Karakterisasi Plastik Biodegradabel dari Ldpe-g-ma dan Pati Tandan Kosong Sawit

Penelitian ini bertujuan untuk menghasilkan suatu plastik  biodegradabel yang dapat terurai di alam, sehingga dapat menjadi salah satu solusi dalam penumpukan sampah plastik yang sulit diuraikan oleh alam. Plastik biodegradabel yang dihasilkan dari pencampuran limbah plastik polietilena jenis Low Density Polyetylene (LDPE) dengan pati Tandan kosong Sawit (TKS) yang  dimodifikasi dengan menambahkan maleat anhidrida sebagai agen pengikat silang. Untuk menghasilkan plastik biodegradabel  dilakukan  variasi perbandingan tertentu antara  limbah LDPE, pati TKS, maleat anhidrida dan benzoil peroksida (90:10:1:1), (80:20:1:1), (70:30:1:1), (60:40:1:1). Tahapan penelitian ini melakukan ekstraksi pati dari tandan kosong sawit (TKS), preparasi serbuk plastik biodegradabel dengan metode refluks menggunakan pelarut xilena dari berbagai variasi komposisi limbah LDPE, pati TKS, maleat anhidrida, dan benzoil peroksida, pencetakkan plastik biodegradabel  dengan metode kempa tekan dan karakterisasi terhadap hasil plastik biodegradabel yaitu analisa sifat mekanik dengan uji kuat tarik dan kemuluran, analisa kemampuannya terurai di alam dengan uji biodegradabel, dan analisa sifat kimianya dengan uji FTIR. Dari hasil karakterisasi dapat diperoleh kondisi optimum plastik biodegradabel yang dihasilkan Plastik biodegradabel dengan perbandingan Limbah LDPE, Pati TKS, maleat anhidrida, benzoil peroksida (60:40:1:1) yang memiliki kemampuan terurai pada tanah sampah yaitu sebesar 9,032%, harga kuat tarik 6,9410 N/m2 dan nilai kemuluran 3,1875 %, analisa sifat kimia dengan uji FT-IR menunjukan bilangan gelombang yang khas untuk ikatan antara limbah LDPE-g-MA dan Pati TKS yaitu 1165,00 cm-1 yang menunjukan gugus fungsi C-O bending

An action research on promotion of health ageing and risk reduction of chronic disease : a need assessment study among rural elderly Malays, care givers and health professionals

Prior to the development of a healthy ageing and risk reduction of chronic diseases intervention package for older people in Malaysia, a need assessment study was conducted to identify nutritional knowledge status and information needs, as part of an action research process. Design: A cross sectional study was conducted among 267 elderly people, 54 care givers and 66 health professionals in two rural areas of Peninsular of Malaysia (i.e Sabak Bernam, Selangor and Kuala Pilah, Negeri Sembilan). Information on nutritional knowledge was obtained from an interview based questionnaire for older subjects and caregiver and through self administered questionnaire from the health professionals. Anthropometric and functional measurements were also conducted among elderly subjects. Results: It was found that the elderly subjects had poor nutritional knowledge with 43.8% of them classified as having unsatisfactory nutritional knowledge, followed by moderately satisfactory (33.7%), very unsatisfactory (15.7%) and good (6.7%). Talks, counselling sessions with health professionals and electronic media such as television and radio were the most preferred nutrition education sources among elderly subjects and their care givers. The majority of health professionals studied (98.5%) had good nutritional knowledge. Although most of them (93.6%) were involved in management of the elderly, only 45.5% incorporated nutritional information component in this activity. Most of the health professionals used the guidelines for management of elderly patients (63.6%). However, nutritional knowledge was very minimal in these guidelines. Multiple regression analysis indicated that ‘level education’, involvement in ‘social activities’, presence of ‘hearing problems’, the Instrumental Activities of Daily Living (IADL) score, having previous ‘nutritional information’ and ‘participation in healthy eating programme’ were the major predictors of nutritional knowledge score among elderly subjects. Conclusion: Based on the above findings it is thus, imperative that an appropriate nutritional intervention package and programme be developed so as to help improve nutritional knowledge and subsequently the nutritional status of the rural elderly Malays

Rapid transport of East Asian pollution to the deep tropics

Abstract. Anthropogenic emissions from East Asia have increased over recent decades, and under the prevailing westerly winds, these increases have led to changes in atmospheric composition as far afield as North America. Here we show that, during Northern Hemisphere (NH) winter, pollution originating in East Asia also directly affects atmospheric composition in the deep tropics. We present observations of marked intra-seasonal variability in the anthropogenic tracer perchloroethene (C2Cl4) collected at two locations in Borneo during the NH winter of 2008/09. We use the NAME trajectory model to show that the observed enhancements in C2Cl4 mixing ratio are caused by rapid meridional transport, in the form of "cold surges", from the relatively polluted East Asian land mass. In these events air masses can move across > 30° of latitude in 4 days. We then present data from the Monitoring Atmospheric Composition and Climate reanalysis which suggests that air masses high in C2Cl4 may also contain levels of the pollutants carbon monoxide and ozone that are approximately double the typical "background" levels in Borneo. Convection in Southeast Asia can be enhanced by cold surges, and further trajectory calculations indicate that the polluted air masses can subsequently be lifted to the tropical upper troposphere. This suggests a potentially important connection between mid-latitude pollution sources and the very low stratosphere. This work was supported by a NERC consortium grant to the OP3 team, by NCAS, by the European Commission through the SCOUT-O3 project (505390-GOCECF2004), though the ERC ACCI project, Project No 267760, and by NERC western Pacific grant number NE/F020341/1 and NERC CAST grant number NE/J006246/1. M. J. Ashfold thanks NERC for a research studentship. A. D. Robinson acknowledges NERC for their support through small grant project NE/D008085/1. N. R. P. Harris is supported by a NERC Advanced Research Fellowship. We thank the Sabah Foundation, Danum Valley Field Centre and the Royal Society (Glen Reynolds) for field site support. This is paper number X of the Royal Society’s South East Asian Rainforest Research Programme. We are grateful for use of data provided by the MACC-II project, funded by the European Union under the 7th Framework Programme. We also acknowledge use of the NAME atmospheric dispersion model and associated NWP meteorological data sets made available to us by the Met O ce. We acknowledge the significant storage resources and analysis facilities made available to us on JASMIN by STFC CEDA along with the corresponding support teams.This is the published version. It first appeared at: http://www.atmos-chem-phys-discuss.net/14/30705/2014/acpd-14-30705-2014.html

Neutron Scattering Investigation of the Dimerized Antiferromagnetic Compound CsV2O5

The S = 1/2 antiferromagnetic dimer system CsV2O5 has a nonmagnetic singlet ground state and a finite energy gap to triplet excited states. CsV2O5 is composed of magnetic dimer units of V4+ along the chain, with exchange interaction J0 occurring between two structural dimers. In this study, we investigate the magnetic properties of the layered compound CsV2O5 using magnetic susceptibility measurements and powder inelastic neutron scattering. DC susceptibility is measured across various temperature ranges and analyzed using both isolated and interacting dimer models. From the susceptibility data, the exchange interaction J0 is determined to be 12.45 meV. However, DC susceptibility struggles to accurately describe the interdimer interactions. The inelastic neutron scattering results quantitatively confirm that CsV2O5 has an energy gap ∆ = 10 meV, with a bandwidth of excitations of 4.98 meV. Random phase approximation indicates that the behavior of this system is much closer to that of a two-dimensionally interacting dimer with J′ = 9.98 meV with significant interdimer and interchain couplings than that of isolated or alternating dimers as was initially proposed. The ratio of interdimer to intradimer exchange constants is J′/J0 = 0.80. A comparison to the DFT measurement is discussed

Long-term halocarbon observations from a coastal and an inland site in Sabah, Malaysian Borneo

Abstract. Short-lived halocarbons are believed to have important sources in the tropics, where rapid vertical transport could provide a significant source to the stratosphere. In this study, quasi-continuous measurements of short-lived halocarbons are reported for two tropical sites in Sabah (Malaysian Borneo), one coastal and one inland (rainforest). We present the observations for C2Cl4, CHBr3, CH2Br2* (actually ~80% CH2Br2 and ~20% CHBrCl2) and CH3I from November 2008 to January 2010 made using our μDirac gas chromatographs with electron capture detection (GC-ECD). We focus on the first 15 months of observations, showing over one annual cycle for each compound and therefore adding significantly to the few limited-duration observational studies that have been conducted thus far in southeast Asia. The main feature in the C2Cl4 behaviour at both sites is its annual cycle, with the winter months being influenced by northerly flow with higher concentrations, typical of the Northern Hemisphere, and with the summer months influenced by southerly flow and lower concentrations representative of the Southern Hemisphere. No such clear annual cycle is seen for CHBr3, CH2Br2* or CH3I. The baseline values for CHBr3 and CH2Br2* are similar at the coastal (overall median: CHBr3 1.7 ppt, CH2Br2* 1.4 ppt) and inland sites (CHBr3 1.6 ppt, CH2Br2* 1.1 ppt), but periods with elevated values are seen at the coast (overall 95th percentile: CHBr3 4.4 ppt, CH2Br2ast 1.9 ppt), presumably resulting from the stronger influence of coastal emissions. Overall median bromine values from [CHBr3 × 3] + [CH2Br2* × 2] are 8.0 ppt at the coast and 6.8 ppt inland. The median values reported here are largely consistent with other limited tropical data and imply that southeast Asia generally is not, as has been suggested, a hot spot for emissions of these compounds. These baseline values are consistent with the most recent emissions found for southeast Asia using the p-TOMCAT (Toulouse Off-line Model of Chemistry And Transport) model. CH3I, which is only observed at the coastal site, is the shortest-lived compound measured in this study, and the observed atmospheric variations reflect this, with high variability throughout the study period. This work was supported by a NERC consortium grant to the OP3 team, by NCAS, by the European Commission through the SCOUT-O3 project (505390-GOCE-CF2004) and by NERC western Pacific grant number NE/F020341/1 and NERC CAST grant number NE/J006246/1. L. M. O’Brien and M. J. Ashfold thank NERC for research studentships. A. D. Robinson acknowledges NERC for their support through small grant project NE/D008085/1. N. R. P. Harris is supported by a NERC Advanced Research Fellowship. We thank the Sabah Foundation, Danum Valley Field Centre and the Royal Society (Glen Reynolds) for field site support. The research leading to these results has received funding from the European Union’s Seventh Framework Programme FP7/2007–2013 under grant agreement no. 226224 – SHIVA. We thank David Oram and Stephen Humphrey at UEA for their assistance in checking the calibration of our Aculife cylinder in May 2009. This is paper number 626 of the Royal Society’s South East Asian Rainforest Research Programme.This is the final published version. It first appeared at http://www.atmos-chem-phys.net/14/8369/2014/acp-14-8369-2014.html

Residual disease and HPV persistence after cryotherapy for cervical intraepithelial neoplasia grade 2/3 in HIV positive women in Kenya

Objective: To assess residual cervical intraepithelial neoplasia (CIN) 2/3 disease and clearance of high-risk (hr) human papillomavirus (HPV) infections at 6 months after cryotherapy among HIV-positive women. Design: Follow-up study. Methods: 79 HIV-positive women received cryotherapy for CIN2/3 in Nairobi, Kenya, and underwent conventional cytology 6 months later. Biopsies were performed on high grade cytological lesions and hrHPV was assessed before (cervical cells and biopsy) and after cryotherapy (cells). Results: At 6 months after cryotherapy CIN2/3 had been eliminated in 61 women (77.2%; 95% Confidence Interval, (CI):66.4–85.9). 18 women (22.8%) had residual CIN2/3, and all these women had hrHPV at baseline. CD4 count and duration of combination antiretroviral therapy (cART) were not associated with residual CIN2/3. CIN3 instead of CIN2 was the only significant risk factor for residual disease (odds ratio, OR vs CIN2 = 4.3; 95% CI: 1.2–15.0) among hrHPV-positive women after adjustment for age and HPV16 infection. Persistence of hrHPV types previously detected in biopsies was found in 77.5% of women and was associated with residual CIN2/3 (OR = 8.1, 95% CI: 0.9–70). The sensitivity, specificity, and negative predictive value of hrHPV test in detecting residual CIN2/3 were 0.94, 0.36, and 0.96 respectively. Conclusions: Nearly one quarter of HIV-positive women had residual CIN2/3 disease at 6 months after cryotherapy, and the majority had persistent hrHPV. CD4 count and cART use were not associated with residual disease or hrHPV persistence. The value of hrHPV testing in the detection of residual CIN2/3 was hampered by a low specificity

Security Authentication for Student Cards’ Biometric Recognition Using Viola-Jones Algorithm

The unauthorized access to the university entrance could be gained by only flashing a student card. This unsecure situation shows the loophole of security authentication in a university. In order to overcome this, a biometric recognition could be the most suitable candidate as it varies uniquely from one person to another. A study on student cards’ biometric recognition using Viola-Jones algorithm is presented as it is proven as a powerful algorithm in terms of superb detection rates and speed.  It is done by comparing the facial structures and features between the student card’s image and the card holder image, thus determining the similarity. The recognition performance is evaluated based on the percentage of similarity using 100 testing images of 50 students. The observation on results obtained the effectiveness of the Viola-Jones features in student cards’ biometric recognition rate

A growing threat to the ozone layer from short-lived anthropogenic chlorocarbons

Large and effective reductions in emissions of long-lived ozone-depleting substance (ODS) are being achieved through the Montreal Protocol, the effectiveness of which can be seen in the declining atmospheric abundances of many ODSs. An important remaining uncertainty concerns the role of very short-lived substances (VSLSs) which, owing to their relatively short atmospheric lifetimes (less than 6 months), are not regulated under the Montreal Protocol. Recent studies have found an unexplained increase in the global tropospheric abundance of one VSLS, dichloromethane (CH2Cl2), which has increased by around 60 % over the past decade. Here we report dramatic enhancements of several chlorine-containing VSLSs (Cl-VSLSs), including CH2Cl2 and CH2ClCH2Cl (1,2-dichloroethane), observed in surface and upper-tropospheric air in East and South East Asia. Surface observations were, on occasion, an order of magnitude higher than previously reported in the marine boundary layer, whilst upper-tropospheric data were up to 3 times higher than expected. In addition, we provide further evidence of an atmospheric transport mechanism whereby substantial amounts of industrial pollution from East Asia, including these chlorinated VSLSs, can rapidly, and regularly, be transported to tropical regions of the western Pacific and subsequently uplifted to the tropical upper troposphere. This latter region is a major provider of air entering the stratosphere, and so this mechanism, in conjunction with increasing emissions of Cl-VSLSs from East Asia, could potentially slow the expected recovery of stratospheric ozone

Modelling the chemistry and transport of bromoform within a sea breeze driven convective system during the SHIVA Campaign

We carry out a case study of the transport and chemistry of bromoform and its product gases (PGs) in a sea breeze driven convective episode on 19 November 2011 along the North West coast of Borneo during the "Stratospheric ozone: Halogen Impacts in a Varying Atmosphere" (SHIVA) campaign. We use ground based, ship, aircraft and balloon sonde observations made during the campaign, and a 3-D regional online transport and chemistry model capable of resolving clouds and convection explicitly that includes detailed bromine chemistry. The model simulates the temperature, wind speed, wind direction fairly well for the most part, and adequately captures the convection location, timing, and intensity. The simulated transport of bromoform from the boundary layer up to 12 km compares well to aircraft observations to support our conclusions. The model makes several predictions regarding bromine transport from the boundary layer to the level of convective detrainment (11 to 12 km). First, the majority of bromine undergoes this transport as bromoform. Second, insoluble organic bromine carbonyl species are transported to between 11 and 12 km, but only form a small proportion of the transported bromine. Third, soluble bromine species, which include bromine organic peroxides, hydrobromic acid (HBr), and hypobromous acid (HOBr), are washed out efficiently within the core of the convective column. Fourth, insoluble inorganic bromine species (principally Br2) are not washed out of the convective column, but are also not transported to the altitude of detrainment in large quantities. We expect that Br2 will make a larger relative contribution to the total vertical transport of bromine atoms in scenarios with higher CHBr3 mixing ratios in the boundary layer, which have been observed in other regions. Finally, given the highly detailed description of the chemistry, transport and washout of bromine compounds within our simulations, we make a series of recommendations about the physical and chemical processes that should be represented in 3-D chemical transport models (CTMs) and chemistry climate models (CCMs), which are the primary theoretical means of estimating the contribution made by CHBr3 and other very short-lived substances (VSLS) to the stratospheric bromine budget

A case report on osler-weber-rendu disease

Osler-Weber-Rendu disease, also known as hereditary hemorrhagic telangiectasia (HHT) is a rare autosomal dominant genetic disorder that leads to abnormal blood vessel formation in the skin, mucous membrane and in organs such as lungs, liver, and brain. Here, we report the case of a 68-year-old postmenopausal woman who was admitted to our hospital following multiple episodes of hematemesis and melena during the past 5 days. Upper GI endoscopy revealed multiple telangiectasia with active spurting and gastric polyp. The patient was treated with 1 unit of packed red blood cells transfusion for anemia, Inj. Tranexamic acid 500 mg IV tid and Inj. Ondansetron 4 mg IV for hematemesis. Tab. Thalidomide 100 mg has been given for treating hereditary hemorrhagic telangiectasia. The treatment of HHT is only palliative, with no consensus on the best treatment option. It is essential to promote control of thedisease as long as possible