1,276 research outputs found
Quasi-freestanding and single-atom thick layer of hexagonal boron nitride as a substrate for graphene synthesis
We demonstrate that freeing a single-atom thick layer of hexagonal boron
nitride (hbn) from tight chemical bonding to a Ni(111) thin film grown on a
W(110) substrate can be achieved by intercalation of Au atoms into the
interface. This process has been systematically investigated using
angle-resolved photoemission spectroscopy, X-ray photoemission and absorption
techniques. It has been demonstrated that the transition of the hbn layer from
the "rigid" into the "quasi-freestanding" state is accompanied by a change of
its lattice constant. Using chemical vapor deposition, graphene has been
successfully synthesized on the insulating, quasi-freestanding hbn monolayer.
We anticipate that the in situ synthesized weakly interacting graphene/hbn
double layered system could be further developed for technological applications
and may provide perspectives for further inquiry into the unusual electronic
properties of graphene.Comment: in print in Phys. Rev.
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Controlled assembly of graphene-capped nickel, cobalt and iron silicides
In-situ dendrite/metallic glass matrix composites (MGMCs) with a composition of Ti46Zr20V12Cu5Be17 exhibit ultimate tensile strength of 1510 MPa and fracture strain of about 7.6%. A tensile deformation model is established, based on the five-stage classification: (1) elastic-elastic, (2) elastic-plastic, (3) plastic-plastic (yield platform), (4) plastic-plastic (work hardening), and (5) plastic-plastic (softening) stages, analogous to the tensile behavior of common carbon steels. The constitutive relations strongly elucidate the tensile deformation mechanism. In parallel, the simulation results by a finite-element method (FEM) are in good agreement with the experimental findings and theoretical calculations. The present study gives a mathematical model to clarify the work-hardening behavior of dendrites and softening of the amorphous matrix. Furthermore, the model can be employed to simulate the tensile behavior of in-situ dendrite/MGMCs
Insight into the electronic structure of the centrosymmetric skyrmion magnet GdRuSi
The discovery of a square magnetic-skyrmion lattice in GdRuSi, with
the smallest so far found skyrmion diameter and without a geometrically
frustrated lattice, has attracted significant attention, particularly for
potential applications in memory devices and quantum computing. In this work,
we present a comprehensive study of surface and bulk electronic structures of
GdRuSi by utilizing momentum-resolved photoemission (ARPES)
measurements and first-principles calculations. We show how the electronic
structure evolves during the antiferromagnetic transition when a peculiar
helical order of 4 magnetic moments within the Gd layers sets in. A nice
agreement of the ARPES-derived electronic structure with the calculated one has
allowed us to characterize the features of the Fermi surface (FS), unveil the
nested region along the at the corner of the 3D FS, and reveal their
orbital compositions. Our findings suggest that the
Ruderman-Kittel-Kasuya-Yosida interaction plays a decisive role in stabilizing
the spiral-like order of Gd 4 moments responsible for the skyrmion physics
in GdRuSi. Our results provide a deeper understanding of electronic and
magnetic properties of this material, which is crucial for predicting and
developing novel skyrmion-based devices.Comment: 13 pages, 8 figure
Atomically precise semiconductor-graphene and hBN interfaces by Ge intercalation
The full exploration of the potential, which graphene offers to nanoelectronics requires its integration into semiconductor technology. So far the real-world applications are limited by the ability to concomitantly achieve large single-crystalline domains on dielectrics and semiconductors and to tailor the interfaces between them. Here we show a new direct bottom-up method for the fabrication of high-quality atomically precise interfaces between 2D materials, like graphene and hexagonal boron nitride (hBN), and classical semiconductor via Ge intercalation. Using angle-resolved photoemission spectroscopy and complementary DFT modelling we observed for the first time that epitaxially grown graphene with the Ge monolayer underneath demonstrates Dirac Fermions unaffected by the substrate as well as an unperturbed electronic band structure of hBN. This approach provides the intrinsic relativistic 2D electron gas towards integration in semiconductor technology. Hence, these new interfaces are a promising path for the integration of graphene and hBN into state-of-the-art semiconductor technology
Nitrogen-Functionalized Graphene Nanoflakes (GNFs:N): Tunable Photoluminescence and Electronic Structures
This study investigates the strong photoluminescence (PL) and X-ray excited
optical luminescence observed in nitrogen-functionalized 2D graphene nanoflakes
(GNFs:N), which arise from the significantly enhanced density of states in the
region of {\pi} states and the gap between {\pi} and {\pi}* states. The
increase in the number of the sp2 clusters in the form of pyridine-like N-C,
graphite-N-like, and the C=O bonding and the resonant energy transfer from the
N and O atoms to the sp2 clusters were found to be responsible for the blue
shift and the enhancement of the main PL emission feature. The enhanced PL is
strongly related to the induced changes of the electronic structures and
bonding properties, which were revealed by the X-ray absorption near-edge
structure, X-ray emission spectroscopy, and resonance inelastic X-ray
scattering. The study demonstrates that PL emission can be tailored through
appropriate tuning of the nitrogen and oxygen contents in GNFs and pave the way
for new optoelectronic devices.Comment: 8 pages, 6 figures (including toc figure
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Tunneling current modulation in atomically precise graphene nanoribbon heterojunctions
Lateral heterojunctions of atomically precise graphene nanoribbons (GNRs) hold promise for applications in nanotechnology, yet their charge transport and most of the spectroscopic properties have not been investigated. Here, we synthesize a monolayer of multiple aligned heterojunctions consisting of quasi-metallic and wide-bandgap GNRs, and report characterization by scanning tunneling microscopy, angle-resolved photoemission, Raman spectroscopy, and charge transport. Comprehensive transport measurements as a function of bias and gate voltages, channel length, and temperature reveal that charge transport is dictated by tunneling through the potential barriers formed by wide-bandgap GNR segments. The current-voltage characteristics are in agreement with calculations of tunneling conductance through asymmetric barriers. We fabricate a GNR heterojunctions based sensor and demonstrate greatly improved sensitivity to adsorbates compared to graphene based sensors. This is achieved via modulation of the GNR heterojunction tunneling barriers by adsorbates
Colossal magnetoresistance in EuZnP and its electronic and magnetic structure
We investigate single crystals of the trigonal antiferromagnet EuZnP
() by means of electrical transport, magnetization
measurements, X-ray magnetic scattering, optical reflectivity, angle-resolved
photoemission spectroscopy (ARPES) and ab-initio band structure calculations
(DFT+U). We find that the electrical resistivity of EuZnP increases
strongly upon cooling and can be suppressed in magnetic fields by several
orders of magnitude (CMR effect). Resonant magnetic scattering reveals a
magnetic ordering vector of , corresponding to an
-type antiferromagnetic (AFM) order, below . We
find that the moments are canted out of the plane by an angle of about
degrees and tilted away from the [100] - direction
by . We observe nearly isotropic magnetization
behavior for low fields and low temperatures which is consistent with the
magnetic scattering results. The magnetization measurements show a deviation
from the Curie-Weiss behavior below , the temperature below
which also the field dependence of the material's resistivity starts to
increase. An analysis of the infrared reflectivity spectrum at
allows us to resolve the main phonon bands and intra-/interband transitions,
and estimate indirect and direct band gaps of
and ,
respectively, which are in good agreement with the theoretically predicted
ones. The experimental band structure obtained by ARPES is nearly
-independent above and below . The comparison of the theoretical
and experimental data shows a weak intermixing of the Eu 4 states close to
the point with the bands formed by the phosphorous 3 orbitals
leading to an induction of a small magnetic moment at the P sites
Observation of an Excited Bc+ State
Using pp collision data corresponding to an integrated luminosity of 8.5 fb-1 recorded by the LHCb experiment at center-of-mass energies of s=7, 8, and 13 TeV, the observation of an excited Bc+ state in the Bc+π+π- invariant-mass spectrum is reported. The observed peak has a mass of 6841.2±0.6(stat)±0.1(syst)±0.8(Bc+) MeV/c2, where the last uncertainty is due to the limited knowledge of the Bc+ mass. It is consistent with expectations of the Bc∗(2S31)+ state reconstructed without the low-energy photon from the Bc∗(1S31)+→Bc+γ decay following Bc∗(2S31)+→Bc∗(1S31)+π+π-. A second state is seen with a global (local) statistical significance of 2.2σ (3.2σ) and a mass of 6872.1±1.3(stat)±0.1(syst)±0.8(Bc+) MeV/c2, and is consistent with the Bc(2S10)+ state. These mass measurements are the most precise to date
Study of charmonium production in b -hadron decays and first evidence for the decay Bs0
Using decays to φ-meson pairs, the inclusive production of charmonium states in b-hadron decays is studied with pp collision data corresponding to an integrated luminosity of 3.0 fb−1, collected by the LHCb experiment at centre-of-mass energies of 7 and 8 TeV. Denoting byBC ≡ B(b → C X) × B(C → φφ) the inclusive branching fraction of a b hadron to a charmonium state C that decays into a pair of φ mesons, ratios RC1C2 ≡ BC1 /BC2 are determined as Rχc0ηc(1S) = 0.147 ± 0.023 ± 0.011, Rχc1ηc(1S) =0.073 ± 0.016 ± 0.006, Rχc2ηc(1S) = 0.081 ± 0.013 ± 0.005,Rχc1 χc0 = 0.50 ± 0.11 ± 0.01, Rχc2 χc0 = 0.56 ± 0.10 ± 0.01and Rηc(2S)ηc(1S) = 0.040 ± 0.011 ± 0.004. Here and below the first uncertainties are statistical and the second systematic.Upper limits at 90% confidence level for the inclusive production of X(3872), X(3915) and χc2(2P) states are obtained as RX(3872)χc1 < 0.34, RX(3915)χc0 < 0.12 andRχc2(2P)χc2 < 0.16. Differential cross-sections as a function of transverse momentum are measured for the ηc(1S) andχc states. The branching fraction of the decay B0s → φφφ is measured for the first time, B(B0s → φφφ) = (2.15±0.54±0.28±0.21B)×10−6. Here the third uncertainty is due to the branching fraction of the decay B0s → φφ, which is used for normalization. No evidence for intermediate resonances is seen. A preferentially transverse φ polarization is observed.The measurements allow the determination of the ratio of the branching fractions for the ηc(1S) decays to φφ and p p asB(ηc(1S)→ φφ)/B(ηc(1S)→ p p) = 1.79 ± 0.14 ± 0.32
Measurement of the inelastic pp cross-section at a centre-of-mass energy of 13TeV
The cross-section for inelastic proton-proton collisions at a centre-of-mass energy of 13TeV is measured with the LHCb detector. The fiducial cross-section for inelastic interactions producing at least one prompt long-lived charged particle with momentum p > 2 GeV/c in the pseudorapidity range 2 < η < 5 is determined to be ϭ acc = 62:2 ± 0:2 ± 2:5mb. The first uncertainty is the intrinsic systematic uncertainty of the measurement, the second is due to the uncertainty on the integrated luminosity. The statistical uncertainty is negligible. Extrapolation to full phase space yields the total inelastic proton-proton cross-section ϭ inel = 75:4 ± 3:0 ± 4:5mb, where the first uncertainty is experimental and the second due to the extrapolation. An updated value of the inelastic cross-section at a centre-of-mass energy of 7TeV is also reported
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