Laserspektroskopie an hochgeladenen Bismutionen zum Test der Quantenelektrodynamik

Die Arbeit behandelt einen Test der Quantenelektrodynamik in starken Feldern mit Hilfe von Laserspektroskopie der Grundzustandshyperfeinstruktur hochgeladener Bismutionen. Das Experiment wurde am Speicherring ESR des GSI Helmholtzzentrum für Schwerionenforschung in Darmstadt durchgeführt und ausgewertet. Raumladungseffekte wurden systematisch untersucht und die Wellenlängenmessung des Lasers durch Absorptionsspektroskopie von Jod verifiziert. Durch eine in-situ Messung der Elektronenkühlerspannung ermittelte Ionengeschwindigkeit konnte die größte systematische Unsicherheit des vorherigen Experimentes um mehr als eine Größenordnung verringert werden. Dies zeigte die Notwendigkeit der Etablierung einer permanent installierten Hochspannungsmessung am Elektronenkühler, welche im Rahmen der Arbeit vorangetrieben wurde. Die aus den gemessenen Wellenlängen ermittelte spezifische Differenz weicht so signifikant von der theoretischen Vorhersage ab, dass keine der untersuchten Systematiken als Ursache der Abweichung in Frage kommt. Neben Zweifeln an den Werten aus der Theorie wird der Literaturwert des magnetischen Kernmoments von Bismut-209 als mögliche Ursache angeführt und im Ausblick dargestellt, wie in folgenden Experimenten dieses Rätsel gelöst werden könnteThs dissertation concerns a test of the theory of quantum electrodynamics in strong fields by laser spectroscopy of the ground state hyperfine splitting of highly charged bismuth ions. The experiment was performed and analyzed at the storage ring ESR at Helmholtzzentrum für Schwerionenforschung in Darmstadt. A systematic study of space charge effects was carried out and the laser wavelength measurement was verified by absorption spectroscopy of iodine. The determination of the ion velocity by an in-situ measurement of the electron cooler voltage reduced the main systematic uncertainty of the previous experiment by over an order of magnitude. This indicated the necessity to establish a permanent high voltage measurement at the electron cooler, which was promoted in this work. The measured wavelengths were combined in a specific difference which deviates significantly from the theoretical predictions. None of the investigated systematics has the magnitude to explain this deviation. Apart from doubts regarding theory, the literature value of the nuclear magnetic moment of Bismuth-209 is indicated as a possible explanation. Follow-up experiments to solve this puzzle are described in the outook

Natural Pans as an Important Surface Water Resource in the Cuvelai Basin - Metrics for Storage Volume Calculations and Identification of Potential Augmentation Sites

Numerous ephemeral rivers and thousands of natural pans characterize the transboundary Iishana-System of the Cuvelai Basin between Namibia and Angola. After the rainy season, surface water stored in pans is often the only affordable water source for many people in rural areas. High inter- and intra-annual rainfall variations in this semiarid environment provoke years of extreme flood events and long periods of droughts. Thus, the issue of water availability is playing an increasingly important role in one of the most densely populated and fastest growing regions in southwestern Africa. Currently, there is no transnational approach to quantifying the potential storage and supply functions of the Iishana-System. To bridge these knowledge gaps and to increase the resilience of the local people’s livelihood, suitable pans for expansion as intermediate storage were identified and their metrics determined. Therefore, a modified Blue Spot Analysis was performed, based on the high-resolution TanDEM-X digital elevation model. Further, surface area–volume ratio calculations were accomplished for finding suitable augmentation sites in a first step. The potential water storage volume of more than 190,000 pans was calculated at 1.9 km3. Over 2200 pans were identified for potential expansion to facilitate increased water supply and flood protection in the future

An Observationally Constrained Evaluation of the Oxidative Capacity in the Tropical Western Pacific Troposphere

Hydroxyl radical (OH) is the main daytime oxidant in the troposphere and determines the atmospheric lifetimes of many compounds. We use aircraft measurements of O3, H2O, NO, and other species from the Convective Transport of Active Species in the Tropics (CONTRAST) field campaign, which occurred in the tropical western Pacific (TWP) during January–February 2014, to constrain a photochemical box model and estimate concentrations of OH throughout the troposphere. We find that tropospheric column OH (OHCOL) inferred from CONTRAST observations is 12 to 40% higher than found in chemical transport models (CTMs), including CAM-chem-SD run with 2014 meteorology as well as eight models that participated in POLMIP (2008 meteorology). Part of this discrepancy is due to a clear-sky sampling bias that affects CONTRAST observations; accounting for this bias and also for a small difference in chemical mechanism results in our empirically based value of OHCOL being 0 to 20% larger than found within global models. While these global models simulate observed O3 reasonably well, they underestimate NOx (NO + NO2) by a factor of two, resulting in OHCOL ~30% lower than box model simulations constrained by observed NO. Underestimations by CTMs of observed CH3CHO throughout the troposphere and of HCHO in the upper troposphere further contribute to differences between our constrained estimates of OH and those calculated by CTMs. Finally, our calculations do not support the prior suggestion of the existence of a tropospheric OH minimum in the TWP, because during January–February 2014 observed levels of O3 and NO were considerably larger than previously reported values in the TWP

Screening and contact precautions - A survey on infection control measures for multidrug-resistant bacteria in German university hospitals

To assess the scope of infection control measures for multidrug-resistant bacteria in high-risk settings, a survey among university hospitals was conducted. Fourteen professionals from 8 sites participated. Reported policies varied largely with respect to the types of wards conducting screening, sample types used for screening and implementation of contact precautions. This variability among sites highlights the need for an evidence-based consensus of current infection control policies