Active Thrusting and Folding Along the Northern Tien Shan and Late Cenozoic Rotation of the Tarim Relative to Dzungaria and Kazakhstan

We have studied geometries and rates of late Cenozoic thrust faulting and folding along the northern piedmont of the Tien Shan mountain belt, West of Urumqi, where the M= 8.3 Manas earthquake occurred on December 23, 1906. The northern range of the Tien Shan, rising above 5000 m, overthrusts a flexural foredeep, filled with up to 11,000 m of sediment, of the Dzungarian basement. Our fieldwork reveals that the active thrust reaches the surface 30 km north of the range front, within a 200-km-long zone of Neogene-Quaternary anticlines. Fault scarps are clearest across inset terraces within narrow valleys incised through the anticlines by large rivers flowing down from the range. In all the valleys, the scarps offset vertically the highest terrace surface by the same amount (10.2±0.7 m). Inferring an early Holocene age (10±2 kyr) for this terrace, which is continuous with the largest recent fans of the piedmont, yields a rate of vertical throw of 1.0±0.3mm/yr on the main active thrust at the surface. A quantitative morphological analysis of the degradation of terrace edges that are offset by the thrust corroborates such a rate and yields a mass diffusivity of 5.5±2.5 m^2/kyr. A rather fresh surface scarp, 0.8±0.15 m high, that is unlikely to result from shallow earthquakes with 6 < M < 7 in the last 230 years, is visible at the extremities of the main fold zone. We associate this scarp with the 1906 Manas earthquake and infer that a structure comprising a deep basement ramp under the range, gently dipping flats in the foreland, and shallow ramps responsible for the formation of the active, fault propagation anticlines could have been activated by that earthquake. If so, the return period of a 1906 type event would be 850 ±380 years. The small size of the scarp for an earthquake of this magnitude suggests that a large fraction of the slip at depth (≈2/3) is taken up by incremental folding near the surface. Comparable earthquakes might activate flat detachments and ramp anticlines at a distance from the front of other rising Quaternary ranges such as the San Gabriel mountains in California or the Mont Blanc-Aar massifs in the Alps. We estimate the finite Cenozoic shortening of the folded Dzungarian sediments to be of the order of 30 km and the Cenozoic shortening rate to have been 3 ± 1.5 mm/yr. Assuming comparable shortening along the Tarim piedmont and minor additional active thrusting within the mountain belt, we infer the rate of shortening across the Tien Shan to be at least 6 ± 3 mm/yr at the longitude of Manas (≈85.5°E). A total shortening of 125±30 km is estimated from crustal thickening, assuming local Airy isostatic equilibrium. Under the same assumption, serial N-S sections imply that Cenozoic shortening across the belt increases westwards to 203±50 km at the longitude of Kashgar (≈ 76 °E), as reflected by the westward increase of the width of the belt. This strain gradient implies a clockwise rotation of Tarim relative to Dzungaria and Kazakhstan of 7±2.5° around a pole located near the eastern extremity of the Tien Shan, west of Hami (≈96°E, 43.5°N), comparable to that revealed by paleomagnetism between Tarim and Dzungaria (8.6° ± 8.7°). A 6 mm/yr rate of shortening at the longitude of Manas would imply a rate of rotation of 0.45°/m.y. and would be consistent with a shortening rate of 12 mm/yr north of Kashgar. Taking such values to be representative of Late Cenozoic rates would place the onset of reactivation of the Tien Shan by the India-Asia collision in the early to middle Miocene (16 +22/−9 m.y.), in accord with the existence of particularly thick late Neogene and Quaternary deposits. Such reactivation would thus have started much later than the collision, roughly at the time of the great mid-Miocene changes in tectonic regimes, denudation and sedimentation rates observed in southeast Asia, the Himalayas and the Bay of Bengal, and of the correlative rapid change in seawater Sr isotopic ratio (20 to 15 Ma). Like these other changes, the rise of the Tien Shan might be a distant consequence of the end of Indochina's escape

Towards a spatially and temporally constant Karakorum fault slip rate

Abstract HKT-ISTP 2013 A

Chemical changes in PCPDTBT:PCBM solar cells using XPS and TOF-SIMS and use of inverted device structure for improving lifetime performance

Analysis of the degradation routes for poly[(4,4-bis(2-ethylhexyl)-cyclopenta-[2,1-b;3,4-b′]dithiophene)-2,6-diyl-alt-2,1,3-benzothiadiazole-4,7-diyl] (PCPDTBT)-based solar cells under illumination and in the presence of air have been conducted using a combination of X-ray Photoelectron Spectroscopy (XPS), Time-Of-Flight Secondary Ion Mass Spectrometry (TOF-SIMs) and solar cell device data. After ageing, XPS studies show that PCPDTBT appears as an oxygen-containing polymer, with data indicating that a break-up in the aromatic rings, formation of sulphates at the thiophene ring, chain scission in the polymer backbone and also loss of side chains. XPS studies have also been conducted on Phenyl-C71-butyric acid methyl ester (PC71BM) films and show a breakage of the fullerene cage, loss of molecular shape and oxidation of carbon atoms in the fullerene cage and side chains after ageing. XPS studies on active layers blends of PCPDTBT and PCBM also show significant changes in the vertical composition during ageing, with increased enrichment of PCPDTBT observed at the top surface and that the use of a processing additive (ODT) has a negative impact on the morphological stability. Based on these studies, it shown that inverted structures are better suited than non-inverted devices for PCPDTBT:PCBM solar cells. An additional advantage of inverted devices is shown using TOF-SIMS; electrode degradation during ageing experiments leads to migration of indium and tin ions into the active layer in non-inverted devices, but is eliminated for inverted devices.HW would like to thank Bangor University for financial support through his “125 scholarship” from the University. ZD is supported from the “SteelPV” project, which is funded from the EC’s Research Fund for Coal and Steel (RFCS) research programme under grant agreement number RFSR-CT-2014-00014. Finally, JK would like to thank the Royal Academy of Engineering for funding via the Newton Research Collaboration Programme (NRCP/1415/28)

Performance of highly sensitive cardiac troponin T assay to detect ischaemia at PET-CT in low-risk patients with acute coronary syndrome: a prospective observational study.

Highly sensitive troponin T (hs-TnT) assay has improved clinical decision-making for patients admitted with chest pain. However, this assay's performance in detecting myocardial ischaemia in a lowrisk population has been poorly documented. To assess hs-TnT assay's performance to detect myocardial ischaemia at positron emission tomography/CT (PET-CT) in low-risk patients admitted with chest pain. Patients admitted for chest pain with a nonconclusive ECG and negative standard cardiac troponin T results at admission and after 6 hours were prospectively enrolled. Their hs-TnT samples were at T0, T2 and T6. Physicians were blinded to hs-TnT results. All patients underwent a PET-CT at rest and during adenosine-induced stress. All patients with a positive PET-CT result underwent a coronary angiography. Forty-eight patients were included. Six had ischaemia at PET-CT. All of them had ≥1 significant stenosis at coronary angiography. Areas under the curve (95% CI) for predicting significant ischaemia at PET-CT using hs-TnT were 0.764 (0.515 to 1.000) at T0, 0.812(0.616 to 1.000) at T2 and 0.813(0.638 to 0.989) at T6. The receiver operating characteristicbased optimal cut-off value for hs-TnT at T0, T2 and T6 needed to exclude significant ischaemia at PET-CT was &lt;4 ng/L. Using this value, sensitivity, specificity, positive and negative predictive values of hs-TnT to predict significant ischaemia were 83%/38%/16%/94% at T0, 100%/40%/19%/100% at T2 and 100%/43%/20%/100% at T6, respectively. Our findings suggest that in low-risk patients, using the hs-TnT assay with a cut-off value of 4 ng/L demonstrates excellent negative predictive value to exclude myocardial ischaemia detection at PET-CT, at the expense of weak specificity and positive predictive value. ClinicalTrials.gov Identifier: NCT01374607

Applications of Morphochronology to the Active Tectonics of Tibet

The Himalayas and the Tibetan Plateau were formed as a result of the collision of India and Asia, and provide an excellent opportunity to study the mechanical response of the continental lithosphere to tectonic stress. Geophysicists are divided in their views on the nature of this response advocating either (1) homogeneously distributed deformation with the lithosphere deforming as a fluid continuum or (2) deformation is highly localized with the lithosphere that deforms as a system of blocks. The resolution of this issue has broad implications for understanding the tectonic response of continental lithosphere in general. Homogeneous deformation is supported by relatively low decadal, geodetic slip-rate estimates for the Altyn Tagh and Karakorum Faults. Localized deformation is supported by high millennial, geomorphic slip-rates constrained by both cosmogenic and radiocarbon dating on these faults. Based upon the agreement of rates determined by radiocarbon and cosmogenic dating, the overall linearity of offset versus age correlations, and on the plateau-wide correlation of landscape evolution and climate history, the disparity between geomorphic and geodetic slip-rate determinations is unlikely to be due to the effects of surface erosion on the cosmogenic age determinations. Similarly, based upon the consistency of slip-rates over various observation intervals, secular variations in slip-rate appear to persist no longer than 2000 years and are unlikely to provide reconciliation. Conversely, geodetic and geomorphic slip-rate estimates on the Kunlun fault, which does not have significant splays or associated thrust faults, are in good agreement, indicating that there is no fundamental reason why these complementary geodetic and geomorphic methods should disagree. Similarly, the geodetic and geomorphic estimates of shortening rates across the northeastern edge of the plateau are in reasonable agreement, and the geomorphic rates on individual thrust faults demonstrate a significant eastward decrease in the shortening rate. This rate decrease is consistent with the transfer of slip from the Altyn Tagh Fault (ATF) to genetically-related thrust mountain building at its terminus. Rates on the ATF suggest a similar decrease in rate, but the current data set is too small to be definitive. Overall, the high, late Pleistocene-Holocene, geomorphic slip velocities on the major strike-slip faults of Tibet, suggests that they absorb as much of India's convergence relative to Siberia as the Himalayan Main Frontal Thrust on the southern edge of the plateau

Thermochronologic constraints on the late Cenozoic exhumation history of the Gurla Mandhata metamorphic core complex, Southwestern Tibet

This is the publisher's version, also available electronically from http://onlinelibrary.wiley.com/doi/10.1002/2013TC003302/abstractHow the Tibetan plateau is geodynamically linked to the Himalayas is a topic receiving considerable attention. The Karakoram fault plays key roles in describing the structural relationship between southern Tibet and the Himalayas. In particular, considerable debate exists at the southeastern end of the Karakoram fault, where its role is interpreted in two different ways. One interpretation states that slip along the dextral Karakoram fault extends eastward along the Indus-Yalu suture zone, bypassing the Himalayas. The other interprets that fault slip is fed southward into the Himalayan thrust belt along the Gurla Mandhata detachment (GMD). To evaluate these competing models, the late Miocene history of the GMD was reconstructed from thermokinematic modeling of zircon (U-Th)/He data. Three east-west transects reveal rapid cooling of the GMD footwall from 8.0 ± 1.3 Ma to 2.6 ± 0.7 Ma. Model simulations show a southward decrease in slip magnitude and rate along the GMD. In the north, initiation of the GMD range between 14 and 11 Ma with a mean fault slip rate of 5.0 ± 0.9 mm/yr. The central transect shows an initiation age from 14 to 11 Ma with a mean fault slip rate of 3.3 ± 0.6 mm/yr. In the south, initiation began between 15 and 8 Ma with a mean fault slip rate of 3.2 ± 1.6 mm/yr. The initiation ages and slip rates match the Karakoram fault across several timescales, supporting the idea that the two are kinematically linked. Specifically, the data are consistent with the GMD acting as an extensional stepover, with slip transferred southward into the Himalayas of western Nepal

Effects of crystallographic anisotropy on fracture development and acoustic emission in quartz

Transgranular microcracking is fundamental for the initiation and propagation of all fractures in rocks. The geometry of these microcracks is primarily controlled by the interaction of the imposed stress field with the mineral elastic properties. However, the effects of anisotropic elastic properties of minerals on brittle fracture are not well understood. This study examines the effects of elastic anisotropy of quartz on the geometry of brittle fracture and related acoustic emissions (AE) developed during indentation experiments on single crystals at ambient pressure and temperature. A Hertzian cone crack developed during blunt indentation of a single crystal of flawless Brazilian quartz parallel to the c axis shows geometric deviation away from predictions based on the isotropic case, consistent with trigonal symmetry. The visible cone crack penetration depth varies from 3 to 5 mm and apical angle from 53 to 40. Electron backscatter diffraction (EBSD) mapping of the crack tip shows that fracturing initiates along a ~40 μm wide process zone, comprising damage along overlapping en echelon high-index crystallographic planes, shown by discrete bands of reduced electron backscatter pattern (EBSP) quality (band contrast).Coalescence of these surfaces results in a stepped fracture morphology. Monitoring of AE during indentation reveals that the elastic anisotropy of quartz has a significant effect on AE location and focal mechanisms. Ninety-four AE events were recorded during indentation and show an increasing frequency with increasing load. They correspond to the development of subsidiary concentric cracks peripheral to the main cone crack. The strong and complex anisotropy in seismic velocity (~28% Vp, ~43% Vs with trigonal symmetry) resulted in inaccurate and high uncertainty in AE locations using Geiger location routine with an isotropic velocity model. This problem was overcome by using a relative (master event) location algorithm that only requires a priori knowledge of the velocity structure within the source volume. The AE location results correlate reasonably well to the extent of the observed cone crack. Decomposition of AE source mechanisms of the Geiger relocated events shows dominantly end-member behavior between tensile and compressive vector dipole events, with some double-couple-dominated events and no purely tensile or compressive events. The same events located by the master event algorithm yield greater percentage of vector dipole components and no double-couple events, indicating that AE source mechanism solutions can depend on AE location accuracy, and therefore, relocation routine that is utilized. Calculations show that the crystallographic anisotropy of quartz causes apparent deviation of the moment tensors away from double-couple and pure tensile/compressive sources consistent with the observations. Preliminary modeling of calcite anisotropy shows a response distinct from quartz, indicating that the effects of anisotropy on interpreting AE are complex and require detailed further study

The Mw = 6.3, November 21, 2004, Les Saintes earthquake (Guadeloupe): Tectonic setting, slip model and static stress changes,

International audienceOn November 21, 2004, a magnitude 6.3 earthquake occurred offshore, 10 km south of Les Saintes archipelago in Guadeloupe (French West Indies). There were more than 30000 aftershocks recorded in the following two years, most of them at shallow depth near the islands of the archipelago. The main shock and its main aftershock of February 14, 2005 (Mw = 5.8) ruptured a NE-dipping normal fault (Roseau fault), mapped and identified as active from high-resolution bathymetric data a few years before. This fault belongs to an arc-parallel en echelon fault system that follows the inner edge of the northern part of the Lesser Antilles arc, accommodating the sinistral component of oblique convergence between the North American and Caribbean plates. The distribution of aftershocks and damage (destruction and landslides) are consistent with the main fault plane location and attitude. The slip model of the main shock, obtained by inverting jointly global broadband and local strong motion records, is characterized by two main slip zones located 5 to 10 km to the SE and NW of the hypocenter. The main shock is shown to have increased the Coulomb stress at the tips of the ruptured plane by more than 4 bars where most of the aftershocks occurred, implying that failures on fault system were mainly promoted by static stress changes. The earthquake also had an effect on volcanic activity since the Boiling Lake in Dominica drained twice, probably as a result of the extensional strain induced by the earthquake and its main aftershock