Ab initio Molecular Orbital Studies of the Vibrational Spectra of some van der Waals Complexes. Part 4. Complexes of Sulphur Dioxide with Carbon Dioxide, Carbonyl Sulphide, Carbon Disulphide and Nitrous Oxide

The binary complexes formed between sulphur dioxide, as electron donor, and the series carbon dioxide, carbonyl sulphide and carbon disulphide, as electron acceptors, have been studied by means of ab initio molecular orbital theory. The optimized structures, the interaction energies and the vibrational spectra have been determined, and the effect of successive substitution of sulphur for oxygen atoms in the electron acceptor molecules has been established. Nitrous oxide, which is isoelectronic with carbon dioxide, has also been included among the electron acceptors, but the properties of the complex formed between sulphur dioxide and nitrous oxide are substantially different from those of the other three complexes.Keywords: Ab initio calculations, molecular complexes, sulphur dioxide, carbon dioxide, carbonyl sulphide, carbon disulphide, nitrous oxide, molecular structures, interaction energies, vibrational spectraPDF and Supplementry file attache

Density Estimation Using a Generalized Neuron

Neural networks have been shown to be useful tools for density estimation. However, the training of neural network structures is time consuming and requires fast processors for practical applications. A new method with a generalized neuron (GN) for density estimation is presented in this paper. The GN is trained with the particle swarm optimization algorithm which is known to have fast convergence than the standard backpropagation algorithm. Results are presented to show that the GN can estimate the density functions for distribution functions with different means and variances. This density estimation method can also be applied to the multi-sensor data fusion proces

Optimal SVM Switching for a Multilevel Multi-Phase Machine using Modified Discrete PSO

This paper searches for the best possible switching sequence in a multilevel multi-phase inverter that gives the lowest amount of voltage harmonics. A modified discrete particle swarm (MDPSO) algorithm is used in an attempt to find the optimal space vector modulation switching sequence that results in the lowest voltage THD. As with typical PSO cognitive and social parameters are used to guide the search, but an additional mutation term is added to broaden the amount of area searched. The search space is the feasible solutions for the predetermined vectors at a given modulation index. Comparison of the MDPSO algorithm to an integer particle swarm optimization (IPSO) is presented for all three modulation indices tested. The resulting switching sequences found show that the MDPSO algorithm is capable of finding a minimal THD solution for all modulations indices tested. The MDPSO algorithm performed better overall than the IPSO in terms of converging to the best solution with significantly lower iterations

Comparison of Feedforward and Feedback Neural Network Architectures for Short Term Wind Speed Prediction

This paper compares three types of neural networks trained using particle swarm optimization (PSO) for use in the short term prediction of wind speed. The three types of neural networks compared are the multi-layer perceptron (MLP) neural network, Elman recurrent neural network, and simultaneous recurrent neural network (SRN). Each network is trained and tested using meteorological data of one week measured at the National Renewable Energy Laboratory National Wind Technology Center near Boulder, CO. Results show that while the recurrent neural networks outperform the MLP in the best and average case with a lower overall mean squared error, the MLP performance is comparable. The better performance of the feedback architectures is also shown using the mean absolute relative error. While the SRN performance is superior, the increase in required training time for the SRN over the other networks may be a constraint, depending on the application

Enhanced Particle Swarm Optimizer for Power System Applications

Power system networks are complex systems that are highly nonlinear and non-stationary, and therefore, their performance is difficult to optimize using traditional optimization techniques. This paper presents an enhanced particle swarm optimizer for solving constrained optimization problems for power system applications, in particular, the optimal allocation of multiple STATCOM units. The study focuses on the capability of the algorithm to find feasible solutions in a highly restricted hyperspace. The performance of the enhanced particle swarm optimizer is compared with the classical particle swarm optimization (PSO) algorithm, genetic algorithm (GA) and bacterial foraging algorithm (BFA). Results show that the enhanced PSO is able to find feasible solutions faster and converge to feasible regions more often as compared with other algorithms. Additionally, the enhanced PSO is capable of finding the global optimum without getting trapped in local minima

Two-stage Stochastic Model using Benders' Decomposition for Large-scale Energy Resources Management in Smart grids

The ever-increasing penetration level of renewable energy and electric vehicles may threaten power grid operation. Dealing with uncertainty in smart grids is critical in order to mitigate possible issues. This research work proposes a two-stage stochastic model for large-scale energy resources scheduling for aggregators. The proposed model is designed for aggregators managing a smart grid. The idea is to address the challenge brought by the variability of demand, renewable energy, electric vehicles, and market price variations while pursuing cost minimization. Benders’ decomposition approach is implemented to improve the tractability of the original model and its’ computational burden. A realistic case study is presented using a real distribution network in Portugal with high penetration of renewable energy and electric vehicles. The results show the effectiveness and efficiency of the proposed approach when compared with a deterministic formulation and suggest that demand response and storage systems can mitigate the uncertainty.info:eu-repo/semantics/acceptedVersio

Artificial Neural Networks for Short-Term Load Forecasting in Microgrids Environment Energy

The adaptation of energy production to demand has been traditionally very important for utilities in order to optimize resource consumption. This is especially true also in microgrids where many intelligent elements have to adapt their behaviour depending on the future generation and consumption conditions. However, traditional forecasting has been performed only for extremely large areas, such as nations and regions. This work aims at presenting a solution for short-term load forecasting (STLF) in microgrids, based on a three-stage architecture which starts with pattern recognition by a self-organizing map (SOM), a clustering of the previous partition via k-means algorithm, and finally demand forecasting for each cluster with a multilayer perceptron. Model validation was performed with data from a microgrid-sized environment provided by the Spanish company Iberdrola. (C) 2014 Elsevier Ltd. All rights reserved.Hernandez, L.; Baladron, C.; Aguiar, JM.; Carro, B.; Sanchez-Esguevillas, A.; Lloret, J. (2014). Artificial Neural Networks for Short-Term Load Forecasting in Microgrids Environment Energy. Energy. 75:252-264. doi:10.1016/j.energy.2014.07.065S2522647

Multi-objective energy storage power dispatching using plug-in vehicles in a smart-microgrid

This paper describes a multi-objective power dispatching problem that uses Plug-in Electric Vehicle (PEV) as storage units. We formulate the energy storage planning as a Mixed-Integer Linear Programming (MILP) problem, respecting PEV requirements, minimizing three different objectives and analyzing three different criteria. Two novel cost-to-variability indicators, based on Sharpe Ratio, are introduced for analyzing the volatility of the energy storage schedules. By adding these additional criteria, energy storage planning is optimized seeking to minimize the following: total Microgrid (MG) costs; PEVs batteries usage; maximum peak load; difference between extreme scenarios and two Sharpe Ratio indices. Different scenarios are considered, which are generated with the use of probabilistic forecasting, since prediction involves inherent uncertainty. Energy storage planning scenarios are scheduled according to information provided by lower and upper bounds extracted from probabilistic forecasts. A MicroGrid (MG) scenario composed of two renewable energy resources, a wind energy turbine and photovoltaic cells, a residential MG user and different PEVs is analyzed. Candidate non-dominated solutions are searched from the pool of feasible solutions obtained during different Branch and Bound optimizations. Pareto fronts are discussed and analyzed for different energy storage scenarios. Perhaps the most important conclusion from this study is that schedules that minimize the total system cost may increase maximum peak load and its volatility over different possible scenarios, therefore may be less robust

ASIRI : an ocean–atmosphere initiative for Bay of Bengal

Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Bulletin of the American Meteorological Society 97 (2016): 1859–1884, doi:10.1175/BAMS-D-14-00197.1.Air–Sea Interactions in the Northern Indian Ocean (ASIRI) is an international research effort (2013–17) aimed at understanding and quantifying coupled atmosphere–ocean dynamics of the Bay of Bengal (BoB) with relevance to Indian Ocean monsoons. Working collaboratively, more than 20 research institutions are acquiring field observations coupled with operational and high-resolution models to address scientific issues that have stymied the monsoon predictability. ASIRI combines new and mature observational technologies to resolve submesoscale to regional-scale currents and hydrophysical fields. These data reveal BoB’s sharp frontal features, submesoscale variability, low-salinity lenses and filaments, and shallow mixed layers, with relatively weak turbulent mixing. Observed physical features include energetic high-frequency internal waves in the southern BoB, energetic mesoscale and submesoscale features including an intrathermocline eddy in the central BoB, and a high-resolution view of the exchange along the periphery of Sri Lanka, which includes the 100-km-wide East India Coastal Current (EICC) carrying low-salinity water out of the BoB and an adjacent, broad northward flow (∼300 km wide) that carries high-salinity water into BoB during the northeast monsoon. Atmospheric boundary layer (ABL) observations during the decaying phase of the Madden–Julian oscillation (MJO) permit the study of multiscale atmospheric processes associated with non-MJO phenomena and their impacts on the marine boundary layer. Underway analyses that integrate observations and numerical simulations shed light on how air–sea interactions control the ABL and upper-ocean processes.This work was sponsored by the U.S. Office of Naval Research (ONR) in an ONR Departmental Research Initiative (DRI), Air–Sea Interactions in Northern Indian Ocean (ASIRI), and in a Naval Research Laboratory project, Effects of Bay of Bengal Freshwater Flux on Indian Ocean Monsoon (EBOB). ASIRI–RAWI was funded under the NASCar DRI of the ONR. The Indian component of the program, Ocean Mixing and Monsoons (OMM), was supported by the Ministry of Earth Sciences of India.2017-04-2