the direction of the Nha Trang - Tanh Linh  faut is vertical. Geoelectrical section of the Nha Trang - Tanh Linh  profile shows that the resistivity of mid-crust is higher than that of lower-crust and of upper-crust

Spatiotemporal analysis of historical records (2001-2012) on dengue fever in Vietnam and development of a statistical model for forecasting risk

Background: Dengue fever is the most widespread infectious disease of humans transmitted by Aedes mosquitoes. It is the leading cause of hospitalization and death in children in the Southeast Asia and western Pacific regions. We analyzed surveillance records from health centers in Vietnam collected between 2001–2012 to determine seasonal trends, develop risk maps and an incidence forecasting model. Methods: The data were analyzed using a hierarchical spatial Bayesian model that approximates its posterior parameter distributions using the integrated Laplace approximation algorithm (INLA). Meteorological, altitude and land cover (LC) data were used as predictors. The data were grouped by province (n = 63) and month (n = 144) and divided into training (2001–2009) and validation (2010–2012) sets. Thirteen meteorological variables, 7 land cover data and altitude were considered as predictors. Only significant predictors were kept in the final multivariable model. Eleven dummy variables representing month were also fitted to account for seasonal effects. Spatial and temporal effects were accounted for using Besag-York-Mollie (BYM) and autoregressive (1) models. Their levels of significance were analyzed using deviance information criterion (DIC). The model was validated based on the Theil’s coefficient which compared predicted and observed incidence estimated using the validation data. Dengue incidence predictions for 2010–2012 were also used to generate risk maps. Results: The mean monthly dengue incidence during the period was 6.94 cases (SD 14.49) per 100,000 people. Analyses on the temporal trends of the disease showed regular seasonal epidemics that were interrupted every 3 years (specifically in July 2004, July 2007 and September 2010) by major fluctuations in incidence. Monthly mean minimum temperature, rainfall, area under urban settlement/build-up areas and altitude were significant in the final model. Minimum temperature and rainfall had non-linear effects and lagging them by two months provided a better fitting model compared to using unlagged variables. Forecasts for the validation period closely mirrored the observed data and accurately captured the troughs and peaks of dengue incidence trajectories. A favorable Theil’s coefficient of inequality of 0.22 was generated. Conclusions: The study identified temperature, rainfall, altitude and area under urban settlement as being significant predictors of dengue incidence. The statistical model fitted the data well based on Theil’s coefficient of inequality, and risk maps generated from its predictions identified most of the high-risk provinces throughout the country

Safety and efficacy of fluoxetine on functional outcome after acute stroke (AFFINITY): a randomised, double-blind, placebo-controlled trial

Background Trials of fluoxetine for recovery after stroke report conflicting results. The Assessment oF FluoxetINe In sTroke recoverY (AFFINITY) trial aimed to show if daily oral fluoxetine for 6 months after stroke improves functional outcome in an ethnically diverse population. Methods AFFINITY was a randomised, parallel-group, double-blind, placebo-controlled trial done in 43 hospital stroke units in Australia (n=29), New Zealand (four), and Vietnam (ten). Eligible patients were adults (aged ≥18 years) with a clinical diagnosis of acute stroke in the previous 2–15 days, brain imaging consistent with ischaemic or haemorrhagic stroke, and a persisting neurological deficit that produced a modified Rankin Scale (mRS) score of 1 or more. Patients were randomly assigned 1:1 via a web-based system using a minimisation algorithm to once daily, oral fluoxetine 20 mg capsules or matching placebo for 6 months. Patients, carers, investigators, and outcome assessors were masked to the treatment allocation. The primary outcome was functional status, measured by the mRS, at 6 months. The primary analysis was an ordinal logistic regression of the mRS at 6 months, adjusted for minimisation variables. Primary and safety analyses were done according to the patient's treatment allocation. The trial is registered with the Australian New Zealand Clinical Trials Registry, ACTRN12611000774921. Findings Between Jan 11, 2013, and June 30, 2019, 1280 patients were recruited in Australia (n=532), New Zealand (n=42), and Vietnam (n=706), of whom 642 were randomly assigned to fluoxetine and 638 were randomly assigned to placebo. Mean duration of trial treatment was 167 days (SD 48·1). At 6 months, mRS data were available in 624 (97%) patients in the fluoxetine group and 632 (99%) in the placebo group. The distribution of mRS categories was similar in the fluoxetine and placebo groups (adjusted common odds ratio 0·94, 95% CI 0·76–1·15; p=0·53). Compared with patients in the placebo group, patients in the fluoxetine group had more falls (20 [3%] vs seven [1%]; p=0·018), bone fractures (19 [3%] vs six [1%]; p=0·014), and epileptic seizures (ten [2%] vs two [<1%]; p=0·038) at 6 months. Interpretation Oral fluoxetine 20 mg daily for 6 months after acute stroke did not improve functional outcome and increased the risk of falls, bone fractures, and epileptic seizures. These results do not support the use of fluoxetine to improve functional outcome after stroke

STUDY ON THE BREAKDOWN OF MILLING BALLS MADE OF 13%Cr WHITE CAST-IRON WORKING IN STRONG ABRASIVE AND CLASH CONDITIONS

The breakdown due to abrasion and clash of the milling balls made of 13% Cr white cast iron is a complicated process which depends on many factors, especially on the strength of the matrix and carbide phases. As shown, stresses created by abrasion and clash processes are concentrated mainly at the locations such as carbide/matrix boundary and around coarse carbide particles, leading to the cracks and breakdown there. The peeling off carbide particles can be a reason of scratches on the specimen surface. Heat treatment (quenching in oil and tempering at 2500 C for three hours) to transform a soft matrix (austenite) to a harder one (martensite) can be a good solution against abrasion. Concerning the impact, the solution should be the refinement of the carbide particles and their uniform distribution

Magnesium Reduction from Thanhhoa Dolomite by Ferrosilicon and Ferro-Silicocalcium as Reducing Agent

In this paper, a new reducing agent known as ferro-silicocalcium is being studied for its application in magnesium production through the Pidgeon process. Ferro-silicocalcium with main phase components CaSi2 and Si can reduce Mg from dolomite at a lower temperature than a traditional reducing agent. It thus improves the efficiency of magnesium production and solves the large energy consumption problem of the Pidgeon process. This paper presents thermodynamics calculations and experimental study on reducing magnesium from Thanhhoa dolomite with the new reducing agents known as ferro-silicocalcium and ferrosilicon as traditional reducing agents. From the thermodynamics calculations, CaSi2 in the ferro-silicocalcium can eliminate magnesium oxide at temperatures 1000°C lower than FeSi2 in ferrosilicon. This leads to a substantial decrease in the recovery temperature. When CaSi2 is decomposed, it releases silicon to improve the reduction process at temperatures greater than 1100°C. Experiments are performed to confirm the calculation results. The reduction process of dolomite by ferro-silicocalcium and ferrosilicon was analyzed by phases analysis of reduction slag through X-ray diffraction. The experimental results show that when using ferro-silicocalcium as a reducing agent, the recovering magnesium oxide efficiency reaches 91.3% over three hours with a recovering temperature of 1200°C. The efficiency is 7% higher than the traditional method using ferrosilicon under the same conditions. This proves that using ferro-silicocalcium as a reducing agent reduces the operating temperature of the reducing system and saves energy for the whole process. Therefore, ferro-silicocalium promises to be an effective alternative reducing agent in magnesium production