143 research outputs found
Predominant formation of aromatic aldehyde and acid from a dimeric Ξ²-O-4-type lignin model compound under hydrogen peroxide bleaching conditions with high pH levels
Π Π°Π΄ΠΈΠΊΠ°Π»ΡΠ½Π°Ρ ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΡ ΡΡΠΈΡΠΎΠ»Π° ΠΈ Ξ±-Π°Π½Π³Π΅Π»ΠΈΠΊΠ°Π»Π°ΠΊΡΠΎΠ½Π°: ΡΠΈΠ½ΡΠ΅Π· ΠΈ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΎΠ²
Biodegradation ability of synthetic polymer materials is an urgent problem of modern ecology
situation. A known new biodegradable polymer is polyangelicalactone (PAL). In this paper, styrene-Ξ±-
angelicalactone copolymers were obtained by radical polymerization. The resulting copolymers have
physical and mechanical properties similar to those of polystyrene and its graft-copolymers
with PAL.
Both they were mechanically destroyed when incubated in gray forest soil over 28 weeks. The obtained
results show that the modification of polystyrene with the impurities of Ξ±-angelicalactone
does not
worsen the mechanical properties of the copolymers but instead gives them biodegradation abilitiesΠ Π½Π°ΡΡΠΎΡΡΠ΅ΠΉ ΡΠ°Π±ΠΎΡΠ΅ ΠΏΠΎΠ»ΡΡΠ΅Π½Ρ ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΡ ΡΡΠΈΡΠΎΠ»Π° ΠΈ Ξ±-Π°Π½Π³Π΅Π»ΠΈΠΊΠ°Π»Π°ΠΊΡΠΎΠ½Π°
ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ
ΡΠ°Π΄ΠΈΠΊΠ°Π»ΡΠ½ΠΎΠΉ ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ. ΠΠΎΠ»ΡΡΠ΅Π½Π½ΡΠ΅ ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΡ ΠΈΠΌΠ΅ΡΡ ΡΠΈΠ·ΠΈΠΊΠΎ-ΠΌΠ΅Ρ
Π°Π½ΠΈΡΠ΅ΡΠΊΠΈΠ΅
ΡΠ²ΠΎΠΉΡΡΠ²Π°,
Π°Π½Π°Π»ΠΎΠ³ΠΈΡΠ½ΡΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π°ΠΌ
ΠΏΠΎΠ»ΠΈΡΡΠΈΡΠΎΠ»Π° ΠΈ Π΅Π³ΠΎ ΠΏΡΠΈΠ²ΠΈΡΡΡ
ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΎΠ² Ρ ΠΏΠΎΠ»ΠΈΠ°Π½Π³Π΅Π»ΠΈΠΊΠ°Π»Π°ΠΊΡΠΎΠ½ΠΎΠΌ. ΠΠ±Π°
ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠ° ΠΌΠ΅Ρ
Π°Π½ΠΈΡΠ΅ΡΠΊΠΈ ΡΠ°Π·ΡΡΡΠ°ΡΡΡΡ ΠΏΡΠΈ ΠΈΠ½ΠΊΡΠ±Π°ΡΠΈΠΈ Π² ΡΠ΅ΡΠΎΠΉ Π»Π΅ΡΠ½ΠΎΠΉ ΠΏΠΎΡΠ²Π΅ Π² ΡΠ΅ΡΠ΅Π½ΠΈΠ΅ 28 Π½Π΅Π΄Π΅Π»Ρ.
ΠΠΎΠ»ΡΡΠ΅Π½Π½ΡΠ΅ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΡ ΠΏΠΎΠΊΠ°Π·ΡΠ²Π°ΡΡ, ΡΡΠΎ ΠΌΠΎΠ΄ΠΈΡΠΈΠΊΠ°ΡΠΈΡ ΠΏΠΎΠ»ΠΈΡΡΠΈΡΠΎΠ»Π° ΠΏΡΠΈΠΌΠ΅ΡΡΠΌΠΈ Ξ±-Π°Π½Π³Π΅Π»ΠΈΠΊΠ°Π»Π°ΠΊΡΠΎΠ½Π°
Π½Π΅ ΡΡ
ΡΠ΄ΡΠ°Π΅Ρ ΠΌΠ΅Ρ
Π°Π½ΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π°
ΡΠΎΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΎΠ² ΠΈ ΠΏΡΠΈΠ΄Π°Π΅Ρ ΠΈΠΌ ΡΠΏΠΎΡΠΎΠ±Π½ΠΎΡΡΡ ΠΊ Π±ΠΈΠΎΡΠ°Π·Π»ΠΎΠΆΠ΅Π½ΠΈ
Towards sustainable production of formic acid
peer-reviewedFormic acid is a widely used commodity chemical. It can be applied as a safe, easily handled and
transported source of hydrogen or CO for different reactions including those producing fuels. The
review includes historical aspects of formic acid production. It shortly analyzes the production
based on traditional sources such as toxic CO, methanol and methane. However, the main emphasis
is done to the sustainable production of formic acid from biomass and biomass-derived products
via hydrolysis, wet and catalytic oxidation processes. New strategies of low temperature synthesis
from biomass may lead to utilization of formic acid for production of fuel additives such as
methanol, upgraded bio-oil, Ξ³-valerolactone and its derivatives, as well as synthesis gas used for
Fischer-Tropsch synthesis of hydrocarbons. Some technological aspects are considered
Electroanalysis may be used in the Vanillin Biotechnological Production
This study shows that electroanalysis may be used in vanillin biotechnological production. As a matter of fact, vanillin and some molecules implicated in the process like eugenol, ferulic acid, and vanillic acid may be oxidized on electrodes made of different materials (gold, platinum, glassy carbon). By a judicious choice of the electrochemical method and the experimental conditions the current intensity is directly proportional to the molecule concentrations in a range suitable for the biotechnological process. So, it is possible to imagine some analytical strategies to control some steps in the vanillin biotechnological production: by sampling in the batch reactor during the process, it is possible to determine out of line the concentration of vanillin, eugenol, ferulic acid, and vanillic acid with a gold rotating disk electrode, and low concentration of vanillin with addition of hydrazine at an amalgamated electrode. Two other possibilities consist in the introduction of electrodes directly in the batch during the process; the first one with a gold rotating disk electrode using linear sweep voltammetry and the second one requires three gold rotating disk electrodes held at different potentials for chronoamperometry. The last proposal is the use of ultramicroelectrodes in the case when stirring is not possible
Determination of hydroxyl groups in biorefinery resources via quantitative 31P NMR spectroscopy
The analysis of chemical structural characteristics of biorefinery product streams (such as lignin and tannin) has advanced substantially over the past decade, with traditional wet-chemical techniques being replaced or supplemented by NMR methodologies. Quantitative 31P NMR spectroscopy is a promising technique for the analysis of hydroxyl groups because of its unique characterization capability and broad potential applicability across the biorefinery research community. This protocol describes procedures for (i) the preparation/solubilization of lignin and tannin, (ii) the phosphitylation of their hydroxyl groups, (iii) NMR acquisition details, and (iv) the ensuing data analyses and means to precisely calculate the content of the different types of hydroxyl groups. Compared with traditional wet-chemical techniques, the technique of quantitative 31P NMR spectroscopy offers unique advantages in measuring hydroxyl groups in a single spectrum with high signal resolution. The method provides complete quantitative information about the hydroxyl groups with small amounts of sample (~30 mg) within a relatively short experimental time (~30-120 min)
Bright Side of Lignin Depolymerization:Toward New Platform Chemicals
Lignin,
a major component of lignocellulose, is the largest source
of aromatic building blocks on the planet and harbors great potential
to serve as starting material for the production of biobased products.
Despite the initial challenges associated with the robust and irregular
structure of lignin, the valorization of this intriguing aromatic
biopolymer has come a long way: recently, many creative strategies
emerged that deliver defined products via catalytic or biocatalytic
depolymerization in good yields. The purpose of this review is to
provide insight into these novel approaches and the potential application
of such emerging new structures for the synthesis of biobased polymers
or pharmacologically active molecules. Existing strategies for functionalization
or defunctionalization of lignin-based compounds are also summarized.
Following the whole value chain from raw lignocellulose through depolymerization
to application whenever possible, specific lignin-based compounds
emerge that could be in the future considered as potential lignin-derived
platform chemicals
A New Vanadium Catalyst for Chlorine Production by Hydrogen Chloride Oxidation
ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΠΏΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΡΠΉ Π²Π°Π½Π°Π΄ΠΈΠ΅Π²ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΠΎΠΊΠΈΡΠ»Π΅Π½ΠΈΡ Π΄ΠΈΠΎΠΊΡΠΈΠ΄Π° ΡΠ΅ΡΡ ΠΠ-1-6 Π°ΠΊΡΠΈΠ²Π΅Π½ Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ ΠΎΠΊΠΈΡΠ»Π΅Π½ΠΈΡ Ρ
Π»ΠΎΡΠΈΡΡΠΎΠ³ΠΎ Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Π° Π² ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΡΠΉ Ρ
Π»ΠΎΡ (ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΡΠ΅Π»ΡΠ½ΠΎΡΡΡ Π΄ΠΎ 180 Π³ΡΠ°ΠΌΠΌ Ρ
Π»ΠΎΡΠ° Π½Π° ΠΊΠΈΠ»ΠΎΠ³ΡΠ°ΠΌΠΌ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Π² ΡΠ°Ρ ΠΏΡΠΈ 400 ΠΎΠ‘). ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΡΡΠ°Π±ΠΈΠ»Π΅Π½ Π² ΡΠ΅ΡΠ΅Π½ΠΈΠ΅ 6 ΡΠ°ΡΠΎΠ² ΠΈ ΠΏΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ ΠΏΡΡΠΈ ΡΠΎΠ·Π΄Π°Π½ΠΈΡ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΠΎ ΡΠ°Π±ΠΎΡΠ°ΡΡΠ΅ΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΡΡΠ°Π½ΠΎΠ²ΠΊΠΈ Π΄Π»Ρ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Π° Ρ
Π»ΠΎΡΠ°.Industrial vanadia catalyst for SO2 oxidation, IK-1-6, was shown to be efficient in a process of hydrogen chloride oxidation into molecular chlorine. The productivity of the catalyst attains values of 180 grams of chlorine per kilogram of catalyst per hour at 400 oC. The catalyst was shown to be stable for 6 hours. A way to create a stable-operating catalytic system for chlorine production is suggested
A Novel Vanadium Catalyst for Oxidation of Hydrogen Chloride with Dioxygen
A novel catalytic system for oxidation of hydrogen chloride, V2O5-LiCl-KCl, has been studied. This
catalyst shows activity in a range of relatively low temperatures, 250 - 350 Β°C. Chlorine yield attains
200 - 780 g per kg of catalyst per hour at 350 Β°C, which greatly exceeds the characteristics of known
vanadium, copper and chromia catalysts
New Environmentally Benign Polymers Produced by Copolymerization with Ξ±-Angelicalactone
Study of Plant Growth Promoting Activity and Chemical Composition of Pine Bark after Various Storage Periods
Composition and content of terpene compounds in pine bark (Pinus sylvestris) after various storage
periods were studied by GLC-MS. Resin acids were found to be the main diterpenoic compounds in
the bark. Content of dehydroabietic acid in initial bark is 0.6 g/kg and it decreases three-fold after one
year of storage. High activity of pine bark after various storage periods towards risogenesis of wheat
(Triticum aestivum) was discovered. Strong correlation (r = 0.89) between growth promoting activity
of pine bark and content of dehydroabietic acid in it was found
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