Polímeros bioplásticos de fontes renováveis

Biopolymers are useful in the industry due to its elastic properties and sustainability as replacements of non-renewable polymers. In this article, bioplastics were produced and characterized using chitosan (CH), sodium alginate (SA), and galactomannan (GAL) from insects (Hermetia illucens), brown algae (Macrocystis pyrifera) and seeds (Leucaena leucocephala), respectively. The structure of biopolymers was observed by infrared spectroscopy (FTIR) and characterized by viscosity at different concentrations. The developed bioplastics were characterized by color and mechanical properties (texture). The results were compared to standard samples (commercial). The FTIR spectra confrmed the presence of the typical structure (footprint) for the obtained polymers. The SA showed signifcantly higher viscosity for all concentrations comparedto the standard and the other polymers. The bioplastics strength was similar among CH, SA and GAL for all concentrations; only SA (0,5%) demonstrated higher strength than the standard. For color measurements, hue value indicated a red-yellowish color and the chrome increased directly proportional with polymer concentration. The observed properties suggest that these sustainable sources might be an alternativeto bioplastic production, which can be extended to functionalization and molecular interactions for broad applications in different industries.Los biopolímeros son útiles en la industria por sus propiedades elásticas y su carácter sustentable en el reemplazo de polímeros no renovables. En este artículo se elaboraron y caracterizaron bioplásticos utilizando quitosano (CH), alginato de sodio (SA) y galactomanano (GAL) a partir de insectos (Hermetia illucens), algas pardas (Macrocystis pyrifera) y semillas (Leucaena leucocephala), respectivamente. La estructura de losbiopolímeros se observó por espectroscopía de infrarrojo (FTIR) y se caracterizó en viscosidad a diferentes concentraciones, y los bioplásticos desarrollados se caracterizaron en color y propiedades mecánicas (textura). Los resultados fueron comparados con muestras estándar (comerciales). Los espectros de FTIR confrmaron la presencia de la estructura típica (huella) de los polímeros obtenidos. El SA mostró una viscosidad signifcativamente mayor en todas las concentraciones comparado con el estándar y los otros polímeros. La fuerza de los bioplásticos fue similar entre CH, SA y GAL para todas las concentraciones; únicamente SA (0,5%) demostró una mayor fuerza que el estándar. Para las mediciones de color, los valores de matiz indicaron colores rojo-amarillento y el croma aumentó proporcionalmente a la concentración de polímero. Las propiedades observadas sugieren que estas fuentes sustentables son una alternativa para la producción de bioplásticos y podría mejorarse su funcionalización por interacciones moleculares para su aplicación en diferentes sectores industriales.Os biopolímeros são úteis na indústria por suas propriedades elásticas e sua natureza sustentável na substituição de polímeros não renováveis. Neste artigo, os bioplásticos foram preparados e caracterizados utilizando quitosana (CH), alginato de sódio (SA) e galactomanano (GAL) de insetos (Hermetia illucens), algas marrons (Macrocystis pyrifera) e sementes (Leucaena leucocephala), respectivamente. A estrutura dos biopolímeros foi observada por espectroscopia no infravermelho (FTIR) e caracterizada em viscosidade em diferentes concentrações, e os bioplásticos desenvolvidos foram caracterizados em propriedades mecânicas e de cor (textura). Os resultados foram comparados com amostras padrão (comerciais). Os espectros de FTIR confrmaram a presença da estrutura típica (pegada) dos polímeros obtidos. O SA mostrou uma viscosidade signifcativamente maior em todas as concentrações em comparação com o padrão e os outros polímeros. A força dos bioplásticos foi semelhante entre CH, SA e GAL para todas as concentrações; somente o SA (0,5%) demonstrou maior força que o padrão. Para medições de cores, os valores de matiz indicaram cores vermelho-amareladas e o croma aumentou proporcionalmente à concentração do polímero. As propriedades observadas sugerem que essas fontes sustentáveis são uma alternativa para a produção de bioplásticos, podendo ser melhoradas por interações moleculares para aplicação em diferentes setores industriais

Bio-plastic polymers from renewable sources = Bio-plásticos de polímeros a partir de fuentes renovables

Biopolymers are useful in the industry due to its elastic properties and sustainability as replacements of non-renewable polymers. In this article, bioplastics were produced and characterized using chitosan (CH), sodium alginate (SA), and galactomannan (GAL) from insects (Hermetia illucens), brown algae (Macrocystis pyrifera) and seeds (Leucaena leucocephala), respectively. The structure of biopolymers was observed by infrared spectroscopy (FTIR) and characterized by viscosity at different concentrations. The developed bioplastics were characterized by color and mechanical properties (texture). The results were compared to standard samples (commercial). The FTIR spectra confirmed the presence of the typical structure (footprint) for the obtained polymers. The SA showed significantly higher viscosity for all concentrations compared to the standard and the other polymers. The bioplastics strength was similar among CH, SA and GAL for all concentrations; only SA (0,5%) demonstrated higher strength than the standard. For color measurements, hue value indicated a red-yellowish color and the chrome increased directly proportional with polymer concentration. The observed properties suggest that these sustainable sources might be an alternative to bioplastic production, which can be extended to functionalization and molecular interactions for broad applications in different industries

Três pontos de vista sobre a pandemia

Entrevistamos a Ana Esther Ceceña, Coordinadora del Observatorio Latinoamericano de Geopolítica, Investigadora de la Universidad Nacional Autónoma de México y Presidenta de la Agencia Latinoamericana de Información; a Jin Xiaowen, Doctor en Política Internacional por la Universidad de Beijing e Investigador de la Academia Nacional de Desarrollo y Estrategia de la Universidad Renmin de la República Popular China y a Mario Róvere, médico sanitarista, quien fue Consultor Regional de la Organización Panamericana de la Salud y Viceministro de Salud de la Nación Argentina y es actualmente Director Provincial de Gestión del Conocimiento en el Ministerio de Salud de la Provincia de Buenos Aires.We interviewed Ana Esther Ceceña, Coordinator of the Latin American Observatory of Geopolitics, researcher at the National Autonomous University of Mexico and President of the Latin American Information Agency; Jin Xiaowen, Doctor in International Policy from Beijing University and researcher at the National Academy of Development and Strategy from the Renmin University of the People’s Republic of China and Mario Róvere, a medical doctor, who was a Regional Consultant of the Pan American Health Organization and Vice Minister of Health of the Argentine Nation, and is currently Provincial Director of Knowledge Management in the Ministry of Health of the Province of Buenos Aires.Entrevistamos a Ana Esther Ceceña, Coordenadora do Observatório Latino-Americano de Geopolítica, Pesquisadora da Universidade Nacional Autônoma do México e Presidente da Agência Latino-Americana de Informação, a Jin Xiaowen, Doutor em Política Internacional pela Universidade de Pequim e Pesquisador da Academia Nacional de Desenvolvimento e Estratégia da Universidade Renmin da República Popular da China e a Mario Róvere, médico sanitário, quem era consultor regional da Organização Pan-Americana da Saúde e vice-ministro da Saúde da nação argentina e é atualmente diretor provincial de gestão do conhecimento do Ministério da Saúde da Província de Buenos Aires.Cátedra Libre Ciencia, Política y Socieda

Três pontos de vista sobre a pandemia

Entrevistamos a Ana Esther Ceceña, Coordinadora del Observatorio Latinoamericano de Geopolítica, Investigadora de la Universidad Nacional Autónoma de México y Presidenta de la Agencia Latinoamericana de Información; a Jin Xiaowen, Doctor en Política Internacional por la Universidad de Beijing e Investigador de la Academia Nacional de Desarrollo y Estrategia de la Universidad Renmin de la República Popular China y a Mario Róvere, médico sanitarista, quien fue Consultor Regional de la Organización Panamericana de la Salud y Viceministro de Salud de la Nación Argentina y es actualmente Director Provincial de Gestión del Conocimiento en el Ministerio de Salud de la Provincia de Buenos Aires.We interviewed Ana Esther Ceceña, Coordinator of the Latin American Observatory of Geopolitics, researcher at the National Autonomous University of Mexico and President of the Latin American Information Agency; Jin Xiaowen, Doctor in International Policy from Beijing University and researcher at the National Academy of Development and Strategy from the Renmin University of the People’s Republic of China and Mario Róvere, a medical doctor, who was a Regional Consultant of the Pan American Health Organization and Vice Minister of Health of the Argentine Nation, and is currently Provincial Director of Knowledge Management in the Ministry of Health of the Province of Buenos Aires.Entrevistamos a Ana Esther Ceceña, Coordenadora do Observatório Latino-Americano de Geopolítica, Pesquisadora da Universidade Nacional Autônoma do México e Presidente da Agência Latino-Americana de Informação, a Jin Xiaowen, Doutor em Política Internacional pela Universidade de Pequim e Pesquisador da Academia Nacional de Desenvolvimento e Estratégia da Universidade Renmin da República Popular da China e a Mario Róvere, médico sanitário, quem era consultor regional da Organização Pan-Americana da Saúde e vice-ministro da Saúde da nação argentina e é atualmente diretor provincial de gestão do conhecimento do Ministério da Saúde da Província de Buenos Aires.Cátedra Libre Ciencia, Política y Socieda

Integrated methodological framework fos assesing the risk of failure in water supply incorporating drought forecast. Case study: Andean regulated river basin

[EN] Hydroclimatic drought conditions can affect the hydrological services offered by mountain river basins causing severe impacts on the population, becoming a challenge for water resource managers in Andean river basins. This study proposes an integrated methodological framework for assessing the risk of failure in water supply, incorporating probabilistic drought forecasts, which assists in making decisions regarding the satisfaction of consumptive, non-consumptive and environmental requirements under water scarcity conditions. Monte Carlo simulation was used to assess the risk of failure in multiple stochastic scenarios, which incorporate probabilistic forecasts of drought events based on a Markov chains (MC) model using a recently developed drought index (DI). This methodology was tested in the Machángara river basin located in the south of Ecuador. Results were grouped in integrated satisfaction indexes of the system (DSIG). They demonstrated that the incorporation of probabilistic drought forecasts could better target the projections of simulation scenarios, with a view of obtaining realistic situations instead of optimistic projections that would lead to riskier decisions. Moreover, they contribute to more effective results in order to propose multiple alternatives for prevention and/or mitigation under drought conditions.This study was part of the doctoral thesis of Aviles A. at the Technical University of Valencia. This research was funded by the University of Cuenca through its Research Department (DIUC) and the Municipal public enterprise of telecommunications, drinking water, sewage and sanitation of Cuenca (ETAPA) through the projects: BIdentificacion de los procesos hidrometeorologicos que desencadenan inundaciones en la ciudad de Cuenca usando un radar de precipitacion" and "Ciclos meteorologicos y evapotranspiracion a lo largo de una gradiente altitudinal del Parque Nacional Cajas". The authors also thank INAMHI and the CBRM for providing the information for this study. The authors wish to thank the Spanish Ministry of Economy and Competitiveness for its financial support through the ERAS project (CTM2016-77804-P). We thank Angel Vazquez, who helped in the programming of the multiple simulations. Also we thank to the TropiSeca project.Avilés-Añazco, A.; Solera Solera, A.; Paredes Arquiola, J.; Pedro Monzonís, M. (2018). Integrated methodological framework fos assesing the risk of failure in water supply incorporating drought forecast. Case study: Andean regulated river basin. Water Resources Management. 32(4):1209-1223. https://doi.org/10.1007/s11269-017-1863-7S12091223324Andreu J, Capilla J, Sanchís E (1996) AQUATOOL, a generalized decision-support system for water-resources planning and operational management. J Hydrol 177(3-4):269–291. https://doi.org/10.1016/0022-1694(95)02963-XAndreu J, Solera A, Capilla J, Ferrer J (2007) Modelo SIMGES para simulación de cuencas. Manual de usuario v3. 00. Universidad Politécnica de Valencia, ValenciaAndreu J, Ferrer J, Perez MA et al (2013) Drought planning and management in the Júcar River Basin, Spain. In: Schwabe K et al (eds) Drought in arid and semi-arid regions. Springer science, Dordrecht, pp 237–249. https://doi.org/10.1007/978-94-007-6636-5_13Avilés A, Solera A (2013) Análisis de sistemas de recursos hídricos de la cuenca del rio Tomebamba en Ecuador, mediante modelos estocásticos y de gestión. In: Solera A, Paredes J, Andreu J (eds) Aplicaciones de sistemas soporte a la decisión en planificación y gestión integradas de cuencas hidrográficas. Marcombo, Barcelona, España pp 51–61Avilés A, Célleri R, Paredes J, Solera A (2015) Evaluation of Markov chain based drought forecasts in an Andean Regulated River basin using the skill scores RPS and GMSS. Water Resour Manag 29(6):1949–1963. https://doi.org/10.1007/s11269-015-0921-2Avilés A, Célleri R, Solera A, Paredes J (2016) Probabilistic forecasting of drought events using Markov chain-and Bayesian network-based models: a case study of an Andean Regulated River Basin. Water 8:1–16Barua S, Ng A, Perera B (2012) Drought assessment and forecasting: a case study on the Yarra River catchment in Victoria, Australia. Aust J Water Resour 15(2):95–108. https://doi.org/10.7158/W10-848.2012.15.2Bazaraa MS, Jarvis JJ, Sherali HD (2011) Linear programming and network flows, fourth Edi. John Wiley & Sons, New JerseyBrown C, Baroang KM, Conrad E et al (2010) IRI technical report 10–15, managing climate risk in water supply systems. Palisades, NYCancelliere A, Di Mauro G, Bonaccorso B, Rossi G (2007) Drought forecasting using the standardized precipitation index. Water Resour Manag 21(5):801–819. https://doi.org/10.1007/s11269-006-9062-yCancelliere A, Nicolosi V, Rossi G (2009) Assessment of drought risk in water supply systems in coping with drought risk in agriculture and water supply systems. Advances in natural and technological hazards research 26. In: Coping with drought risk in agriculture. Springer, pp 93–109. https://doi.org/10.1007/978-1-4020-9045-5_8Chen YD, Zhang Q, Xiao M, Singh VP, Zhang S (2016) Probabilistic forecasting of seasonal droughts in the Pearl River basin, China. Stoch Environ Res Risk Assess 30(7):2031–2040. https://doi.org/10.1007/s00477-015-1174-6Gong G, Wang L, Condon L, Shearman A, Lall U (2010) A simple framework for incorporating seasonal Streamflow forecasts into existing water resource management practices. 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J Hydrol 512:134–146. https://doi.org/10.1016/j.jhydrol.2014.02.039Mahmoudzadeh H, Mahmoudzadeh H, Afshar M, Yousefi S (2016) Applying first-order Markov chains and SPI drought index to monitor and forecast drought in West Azerbaijan Province of Iran. Int J Geo Sci Environ Plan 1:44–53. 10.22034/ijgsep.2016.40669Mishra AK, Singh VP (2010) Review paper a review of drought concepts. J Hydrol 391(1-2):202–216. https://doi.org/10.1016/j.jhydrol.2010.07.012Nalbantis I, Tsakiris G (2009) Assessment of hydrological drought revisited. Water Resour Manag 23(5):881–897. https://doi.org/10.1007/s11269-008-9305-1Ochola WO, Kerkides P (2003) A Markov chain simulation model for predicting critical wet and dry spells in Kenya: Analysing rainfall events in the kano plains. Irrig Drain 52(4):327–342. https://doi.org/10.1002/ird.094Paulo AA, Pereira LS (2007) Prediction of SPI drought class transitions using Markov chains. Water Resour Manag 21(10):1813–1827. https://doi.org/10.1007/s11269-006-9129-9Phan TD, Smart JCR, Capon SJ, Hadwen WL, Sahin O (2016) Applications of Bayesian belief networks in water resource management: a systematic review. Environ Model Softw 85:98–111. https://doi.org/10.1016/j.envsoft.2016.08.006Pouget L, Roldán T, Gómez M et al (2015) Use of seasonal climate predictions in the water sector—preliminary results from the EUPORIAS project. In: Andreu J, Solera A, Paredes J et al (eds) Drought: research and science-policy interfacing. Taylor & Francis Group, London, UK, p 247Rossi G, Cancelliere A (2013) Managing drought risk in water supply systems in Europe: a review. Int J Water Resour Dev 29(2):272–289. https://doi.org/10.1080/07900627.2012.713848Rossi G, Caporali E, Garrote L (2012) Definition of risk indicators for reservoirs management optimization. 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A review of water scarcity and drought indexes in water resources planning and management

Water represents an essential element for the life of all who inhabit our planet. But the random nature of this resource, which is manifested by the alternation of wet periods and dry periods, makes it even more precious. Whatever the approach (water planning, water management, drought, economy), in order to maximise the profit produced by the allocation of water it is necessary an understanding of the relationships between physical variables as precipitation, temperatures, streamflows, reservoir volumes, piezometric levels, water demands and infrastructures management. This paper attends to provide a review of fundamental water scarcity and drought indexes that enables to assess the status of a water exploitation system. With the aim of a better water management and governance under water scarcity conditions., this paper also presents a classification of indexes to help decision makers and stakeholders to select the most appropriate indexes, taking as the starting point the objectives of the analysis and the river basin features.Pedro Monzonis, M.; Solera Solera, A.; Ferrer Polo, FJ.; Estrela Monreal, T.; Paredes Arquiola, J. (2015). A review of water scarcity and drought indexes in water resources planning and management. Journal of Hydrology. (527):482-493. doi:10.1016/j.jhydrol.2015.05.003S48249352

Role of age and comorbidities in mortality of patients with infective endocarditis

[Purpose]: The aim of this study was to analyse the characteristics of patients with IE in three groups of age and to assess the ability of age and the Charlson Comorbidity Index (CCI) to predict mortality. [Methods]: Prospective cohort study of all patients with IE included in the GAMES Spanish database between 2008 and 2015.Patients were stratified into three age groups:<65 years,65 to 80 years,and ≥ 80 years.The area under the receiver-operating characteristic (AUROC) curve was calculated to quantify the diagnostic accuracy of the CCI to predict mortality risk. [Results]: A total of 3120 patients with IE (1327 < 65 years;1291 65-80 years;502 ≥ 80 years) were enrolled.Fever and heart failure were the most common presentations of IE, with no differences among age groups.Patients ≥80 years who underwent surgery were significantly lower compared with other age groups (14.3%,65 years; 20.5%,65-79 years; 31.3%,≥80 years). In-hospital mortality was lower in the <65-year group (20.3%,<65 years;30.1%,65-79 years;34.7%,≥80 years;p < 0.001) as well as 1-year mortality (3.2%, <65 years; 5.5%, 65-80 years;7.6%,≥80 years; p = 0.003).Independent predictors of mortality were age ≥ 80 years (hazard ratio [HR]:2.78;95% confidence interval [CI]:2.32–3.34), CCI ≥ 3 (HR:1.62; 95% CI:1.39–1.88),and non-performed surgery (HR:1.64;95% CI:11.16–1.58).When the three age groups were compared,the AUROC curve for CCI was significantly larger for patients aged <65 years(p < 0.001) for both in-hospital and 1-year mortality. [Conclusion]: There were no differences in the clinical presentation of IE between the groups. Age ≥ 80 years, high comorbidity (measured by CCI),and non-performance of surgery were independent predictors of mortality in patients with IE.CCI could help to identify those patients with IE and surgical indication who present a lower risk of in-hospital and 1-year mortality after surgery, especially in the <65-year group

5to. Congreso Internacional de Ciencia, Tecnología e Innovación para la Sociedad. Memoria académica

El V Congreso Internacional de Ciencia, Tecnología e Innovación para la Sociedad, CITIS 2019, realizado del 6 al 8 de febrero de 2019 y organizado por la Universidad Politécnica Salesiana, ofreció a la comunidad académica nacional e internacional una plataforma de comunicación unificada, dirigida a cubrir los problemas teóricos y prácticos de mayor impacto en la sociedad moderna desde la ingeniería. En esta edición, dedicada a los 25 años de vida de la UPS, los ejes temáticos estuvieron relacionados con la aplicación de la ciencia, el desarrollo tecnológico y la innovación en cinco pilares fundamentales de nuestra sociedad: la industria, la movilidad, la sostenibilidad ambiental, la información y las telecomunicaciones. El comité científico estuvo conformado formado por 48 investigadores procedentes de diez países: España, Reino Unido, Italia, Bélgica, México, Venezuela, Colombia, Brasil, Estados Unidos y Ecuador. Fueron recibidas un centenar de contribuciones, de las cuales 39 fueron aprobadas en forma de ponencias y 15 en formato poster. Estas contribuciones fueron presentadas de forma oral ante toda la comunidad académica que se dio cita en el Congreso, quienes desde el aula magna, el auditorio y la sala de usos múltiples de la Universidad Politécnica Salesiana, cumplieron respetuosamente la responsabilidad de representar a toda la sociedad en la revisión, aceptación y validación del conocimiento nuevo que fue presentado en cada exposición por los investigadores. Paralelo a las sesiones técnicas, el Congreso contó con espacios de presentación de posters científicos y cinco workshops en temáticas de vanguardia que cautivaron la atención de nuestros docentes y estudiantes. También en el marco del evento se impartieron un total de ocho conferencias magistrales en temas tan actuales como la gestión del conocimiento en la universidad-ecosistema, los retos y oportunidades de la industria 4.0, los avances de la investigación básica y aplicada en mecatrónica para el estudio de robots de nueva generación, la optimización en ingeniería con técnicas multi-objetivo, el desarrollo de las redes avanzadas en Latinoamérica y los mundos, la contaminación del aire debido al tránsito vehicular, el radón y los riesgos que representa este gas radiactivo para la salud humana, entre otros

Demographic history and genetic structure in pre-Hispanic Central Mexico

International audienceAridoamerica and Mesoamerica are two distinct cultural areas in northern and central Mexico, respectively, that hosted numerous pre-Hispanic civilizations between 2500 BCE and 1521 CE. The division between these regions shifted southward because of severe droughts ~1100 years ago, which allegedly drove a population replacement in central Mexico by Aridoamerican peoples. In this study, we present shotgun genome-wide data from 12 individuals and 27 mitochondrial genomes from eight pre-Hispanic archaeological sites across Mexico, including two at the shifting border of Aridoamerica and Mesoamerica. We find population continuity that spans the climate change episode and a broad preservation of the genetic structure across present-day Mexico for the past 2300 years. Lastly, we identify a contribution to pre-Hispanic populations of northern and central Mexico from two ancient unsampled “ghost” populations