Observation of Quantum Effects in sub Kelvin Cold Reactions

There has been a long-standing quest to observe chemical reactions at low temperatures where reaction rates and pathways are governed by quantum mechanical effects. So far this field of Quantum Chemistry has been dominated by theory. The difficulty has been to realize in the laboratory low enough collisional velocities between neutral reactants, so that the quantum wave nature could be observed. We report here the first realization of merged neutral supersonic beams, and the observation of clear quantum effects in the resulting reactions. We observe orbiting resonances in the Penning ionization reaction of argon and molecular hydrogen with metastable helium leading to a sharp increase in the absolute reaction rate in the energy range corresponding to a few degrees kelvin down to 10 mK. Our method is widely applicable to many canonical chemical reactions, and will enable a breakthrough in the experimental study of Quantum Chemistry

Reactions of C+ + Cl-, Br-, and I--A comparison of theory and experiment.

Rate constants for the reactions of C+ + Cl-, Br-, and I- were measured at 300 K using the variable electron and neutral density electron attachment mass spectrometry technique in a flowing afterglow Langmuir probe apparatus. Upper bounds of <10-8 cm3 s-1 were found for the reaction of C+ with Br- and I-, and a rate constant of 4.2 ± 1.1 × 10-9 cm3 s-1 was measured for the reaction with Cl-. The C+ + Cl- mutual neutralization reaction was studied theoretically from first principles, and a rate constant of 3.9 × 10-10 cm3 s-1, an order of magnitude smaller than experiment, was obtained with spin-orbit interactions included using a semiempirical model. The discrepancy between the measured and calculated rate constants could be explained by the fact that in the experiment, the total loss of C+ ions was measured, while the theoretical treatment did not include the associative ionization channel. The charge transfer was found to take place at small internuclear distances, and the spin-orbit interaction was found to have a minor effect on the rate constant

A laser based accelerator for ultracold atoms

We present first results on our implementation of a laser based accelerator for ultracold atoms. Atoms cooled to a temperature of 420 nK are confined and accelerated by means of laser tweezer beams and the atomic scattering is directly observed in laser absorption imaging. The optical collider has been characterized using Rb87 atoms in the |F=2,mF=2> state, but the scheme is not restricted to atoms in any particular magnetic substates and can readily be extended to other atomic species as well.Comment: (c) 2012 The Optical Society, 3 pages, 4 figures, 1 movie lin

Providing immediate neonatal care and resuscitation at birth beside the mother: parents' views, a qualitative study

Objectives: The aims of this study were to assess parents’ views of immediate neonatal care and resuscitation at birth being provided beside the mother, and their experiences of a mobile trolley designed to facilitate this bedside care. Design: Qualitative study with semistructured interviews. Results were analysed using thematic analysis. Setting: Large UK maternity hospital. Participants: Mothers whose baby received initial neonatal care in the first few minutes of life at the bedside, and their birth partners, were eligible. 30 participants were interviewed (19 mothers, 10 partners and 1 grandmother). 5 babies required advanced neonatal resuscitation. Results: 5 themes were identified: (1) Reassurance, which included ‘Baby is OK’, ‘Having baby close’, ‘Confidence in care’, ‘Knowing what's going on’ and ‘Dad as informant’; (2) Involvement of the family, which included ‘Opportunity for contact’, ‘Family involvement’ and ‘Normality’; (3) Staff communication, which included ‘Communication’ and ‘Experience’; (4) Reservations, which included ‘Reservations about witnessing resuscitation’, ‘Negative emotions’ and ‘Worries about the impact on staff’ and (5) Experiences of the trolley, which included ‘Practical issues’ and ‘Comparisons with standard resuscitation equipment’. Conclusions: Families were positive about neonatal care being provided at the bedside, and felt it gave reassurance about their baby's health and care. They also reported feeling involved as a family. Some parents reported experiencing negative emotions as a result of witnessing resuscitation of their baby. Parents were positive about the trolley

Nucleon Spin Fluctuations and the Supernova Emission of Neutrinos and Axions

In the hot and dense medium of a supernova (SN) core, the nucleon spins fluctuate so fast that the axial-vector neutrino opacity and the axion emissivity are expected to be significantly modified. Axions with m_a\alt10^{-2}\,{\rm eV} are not excluded by SN~1987A. A substantial transfer of energy in neutrino-nucleon ($\nu N$) collisions is enabled which may alter the spectra of SN neutrinos relative to calculations where energy-conserving $\nu N$ collisions had been assumed near the neutrinosphere.Comment: 8 pages. REVTeX. 2 postscript figures, can be included with epsf. Small modifications of the text, a new "Note Added", and three new references. To be published in Phys. Rev. Let

Irrigated lands assessment for water management: Technique test

A procedure for estimating irrigated land using full frame LANDSAT imagery was demonstrated. Relatively inexpensive interpretation of multidate LANDSAT photographic enlargements was used to produce a map of irrigated land in California. The LANDSAT and ground maps were then linked by regression equations to enable precise estimation of irrigated land area by county, basin, and statewide. Land irrigated at least once in California in 1979 was estimated to be 9.86 million acres, with an expected error of less than 1.75% at the 99% level of confidence. To achieve the same level of error with a ground-only sample would have required 3 to 5 times as many ground sample units statewide. A procedure for relatively inexpensive computer classification of LANDSAT digital data to irrigated land categories was also developed. This procedure is based on ratios of MSS band 7 and 5, and gave good results for several counties in the Central Valley

Guidance and standard operating procedures for functional exercise testing in cystic fibrosis

Regular exercise testing is recommended for all people with cystic fibrosis (PwCF). A range of validated tests, which integrate both strength and aerobic function, are available and increasingly being used. Together, these tests offer the ability for comprehensive exercise evaluation. Extensive research and expert consensus over recent years has enabled the adaptation and standardisation of a range of exercise tests to aid the understanding of the pathophysiology related to exercise limitation in PwCF and has led to the development of novel exercise tests which may be applied to PwCF. This article provides expert, opinion-based clinical practice guidance, along with test instructions, for a selection of commonly used valid tests which have documented clinimetric properties for PwCF. Importantly, this document also highlights previously used tests that are no longer suggested for PwCF and areas where research is mandated. This collaboration, on behalf of the European Cystic Fibrosis Society Exercise Working Group, represents expert consensus by a multidisciplinary panel of physiotherapists, exercise scientists and clinicians and aims to improve global standardisation of functional exercise testing of PwCF. In short, the standardised use of a small selection of tests performed to a high standard is advocated

Getting It on Record: Issues and Strategies for Ethnographic Practice in Recording Studios

The recording studio has been somewhat neglected as a site for ethnographic fieldwork in the field of ethno-musicology and, moreover, the majority of published studies tend to overlook the specific concerns faced by the researcher within these contexts. Music recording studios can be places of creativity, artistry, and collaboration, but they often also involve challenging, intimidating, and fractious relations. Given that recording studios are, first and foremost, concerned with documenting musicians’ performances, we discuss the concerns of getting studio interactions “on record” in terms of access, social relations, and methods of data collection. This article reflects on some of the issues we faced when conducting our fieldwork within British music recording facilities and makes suggestions based on strategies that we employed to address these issues

Psychosocial correlates of attitudes towards male sexual violence in a sample of financial crime, property crime, general violent, and homicide offenders

Whilst those currently serving prison sentences for sexual violence can be identified and receive treatment, the number of prisoners with a history of sexual violence against female partners is unknown. Methods to identify prisoners with a proclivity for such violence and accurately assess the risk they pose before and after incarceration are therefore required. Here, we aimed to assess the level of sexually violent attitudes within dating relationships and to examine their associations with experiences of child abuse and neglect (CAN), psychopathic personality traits, prisonization, number of incarcerations, age, years of schooling, relationship status, and parenting among different types of offenders (financial crime, property crime, general violent, and homicide offenders). Data were collected among a large systematically selected sample of adult male inmates (N = 1,123). We demonstrated that sexual violence-supportive attitudes appear to be a function of child sexual abuse, psychopathic personality traits, and may be developed through early socialisation experiences as well as incarceration. Practical implications of current findings are discussed

A dual process account of creative thinking

This article explicates the potential role played by type 1 thinking (automatic, fast) and type 2 thinking (effortful, logical) in creative thinking. The relevance of Evans's (2007) models of conflict of dual processes in thinking is discussed with regards to creative thinking. The role played by type 1 thinking and type 2 thinking during the different stages of creativity (problem finding and conceptualization, incubation, illumination, verification and dissemination) is discussed. It is proposed that although both types of thinking are active in creativity, the extent to which they are active and the nature of their contribution to creativity will vary between stages of the creative process. Directions for future research to test this proposal are outlined; differing methodologies and the investigation of different stages of creative thinking are discussed. © Taylor & Francis Group, LLC