338 research outputs found

    Reflectometry measurements of the m=1 satellite mode in L- and H-mode plamas in ASDEX

    Get PDF
    In ASDEX, with strong NB, heating, often a large central m=1, n=1 mode is observed on the SXR emission. For PNBI > 1 MW a mode rotating with the same frequency, the so-called`m=1 satellite`, is seen on the magnetic pick-up coils in the L and H-phases. Magnetic measurement s in the divertor chamber suggest that the satellite mode might be located outside the separatix, on open field lines reaching the diretor /1/. Here we present results from localized microave reflectrometric measurements. The time evolution of the satellite mode frequency is studied for plasmas with different qa and the mode localization is estimated, confirming that is shoud be close to but outside the separatrix. The central toroidal rotation velocities of the plasma can be inferred from the measured frenquencies of the satellite modes

    Changes in the density profile due to the m=2 tearing mode in asdex

    Get PDF
    Resistive MHO tearing modes can develop magnetic islands near the rational magnetic surfaces, where q=m/ n

    Spray‐dried formulations rich in malvidin from tintorera grape wastes: Characterization, stability, and storage

    Get PDF
    Indexación ScopusThis research was focused on developing means of Tintorera grape (Vitis vinifera L.) waste recovery, devising new value‐added uses for that material and optimizing of anthocyanin‐rich formulations by spray‐drying in order to obtain novel ingredients, all for food industry use. First, the identification of phenolic compounds in Tintorera grape extracts by HPLC‐DAD‐ESI‐MSn enabled characterization of the raw material’s health‐promoting characteristics. Maintaining the spray‐dried products for 4 weeks’ storage enabled study of the formulation’s loss of anthocyanins and antioxi-dant properties due to drying process temperatures as well as analysis of the retention and stability of such compounds under different conditions (20 and 40 °C). Tintorera grapes presented a significant amount of Malvidin 3‐O‐hex (5.66 mg g−1 DW). Anthocyanins in spray‐dried formulations were stable for 4 weeks. Optimal conditions in the spray‐dryer facilitated the products’ antioxidant ca-pacity; for instance, using 10% maltodextrin (w:v) at 90 °C inlet temperature had a little influence on the reduction in encapsulated malvidin 3‐O‐hex (15%) and presented 3.35 mg GAE g−1 DW of total polyphenol contents, 98.62 μmol Trolox (FRAP assay), and 39.97 μmol Trolox (DPPH assay). Principal component analyses (PCA) showed a high degree of dependence between anthocyanin content and maintenance of antioxidant capacity during storage. These results offer a promising alternative for the industrial management of wine‐making wastes in order to implement a sustainable protocol for development of Tintorera grape extracts rich in bioactive compounds for new bev-erages and functional foods. © 2021 by the author. Licensee MDPI, Basel, Switzerland.https://www.mdpi.com/2227-9717/9/3/51

    Measurement of the B0-anti-B0-Oscillation Frequency with Inclusive Dilepton Events

    Get PDF
    The B0B^0-Bˉ0\bar B^0 oscillation frequency has been measured with a sample of 23 million \B\bar B pairs collected with the BABAR detector at the PEP-II asymmetric B Factory at SLAC. In this sample, we select events in which both B mesons decay semileptonically and use the charge of the leptons to identify the flavor of each B meson. A simultaneous fit to the decay time difference distributions for opposite- and same-sign dilepton events gives Δmd=0.493±0.012(stat)±0.009(syst)\Delta m_d = 0.493 \pm 0.012{(stat)}\pm 0.009{(syst)} ps1^{-1}.Comment: 7 pages, 1 figure, submitted to Physical Review Letter

    Lanthanum tungstate membranes for H-2 extraction and CO2 utilization: Fabrication strategies based on sequential tape casting and plasma-spray physical vapor deposition

    Get PDF
    [EN] In the context of energy conversion efficiency and decreasing greenhouse gas emissions from power generation and energy-intensive industries, membrane technologies for H-2 extraction and CO2 capture and utilization become pronouncedly important. Mixed protonic-electronic conducting ceramic membranes are hence attractive for the pre-combustion integrated gasification combined cycle, specifically in the water gas shift and H-2 separation process, and also for designing catalytic membrane reactors. This work presents the fabrication, microstructure and functional properties of Lanthanum tungstates (La28-xW4+xO54+delta, LaWO) asymmetric membranes supported on porous ceramic and porous metallic substrates fabricated by means of the sequential tape casting route and plasma spray-physical vapor deposition (PS-PVD). Pure LaWO and W site substituted LaWO were employed as membrane materials due to the promising combination of properties: appreciable mixed protonic-electronic conductivity at intermediate temperatures and reducing atmospheres, good sinterability and noticeable chemical stability under harsh operating conditions. As substrate materials porous LaWO (non-substituted), MgO and Crofer22APU stainless steel were used to support various LaWO membrane layers. The effect of fabrication parameters and material combinations on the assemblies' microstructure, LaWO phase formation and gas tightness of the functional layers was explored along with the related fabrication challenges for shaping LaWO layers with sufficient quality for further practical application. The two different fabrication strategies used in the present work allow for preparing all-ceramic and ceramic-metallic assemblies with LaWO membrane layers with thicknesses between 25 and 60 mu m and H-2 flux of ca. 0.4 ml/min cm(2) measured at 825 degrees C in 50 vol% H-2 in He dry feed and humid Ar sweep configuration. Such a performance is an exceptional achievement for the LaWO based H-2 separation membranes and it is well comparable with the H-2 flux reported for other newly developed dual phase cer-cer and cer-met membranes.ProtOMem Project under the BMBF grant 03SF0537 is gratefully acknowledged. Furthermore, the authors thank Ralf Laufs for his assistance in operating the PS-PVD facility. Dr. A. Schwedt from the Central Facility for Electron Microscopy (Gemeinschaftslabor fur Elektronenmikroskopie GFE), RWTH Aachen University is acknowledged for performing the EBSD analysis on the PS-PVD samples.Ivanova, ME.; Deibert, W.; Marcano, D.; Escolástico Rozalén, S.; Mauer, G.; Meulenberg, WA.; Bram, M.... (2019). Lanthanum tungstate membranes for H-2 extraction and CO2 utilization: Fabrication strategies based on sequential tape casting and plasma-spray physical vapor deposition. Separation and Purification Technology. 219:100-112. https://doi.org/10.1016/j.seppur.2019.03.015S100112219A.A. Evers, The hydrogen society, More than just a vision? ISBN 978-3-937863-31-3, Hydrogeit Verlag, 16727 Oberkraemer, Germany, 2010.Deibert, W., Ivanova, M. E., Baumann, S., Guillon, O., & Meulenberg, W. A. (2017). Ion-conducting ceramic membrane reactors for high-temperature applications. Journal of Membrane Science, 543, 79-97. doi:10.1016/j.memsci.2017.08.016Arun C. Bose, Inorganic membranes for energy and environmental applications, Edt. A. C. Bose, ISBN: 978-0-387-34524-6, Springer Science+Business Media, LLC, 2009.M. Marrony, H. Matsumoto, N. Fukatsu, M. Stoukides, Typical applications of proton ceramic cells: a way to market? in: M. Marrony (ed.), Proton-conducting ceramics. From fundamentals to applied research, by Pan Stanford Publishing Pte. Ltd., ISBN 978-981-4613-84-2, 2016.Di Giorgio, P., & Desideri, U. (2016). Potential of Reversible Solid Oxide Cells as Electricity Storage System. Energies, 9(8), 662. doi:10.3390/en9080662A.L. Dicks, D.A.J. Rand, Fuel cell systems explained, ISBN: 9781118613528, John Wiley & Sons Ltd., 2018.Zheng, Y., Wang, J., Yu, B., Zhang, W., Chen, J., Qiao, J., & Zhang, J. (2017). A review of high temperature co-electrolysis of H2O and CO2to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology. Chemical Society Reviews, 46(5), 1427-1463. doi:10.1039/c6cs00403bGötz, M., Lefebvre, J., Mörs, F., McDaniel Koch, A., Graf, F., Bajohr, S., … Kolb, T. (2016). Renewable Power-to-Gas: A technological and economic review. Renewable Energy, 85, 1371-1390. doi:10.1016/j.renene.2015.07.066Woodhead publishing series in energy, Nr. 76, Membrane reactors for energy applications and basic chemical production, Edt. A. Basile, L. Di Paola, F.I. Hai, V. Piemonte, by Elsevier Ltd, ISBN 978-1-78242-223-5, 2015.Morejudo, S. H., Zanón, R., Escolástico, S., Yuste-Tirados, I., Malerød-Fjeld, H., Vestre, P. K., … Kjølseth, C. (2016). Direct conversion of methane to aromatics in a catalytic co-ionic membrane reactor. Science, 353(6299), 563-566. doi:10.1126/science.aag0274Malerød-Fjeld, H., Clark, D., Yuste-Tirados, I., Zanón, R., Catalán-Martinez, D., Beeaff, D., … Kjølseth, C. (2017). Thermo-electrochemical production of compressed hydrogen from methane with near-zero energy loss. Nature Energy, 2(12), 923-931. doi:10.1038/s41560-017-0029-4J. Franz, Energetic and economic analysis of CO2 retention in coal gasification power plants by means of polymer and ceramic membranes (dissertation, German), Ruhr-University Bochum, Germany, Shaker Verlag, 2013.Franz, J., & Scherer, V. (2011). Impact of ceramic membranes for CO2 separation on IGCC power plant performance. Energy Procedia, 4, 645-652. doi:10.1016/j.egypro.2011.01.100E. Forster, dissertation, Thermal stability of ceramic membranes and catalysts for H2-separation in CO-shift reactors, Energy and Environment Band, vol. 284, ISBN 978-3-95806-084-5, RUB 2015.Escolástico, S., Stournari, V., Malzbender, J., Haas-Santo, K., Dittmeyer, R., & Serra, J. M. (2018). Chemical stability in H2S and creep characterization of the mixed protonic conductor Nd5.5WO11.25-δ. International Journal of Hydrogen Energy, 43(17), 8342-8354. doi:10.1016/j.ijhydene.2018.03.060Mortalò, C., Rebollo, E., Escolástico, S., Deambrosis, S., Haas-Santo, K., Rancan, M., … Fabrizio, M. (2018). Enhanced sulfur tolerance of BaCe0.65Zr0.20Y0.15O3-δ-Ce0.85Gd0.15O2-δ composite for hydrogen separation membranes. Journal of Membrane Science, 564, 123-132. doi:10.1016/j.memsci.2018.07.015Matsumoto, H., Shimura, T., Higuchi, T., Tanaka, H., Katahira, K., Otake, T., … Mizusaki, J. (2005). Protonic-Electronic Mixed Conduction and Hydrogen Permeation in BaCe[sub 0.9−x]Y[sub 0.1]Ru[sub x]O[sub 3−α]. Journal of The Electrochemical Society, 152(3), A488. doi:10.1149/1.1852442Cai, M., Liu, S., Efimov, K., Caro, J., Feldhoff, A., & Wang, H. (2009). Preparation and hydrogen permeation of BaCe0.95Nd0.05O3−δ membranes. Journal of Membrane Science, 343(1-2), 90-96. doi:10.1016/j.memsci.2009.07.011U. Balachandran, J. Guan, S.E. Dorris, A.C. Bose, G.J. Stiegel, in: Proceedings of the 5th ICIM, A-410, Nagoya, Japan, 1998.Qi, X. (2000). Electrical conduction and hydrogen permeation through mixed proton–electron conducting strontium cerate membranes. Solid State Ionics, 130(1-2), 149-156. doi:10.1016/s0167-2738(00)00281-2Zhan, S., Zhu, X., Ji, B., Wang, W., Zhang, X., Wang, J., … Lin, L. (2009). Preparation and hydrogen permeation of SrCe0.95Y0.05O3−δ asymmetrical membranes. Journal of Membrane Science, 340(1-2), 241-248. doi:10.1016/j.memsci.2009.05.037Song, S. (2004). Hydrogen permeability of SrCe1−xMxO3−δ (x=0.05, M=Eu, Sm). Solid State Ionics, 167(1-2), 99-105. doi:10.1016/j.ssi.2003.12.010Wei, X., Kniep, J., & Lin, Y. S. (2009). Hydrogen permeation through terbium doped strontium cerate membranes enabled by presence of reducing gas in the downstream. Journal of Membrane Science, 345(1-2), 201-206. doi:10.1016/j.memsci.2009.08.041CHENG, S., GUPTA, V., & LIN, J. (2005). Synthesis and hydrogen permeation properties of asymmetric proton-conducting ceramic membranes. Solid State Ionics, 176(35-36), 2653-2662. doi:10.1016/j.ssi.2005.07.005Kniep, J., & Lin, Y. S. (2010). Effect of Zirconium Doping on Hydrogen Permeation through Strontium Cerate Membranes. Industrial & Engineering Chemistry Research, 49(6), 2768-2774. doi:10.1021/ie9015182LIANG, J., MAO, L., LI, L., & YUAN, W. (2010). Protonic and Electronic Conductivities and Hydrogen Permeation of SrCe0.95-xZrxTm0.05O3-δ(0≤x≤0.40) Membrane. Chinese Journal of Chemical Engineering, 18(3), 506-510. doi:10.1016/s1004-9541(10)60250-9Xing, W., Inge Dahl, P., Valland Roaas, L., Fontaine, M.-L., Larring, Y., Henriksen, P. P., & Bredesen, R. (2015). Hydrogen permeability of SrCe0.7Zr0.25Ln0.05O3− membranes (Ln=Tm and Yb). Journal of Membrane Science, 473, 327-332. doi:10.1016/j.memsci.2014.09.027Oh, T., Yoon, H., Li, J., & Wachsman, E. D. (2009). Hydrogen permeation through thin supported SrZr0.2Ce0.8−xEuxO3−δ membranes. Journal of Membrane Science, 345(1-2), 1-4. doi:10.1016/j.memsci.2009.08.031Hamakawa, S. (2002). Synthesis and hydrogen permeation properties of membranes based on dense SrCe0.95Yb0.05O3−α thin films. Solid State Ionics, 148(1-2), 71-81. doi:10.1016/s0167-2738(02)00047-4Escolástico, S., Ivanova, M., Solís, C., Roitsch, S., Meulenberg, W. A., & Serra, J. M. (2012). Improvement of transport properties and hydrogen permeation of chemically-stable proton-conducting oxides based on the system BaZr1-x-yYxMyO3-δ. RSC Advances, 2(11), 4932. doi:10.1039/c2ra20214jH. Matsumoto, T. Shimura, T. Higuchi, T. Otake, Y. Sasaki, K. Yashiro, A. Kaimai, T. Kawada, J. Mizusaki, Mixed protonic-electronic conduction properties of SrZr0.9−xY0.1RuxO3−δ, Electrochemistry, 72(12), 861–864.M.E. Ivanova, S. Escolático, M. Balaguer, J. Palisaitis, Y.J. Sohn, W.A. Meulenberg, O. Guillon, J. Mayer, J.M. Serra, Hydrogen separation through tailored dual phase membranes with nominal composition BaCe0.8Eu0.2O3−δ:Ce0.8Y0.2O2−δ at intermediate temperatures, Sci. Rep. 6 (2016) 34773–34787.S. Elangovan, B.G. Nair, T.A. Small, Ceramic mixed protonic-electronic conducting membranes for hydrogen separation (2007), US 7,258,820 B2, 1997.Rosensteel, W. A., Ricote, S., & Sullivan, N. P. (2016). Hydrogen permeation through dense BaCe 0.8 Y 0.2 O 3−δ – Ce 0.8 Y 0.2 O 2−δ composite-ceramic hydrogen separation membranes. International Journal of Hydrogen Energy, 41(4), 2598-2606. doi:10.1016/j.ijhydene.2015.11.053Rebollo, E., Mortalò, C., Escolástico, S., Boldrini, S., Barison, S., Serra, J. M., & Fabrizio, M. (2015). Exceptional hydrogen permeation of all-ceramic composite robust membranes based on BaCe0.65Zr0.20Y0.15O3−δ and Y- or Gd-doped ceria. Energy & Environmental Science, 8(12), 3675-3686. doi:10.1039/c5ee01793aMontaleone, D., Mercadelli, E., Escolástico, S., Gondolini, A., Serra, J. M., & Sanson, A. (2018). All-ceramic asymmetric membranes with superior hydrogen permeation. Journal of Materials Chemistry A, 6(32), 15718-15727. doi:10.1039/c8ta04764bKim, H., Kim, B., Lee, J., Ahn, K., Kim, H.-R., Yoon, K. J., … Lee, J.-H. (2014). Microstructural adjustment of Ni–BaCe0.9Y0.1O3−δ cermet membrane for improved hydrogen permeation. Ceramics International, 40(3), 4117-4126. doi:10.1016/j.ceramint.2013.08.066(Balu) Balachandran, U., Lee, T. H., Park, C. Y., Emerson, J. E., Picciolo, J. J., & Dorris, S. E. (2014). Dense cermet membranes for hydrogen separation. Separation and Purification Technology, 121, 54-59. doi:10.1016/j.seppur.2013.10.001Shimura, T. (2001). Proton conduction in non-perovskite-type oxides at elevated temperatures. Solid State Ionics, 143(1), 117-123. doi:10.1016/s0167-2738(01)00839-6HAUGSRUD, R. (2007). Defects and transport properties in Ln6WO12 (Ln=La, Nd, Gd, Er). Solid State Ionics, 178(7-10), 555-560. doi:10.1016/j.ssi.2007.01.004Haugsrud, R., & Kjølseth, C. (2008). Effects of protons and acceptor substitution on the electrical conductivity of La6WO12. Journal of Physics and Chemistry of Solids, 69(7), 1758-1765. doi:10.1016/j.jpcs.2008.01.002Magrasó, A., Polfus, J. M., Frontera, C., Canales-Vázquez, J., Kalland, L.-E., Hervoches, C. H., … Haugsrud, R. (2012). Complete structural model for lanthanum tungstate: a chemically stable high temperature proton conductor by means of intrinsic defects. J. Mater. Chem., 22(5), 1762-1764. doi:10.1039/c2jm14981hSeeger, J., Ivanova, M. E., Meulenberg, W. A., Sebold, D., Stöver, D., Scherb, T., … Serra, J. M. (2013). Synthesis and Characterization of Nonsubstituted and Substituted Proton-Conducting La6–xWO12–y. Inorganic Chemistry, 52(18), 10375-10386. doi:10.1021/ic401104mScherb, T., Kimber, S. A. J., Stephan, C., Henry, P. F., Schumacher, G., Escolástico, S., … Banhart, J. (2016). Nanoscale order in the frustrated mixed conductor La5.6WO12−δ. Journal of Applied Crystallography, 49(3), 997-1008. doi:10.1107/s1600576716006415Van Holt, D., Forster, E., Ivanova, M. E., Meulenberg, W. A., Müller, M., Baumann, S., & Vaßen, R. (2014). Ceramic materials for H2 transport membranes applicable for gas separation under coal-gasification-related conditions. Journal of the European Ceramic Society, 34(10), 2381-2389. doi:10.1016/j.jeurceramsoc.2014.03.001Forster, E., van Holt, D., Ivanova, M. E., Baumann, S., Meulenberg, W. A., & Müller, M. (2016). Stability of ceramic materials for H2 transport membranes in gasification environment under the influence of gas contaminants. Journal of the European Ceramic Society, 36(14), 3457-3464. doi:10.1016/j.jeurceramsoc.2016.05.021Medvedev, D., Lyagaeva, J., Plaksin, S., Demin, A., & Tsiakaras, P. (2015). Sulfur and carbon tolerance of BaCeO3–BaZrO3 proton-conducting materials. Journal of Power Sources, 273, 716-723. doi:10.1016/j.jpowsour.2014.09.116Yang, L., Wang, S., Blinn, K., Liu, M., Liu, Z., Cheng, Z., & Liu, M. (2009). Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr 0.1 Ce 0.7 Y 0.2– x Yb x O 3–δ. Science, 326(5949), 126-129. doi:10.1126/science.1174811Duan, C., Kee, R. J., Zhu, H., Karakaya, C., Chen, Y., Ricote, S., … O’Hayre, R. (2018). Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells. Nature, 557(7704), 217-222. doi:10.1038/s41586-018-0082-6Kreuer, K. D. (2003). Proton-Conducting Oxides. Annual Review of Materials Research, 33(1), 333-359. doi:10.1146/annurev.matsci.33.022802.091825Fantin, A., Scherb, T., Seeger, J., Schumacher, G., Gerhards, U., Ivanova, M. E., … Banhart, J. (2016). Crystal structure of Re-substituted lanthanum tungstate La5.4W1−y Re y O12–δ (0 ≤ y ≤ 0.2) studied by neutron diffraction. Journal of Applied Crystallography, 49(5), 1544-1560. doi:10.1107/s1600576716011523Fantin, A., Scherb, T., Seeger, J., Schumacher, G., Gerhards, U., Ivanova, M. E., … Banhart, J. (2017). Relation between composition and vacant oxygen sites in the mixed ionic-electronic conductors La5.4W1−MO12− (M= Mo, Re; 0 ≤y≤ 0.2) and their mother compound La6−WO12− (0.4 ≤x≤ 0.8). Solid State Ionics, 306, 104-111. doi:10.1016/j.ssi.2017.04.005J.M. Serra, S. Escolástico, M.E. Ivanova, W.A. Meulenberg, H.-P. Buchkremer, D. Stöver, US2013-0216938-A1, 2013.Escolastico, S., Seeger, J., Roitsch, S., Ivanova, M., Meulenberg, W. A., & Serra, J. M. (2013). Enhanced H2Separation through Mixed Proton-Electron Conducting Membranes Based on La5.5W0.8M0.2O11.25−δ. ChemSusChem, 6(8), 1523-1532. doi:10.1002/cssc.201300091Gil, V., Gurauskis, J., Kjølseth, C., Wiik, K., & Einarsrud, M.-A. (2013). Hydrogen permeation in asymmetric La28 − xW4 + xO54 + 3x/2 membranes. International Journal of Hydrogen Energy, 38(7), 3087-3091. doi:10.1016/j.ijhydene.2012.12.105Palmqvist, L., Lindqvist, K., & Shaw, C. (2007). Porous Multilayer PZT Materials Made by Aqueous Tape Casting. Key Engineering Materials, 333, 215-218. doi:10.4028/www.scientific.net/kem.333.215Menzler, N. H., Malzbender, J., Schoderböck, P., Kauert, R., & Buchkremer, H. P. (2013). Sequential Tape Casting of Anode-Supported Solid Oxide Fuel Cells. Fuel Cells, 14(1), 96-106. doi:10.1002/fuce.201300153Schulze-Küppers, F., Baumann, S., Tietz, F., Bouwmeester, H. J. M., & Meulenberg, W. A. (2014). Towards the fabrication of La0.98−xSrxCo0.2Fe0.8O3−δ perovskite-type oxygen transport membranes. Journal of the European Ceramic Society, 34(15), 3741-3748. doi:10.1016/j.jeurceramsoc.2014.06.012Weirich, M., Gurauskis, J., Gil, V., Wiik, K., & Einarsrud, M.-A. (2012). Preparation of lanthanum tungstate membranes by tape casting technique. International Journal of Hydrogen Energy, 37(9), 8056-8061. doi:10.1016/j.ijhydene.2011.09.083Deibert, W., Schulze-Küppers, F., Forster, E., Ivanova, M. E., Müller, M., & Meulenberg, W. A. (2017). Stability and sintering of MgO as a substrate material for Lanthanum Tungstate membranes. Journal of the European Ceramic Society, 37(2), 671-677. doi:10.1016/j.jeurceramsoc.2016.09.033Escolástico, S., Vert, V. B., & Serra, J. M. (2009). Preparation and Characterization of Nanocrystalline Mixed Proton−Electronic Conducting Materials Based on the System Ln6WO12. Chemistry of Materials, 21(14), 3079-3089. doi:10.1021/cm900067kGil, V., Strøm, R. A., Groven, L. J., & Einarsrud, M.-A. (2012). La28−xW4+xO54+3x/2Powders Prepared by Spray Pyrolysis. Journal of the American Ceramic Society, 95(11), 3403-3407. doi:10.1111/j.1551-2916.2012.05377.xIvanova, M. E., Meulenberg, W. A., Palisaitis, J., Sebold, D., Solís, C., Ziegner, M., … Guillon, O. (2015). Functional properties of La0.99X0.01Nb0.99Al0.01O4−δ and La0.99X0.01Nb0.99Ti0.01O4−δ proton conductors where X is an alkaline earth cation. Journal of the European Ceramic Society, 35(4), 1239-1253. doi:10.1016/j.jeurceramsoc.2014.11.009Dittmeyer, R., Boeltken, T., Piermartini, P., Selinsek, M., Loewert, M., Dallmann, F., … Pfeifer, P. (2017). Micro and micro membrane reactors for advanced applications in chemical energy conversion. Current Opinion in Chemical Engineering, 17, 108-125. doi:10.1016/j.coche.2017.08.001Mauer, G., Vaßen, R., & Stöver, D. (2009). Thin and Dense Ceramic Coatings by Plasma Spraying at Very Low Pressure. Journal of Thermal Spray Technology, 19(1-2), 495-501. doi:10.1007/s11666-009-9416-0Bakan, E., & Vaßen, R. (2017). Ceramic Top Coats of Plasma-Sprayed Thermal Barrier Coatings: Materials, Processes, and Properties. Journal of Thermal Spray Technology, 26(6), 992-1010. doi:10.1007/s11666-017-0597-7Jarligo, M. O., Mauer, G., Bram, M., Baumann, S., & Vaßen, R. (2013). Plasma Spray Physical Vapor Deposition of La1−x Sr x Co y Fe1−y O3−δ Thin-Film Oxygen Transport Membrane on Porous Metallic Supports. Journal of Thermal Spray Technology, 23(1-2), 213-219. doi:10.1007/s11666-013-0004-yMarcano, D., Mauer, G., Sohn, Y. J., Vaßen, R., Garcia-Fayos, J., & Serra, J. M. (2016). Controlling the stress state of La1−Sr Co Fe1−O3− oxygen transport membranes on porous metallic supports deposited by plasma spray–physical vapor process. Journal of Membrane Science, 503, 1-7. doi:10.1016/j.memsci.2015.12.029Marcano, D., Mauer, G., Vaßen, R., & Weber, A. (2017). Manufacturing of high performance solid oxide fuel cells (SOFCs) with atmospheric plasma spraying (APS) and plasma spray-physical vapor deposition (PS-PVD). Surface and Coatings Technology, 318, 170-177. doi:10.1016/j.surfcoat.2016.10.088D. Marcano, G. Mauer, Y.J. Sohn, A. Schwedt, M. Bram, M.E. Ivanova, R. Vaßen, Plasma spray-physical vapor deposition of single phase lanthanum tungstate for hydrogen gas separation membranes, t.b. submitted (2018).Brunauer, S., Emmett, P. H., & Teller, E. (1938). Adsorption of Gases in Multimolecular Layers. Journal of the American Chemical Society, 60(2), 309-319. doi:10.1021/ja01269a023Ried, P., Lorenz, C., Brönstrup, A., Graule, T., Menzler, N. H., Sitte, W., & Holtappels, P. (2008). Processing of YSZ screen printing pastes and the characterization of the electrolyte layers for anode supported SOFC. Journal of the European Ceramic Society, 28(9), 1801-1808. doi:10.1016/j.jeurceramsoc.2007.11.018R. Mücke, Sintering of ZrO2-electrolytes in multilayered assemblies of SOFC, PhD Thesis, Ruhr-University, Bochum, 2007.Amsif, M., Magrasó, A., Marrero-López, D., Ruiz-Morales, J. C., Canales-Vázquez, J., & Núñez, P. (2012). Mo-Substituted Lanthanum Tungstate La28–yW4+yO54+δ: A Competitive Mixed Electron–Proton Conductor for Gas Separation Membrane Applications. Chemistry of Materials, 24(20), 3868-3877. doi:10.1021/cm301723aDANIELS, A. U., LOWRIE, R. C., GIBBY, R. L., & CUTLER, I. B. (1962). Observations on Normal Grain Growth of Magnesia and Calcia. Journal of the American Ceramic Society, 45(6), 282-285. doi:10.1111/j.1151-2916.1962.tb11145.

    Epigenetic loss of RNA-methyltransferase NSUN5 in glioma targets ribosomes to drive a stress adaptive translational program

    Get PDF
    Altres ajuts: This work was supported by the Obra Social "La Caixa" (to M. Esteller).Tumors have aberrant proteomes that often do not match their corresponding transcriptome profiles. One possible cause of this discrepancy is the existence of aberrant RNA modification landscapes in the so-called epitranscriptome. Here, we report that human glioma cells undergo DNA methylation-associated epigenetic silencing of NSUN5, a candidate RNA methyltransferase for 5-methylcytosine. In this setting, NSUN5 exhibits tumor-suppressor characteristics in vivo glioma models. We also found that NSUN5 loss generates an unmethylated status at the C3782 position of 28S rRNA that drives an overall depletion of protein synthesis, and leads to the emergence of an adaptive translational program for survival under conditions of cellular stress. Interestingly, NSUN5 epigenetic inactivation also renders these gliomas sensitive to bioactivatable substrates of the stress-related enzyme NQO1. Most importantly, NSUN5 epigenetic inactivation is a hallmark of glioma patients with long-term survival for this otherwise devastating disease

    The FAIR Guiding Principles for scientific data management and stewardship

    Get PDF
    There is an urgent need to improve the infrastructure supporting the reuse of scholarly data. A diverse set of stakeholders—representing academia, industry, funding agencies, and scholarly publishers—have come together to design and jointly endorse a concise and measureable set of principles that we refer to as the FAIR Data Principles. The intent is that these may act as a guideline for those wishing to enhance the reusability of their data holdings. Distinct from peer initiatives that focus on the human scholar, the FAIR Principles put specific emphasis on enhancing the ability of machines to automatically find and use the data, in addition to supporting its reuse by individuals. This Comment is the first formal publication of the FAIR Principles, and includes the rationale behind them, and some exemplar implementations in the community
    corecore