98 research outputs found

    Oxygen-doped zig-zag molecular ribbons

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    The synthesis of a zig‐zag oxygen‐doped molecular rhombic ribbon has been achieved. This includes oxidative C−C and C−O bond formations that allowed the stepwise elongation and planarization of an oxa‐congener of 2,7‐periacenoacene. X‐ray diffraction analysis corroborated the flat structure and the zig‐zag topology of the O‐doped edges. Photophysical and electrochemical investigations showed that the extension of the peri‐xanthenoxanthene (PXX) into the molecular ribbon induces a noticeable shrinking of the molecular band gap devised by a rising of the HOMO energy level, a desirable property for p‐type organic semiconductors

    Total and differential cross sections of η-production in proton–deuteron fusion for excess energies between Qη = 13 MeV and Qη = 81 MeV

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    New data on both total and differential cross sections of the production of η mesons in proton–deuteron fusion to He3η in the excess energy region 13.6MeV≤Qη≤80.9MeV are presented. These data have been obtained with the WASA-at-COSY detector setup located at the Forschungszentrum Jülich, using a proton beam at 15 different beam momenta between pp=1.60GeV/c and pp=1.74GeV/c. While significant structure of the total cross section is observed in the energy region 20MeV≲Qη≲60MeV, a previously reported sharp variation around Qη≈50MeV cannot be confirmed. Angular distributions show the typical forward-peaking that was noted earlier. For the first time, it is possible to study the development of these angular distributions with rising excess energy over a wide interval

    The developing person through life span

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    xxxv, 787 p., A-19,B-5,G-15,R-72,NI-23,SI-36;28 c

    Why Campaigns Don't Matter (As Much As You Think)

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    The 2012 presidential election featured a series of so-called "game-changers" -- Obama's and Romney's gaffes, the 47% video, the first debate, Hurricane Sandy, and so on. While press coverage of the campaign lavished attention on these and other campaign dramas, John Sides argues that campaigns don't matter as much as many think. What really drives campaigns and how should the parties prepare for the next epic battle?Center for the Study of Politics and Governance, Humphrey School of Public Affairs, UM
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