The case of TUI : sailing into a bright future or sinking like Thomas Cook?

In the rapidly changing environment of the tourism industry, it becomes crucial for its players to adapt to exogenous factors in order to stay competitive and profitable in the long run. As an increasing number of tourists were individually booking their holidays through online booking portals, the business model of pure tour operators was being undermined. While some players, like TUI, saw the digitalization as an opportunity to change its business model, others, like Thomas Cook, failed to adapt. The case of TUI, one of the largest tourism groups worldwide, serves as an example of a successful strategic change and fit to environmental and organizational contingencies. The case demonstrates how TUI transformed its business model from a traditional tour operator towards a fully vertically integrated provider of holiday experiences. The new management introduced a strategic initiative in 2013, which involved the important merger of the parent company TUI AG with its subsidiary TUI Travel to reach full vertical integration. Thereafter, TUI highly invested in assets in terms of hotels and cruise ships as well as destination experiences. It illustrates, that the management made use of Dynamic Capabilities and changed the company’s resource base through the corporate strategy of vertical integration, in particular in the form of taper integration. Although the strategic change had proven to be successful, the vertical integration exposed the group to enormous financial challenges, when the corona pandemic brought the world to a standstill in 2020.Num ambiente em rápida mudança, como o da indústria do turismo, torna-se crucial que as empresas se adaptem a fatores exógenos para permanecerem competitivas e lucrativas a longo prazo. Com um número crescente de turistas a reservar as suas férias individualmente on-line, o modelo de negócios dos operadores turísticos puros foi posto em causa. Enquanto alguns players, como a TUI, viram a digitalização como uma oportunidade para mudar o seu modelo de negócios, outros, como a Thomas Cook, não conseguiram adaptar-se. O caso da TUI, um dos maiores grupos turísticos do mundo, serve como exemplo de uma mudança estratégica bem-sucedida e adequada às contingências ambientais e organizacionais. O caso demonstra como a TUI transformou o seu modelo de negócios, de uma operadora de turismo tradicional para um fornecedor de experiências de férias totalmente integrado verticalmente. A nova administração introduziu, em 2013, uma iniciativa estratégica que envolveu a importante fusão da empresa-mãe TUI AG com a sua subsidiária TUI Travel para alcançar uma integração vertical completa. Posteriormente, a TUI investiu muito em ativos, tais como hotéis e navios de cruzeiro, bem como em experiências nos destinos de férias. O caso ilustra como a gestão de topo utilizou as dynamic capabilities para mudar a base de recursos da empresa por meio duma estratégia corporativa de integração vertical, em particular na forma duma ‘taper integration’. Embora a mudança estratégica tenha sido bem-sucedida, a integração vertical expôs o grupo a enormes desafios financeiros, quando a pandemia causada pelo coronavírus parou o mundo em 2020

„Aggressive Flüchtlinge, gewaltbereite Hooligans, verunsicherte Bürger“

Unser Beitrag untersucht anhand ausgewählter Medienberichte aus dem Jahr 2018, wie Mediatisierungen von Migration und Konflikt in ostdeutschen Städten mehrdimensionale Prozesse des Othering (Veranderung) (re)produzieren. Angelehnt an das Instrumentarium der wissenssoziologischen Diskursanalyse (Keller 2011) rekonstruieren wir spezifische Deutungsmuster und Subjektpositionen, die ethnosexuelle und räumlich-kulturell-zeitliche Formen der Grenzziehung aufrufen. Durch die Kombination von postkolonialen und postsozialistischen Perspektiven beleuchten wir, wie die Prozesse des Othering mit essentialisierenden sowie homogenisierenden Vorstellungen von nationaler Zugehörigkeit einhergehen

From Lab to Pilot Scale: Commissioning of an Integrated Device for the Generation of Crystals

Fast time-to-market, increased efficiency, and flexibility of production processes are major motivators for the development of integrated, continuous apparatuses with short changeover times. Following this trend, the modular belt crystallizer was developed and characterized in lab scale with the model system sucrose-water. Based on the promising results, the plant concept was upscaled and commissioned in industrial environment. The results are presented within the scope of this work. Starting from small seed crystals in solution, it was possible to grow, separate, and dry product particles. Further, the conducted experiments demonstrated that it is feasible to transfer the results from laboratory to pilot scale, which in turn enables accelerated process design as well as development

Coupling Broadband Terahertz Dipoles to Microscale Resonators

Optically driven spintronic emitters are a unique class of terahertz (THz) sources due to their quasi-two-dimensional geometry and thereby their capability to effectively couple to resonator near fields. Global excitation of the emitters often obstructs the intricate details of the coupling mechanisms between local THz dipoles and the individual modes of resonator structures. Here, we demonstrate the spatial mapping of the coupling strength between a micrometer-scale terahertz source on a spintronic emitter and far-field light mediated by a structured metallic environment. For a bow-tie geometry, experimental results are reproduced by a numerical model, providing insights into the microscopic coupling mechanisms. The broad applicability of the technique is showcased by extracting the THz mode structure in split-ring resonator metasurfaces and linear arrays. With these developments, planar THz sources with tailored spectral and angular emission profiles become accessible

Trifluoromethylation of a well-defined square-planar Aryl-NiII complex involving NiIII/CF3 and NiIV−CF3 intermediate species

Ni-mediated trifluoromethylation of an aryl−Br bond in model macrocyclic ligands (Ln−Br) has been thoroughly studied, starting with an oxidative addition at Ni0 to obtain well-defined aryl-NiII-Br complexes ([Ln−NiII]Br). Abstraction of the halide with AgX (X=OTf− or ClO4−) thereafter provides [Ln−NiII](OTf). The nitrate analogue has been obtained through a direct C−H activation of an aryl−H bond using NiII salts, and this route has been studied by X-ray absorption spectroscopy (XAS). Crystallographic XRD and XAS characterization has shown a tight macrocyclic coordination in the aryl−NiII complex, which may hamper direct reaction with nucleophiles. On the contrary, enhanced reactivity is observed with oxidants, and the reaction of [Ln−NiII](OTf) with CF3+ sources afforded Ln−CF3 products in quantitative yield. A combined experimental and theoretical mechanistic study provides new insights into the operative mechanism for this transformation. Computational analysis indicates the occurrence of an initial single electron transfer (SET) to 5-(trifluoromethyl)dibenzothiophenium triflate (TDTT), producing a transient L1−NiIII/CF3. adduct, which rapidly recombines to form a [L1-NiIV-CF3](X)2 intermediate species. A final facile reductive elimination affords L1−CF3. The well-defined square-planar model system studied here permits to gain fundamental knowledge on the rich redox chemistry of nickel, which is sought to facilitate the development of new Ni-based trifluoromethylation methodologies

Late Quaternary climate and environmental reconstruction based on leaf wax analyses in the loess sequence of Möhlin, Switzerland

We present the results of leaf wax analyses (long-chain n-alkanes) from the 6.8 m deep loess sequence of Möhlin, Switzerland, spanning the last  ∼  70 kyr. Leaf waxes are well preserved and occur in sufficient amounts only down to 0.4 m and below 1.8 m depth, so no paleoenvironmental reconstructions can be done for marine isotope stage (MIS) 2. Compound-specific δ2Hwax analyses yielded similar values for late MIS 3 compared to the uppermost samples, indicating that various effects (e.g., more negative values due to lower temperatures, more positive values due to an enriched moisture source) cancel each other out. A pronounced  ∼  30 ‰ shift towards more negative values probably reflects more humid conditions before  ∼  32 ka. Radiocarbon dating of the n-alkanes corroborates the stratigraphic integrity of leaf waxes and their potential for dating loess–paleosol sequences (LPS) back to  ∼  30 ka

Advances in air quality research – current and emerging challenges

© Author(s) 2022. This work is distributed under the Creative Commons Attribution 4.0 License. https://creativecommons.org/licenses/by/4.0/This review provides a community’s perspective on air quality research focusing mainly on developmentsover the past decade. The article provides perspectives on current and future challenges as well asresearch needs for selected key topics. While this paper is not an exhaustive review of all research areas in thefield of air quality, we have selected key topics that we feel are important from air quality research and policy perspectives. After providing a short historical overview, this review focuses on improvements in characterizingsources and emissions of air pollution, new air quality observations and instrumentation, advances in air qualityprediction and forecasting, understanding interactions of air quality with meteorology and climate, exposure andhealth assessment, and air quality management and policy. In conducting the review, specific objectives were(i) to address current developments that push the boundaries of air quality research forward, (ii) to highlightthe emerging prominent gaps of knowledge in air quality research, and (iii) to make recommendations to guidethe direction for future research within the wider community. This review also identifies areas of particular importancefor air quality policy. The original concept of this review was borne at the International Conferenceon Air Quality 2020 (held online due to the COVID 19 restrictions during 18–26 May 2020), but the articleincorporates a wider landscape of research literature within the field of air quality science. On air pollutionemissions the review highlights, in particular, the need to reduce uncertainties in emissions from diffuse sources,particulate matter chemical components, shipping emissions, and the importance of considering both indoor andoutdoor sources. There is a growing need to have integrated air pollution and related observations from bothground-based and remote sensing instruments, including in particular those on satellites. The research shouldalso capitalize on the growing area of low-cost sensors, while ensuring a quality of the measurements which areregulated by guidelines. Connecting various physical scales in air quality modelling is still a continual issue,with cities being affected by air pollution gradients at local scales and by long-range transport. At the same time,one should allow for the impacts from climate change on a longer timescale. Earth system modelling offers considerablepotential by providing a consistent framework for treating scales and processes, especially where thereare significant feedbacks, such as those related to aerosols, chemistry, and meteorology. Assessment of exposureto air pollution should consider the impacts of both indoor and outdoor emissions, as well as application of moresophisticated, dynamic modelling approaches to predict concentrations of air pollutants in both environments.With particulate matter being one of the most important pollutants for health, research is indicating the urgentneed to understand, in particular, the role of particle number and chemical components in terms of health impact,which in turn requires improved emission inventories and models for predicting high-resolution distributions ofthese metrics over cities. The review also examines how air pollution management needs to adapt to the abovementionednew challenges and briefly considers the implications from the COVID-19 pandemic for air quality.Finally, we provide recommendations for air quality research and support for policy.Peer reviewe

Advances in air quality research – current and emerging challenges

This review provides a community\u27s perspective on air quality research focusing mainly on developments over the past decade. The article provides perspectives on current and future challenges as well as research needs for selected key topics. While this paper is not an exhaustive review of all research areas in the field of air quality, we have selected key topics that we feel are important from air quality research and policy perspectives. After providing a short historical overview, this review focuses on improvements in characterizing sources and emissions of air pollution, new air quality observations and instrumentation, advances in air quality prediction and forecasting, understanding interactions of air quality with meteorology and climate, exposure and health assessment, and air quality management and policy. In conducting the review, specific objectives were (i) to address current developments that push the boundaries of air quality research forward, (ii) to highlight the emerging prominent gaps of knowledge in air quality research, and (iii) to make recommendations to guide the direction for future research within the wider community. This review also identifies areas of particular importance for air quality policy. The original concept of this review was borne at the International Conference on Air Quality 2020 (held online due to the COVID 19 restrictions during 18–26 May 2020), but the article incorporates a wider landscape of research literature within the field of air quality science. On air pollution emissions the review highlights, in particular, the need to reduce uncertainties in emissions from diffuse sources, particulate matter chemical components, shipping emissions, and the importance of considering both indoor and outdoor sources. There is a growing need to have integrated air pollution and related observations from both ground-based and remote sensing instruments, including in particular those on satellites. The research should also capitalize on the growing area of low-cost sensors, while ensuring a quality of the measurements which are regulated by guidelines. Connecting various physical scales in air quality modelling is still a continual issue, with cities being affected by air pollution gradients at local scales and by long-range transport. At the same time, one should allow for the impacts from climate change on a longer timescale. Earth system modelling offers considerable potential by providing a consistent framework for treating scales and processes, especially where there are significant feedbacks, such as those related to aerosols, chemistry, and meteorology. Assessment of exposure to air pollution should consider the impacts of both indoor and outdoor emissions, as well as application of more sophisticated, dynamic modelling approaches to predict concentrations of air pollutants in both environments. With particulate matter being one of the most important pollutants for health, research is indicating the urgent need to understand, in particular, the role of particle number and chemical components in terms of health impact, which in turn requires improved emission inventories and models for predicting high-resolution distributions of these metrics over cities. The review also examines how air pollution management needs to adapt to the above-mentioned new challenges and briefly considers the implications from the COVID-19 pandemic for air quality. Finally, we provide recommendations for air quality research and support for policy