749 research outputs found
H2CO and CH3OH maps of the Orion Bar photodissociation region
A previous analysis of methanol and formaldehyde towards the Orion Bar
concluded that the two molecular species may trace different physical
components, methanol the clumpy material, and formaldehyde the interclump
medium. To verify this hypothesis, we performed multi-line mapping observations
of the two molecules to study their spatial distributions. The observations
were performed with the IRAM-30m telescope at 218 and 241 GHz, with an angular
resolution of ~11''. Additional data for H2CO from the Plateau de Bure array
are also discussed. The data were analysed using an LVG approach.
Both molecules are detected in our single-dish data. Our data show that CH3OH
peaks towards the clumps of the Bar, but its intensity decreases below the
detection threshold in the interclump material. When averaging over a large
region of the interclump medium, the strongest CH3OH line is detected with a
peak intensity of ~0.06K. Formaldehyde also peaks on the clumps, but it is also
detected in the interclump gas. We verified that the weak intensity of CH3OH in
the interclump medium is not caused by the different excitation conditions of
the interclump material, but reflects a decrease in the column density of
methanol. The abundance of CH3OH relative to H2CO decreases by at least one
order of magnitude from the dense clumps to the interclump medium.Comment: 11 pages, accepted for publication in A&
Hydrogen Fluoride in High-Mass Star-forming Regions
Hydrogen fluoride has been established to be an excellent tracer of molecular
hydrogen in diffuse clouds. In denser environments, however, the HF abundance
has been shown to be approximately two orders of magnitude lower. We present
Herschel/HIFI observations of HF J=1-0 toward two high-mass star formation
sites, NGC6334 I and AFGL 2591. In NGC6334 I the HF line is seen in absorption
in foreground clouds and the source itself, while in AFGL 2591 HF is partially
in emission. We find an HF abundance with respect to H2 of 1.5e-8 in the
diffuse foreground clouds, whereas in the denser parts of NGC6334 I, we derive
a lower limit on the HF abundance of 5e-10. Lower HF abundances in dense clouds
are most likely caused by freeze out of HF molecules onto dust grains in
high-density gas. In AFGL 2591, the view of the hot core is obstructed by
absorption in the massive outflow, in which HF is also very abundant 3.6e-8)
due to the desorption by sputtering. These observations provide further
evidence that the chemistry of interstellar fluorine is controlled by freeze
out onto gas grains.Comment: accepted in Ap
Multiple Rieske/cytb complexes in a single organism
AbstractMost organisms contain a single Rieske/cytb complex. This enzyme can be integrated in any respiratory or photosynthetic electron transfer chain that is quinone-based and sufficiently energy rich to allow for the turnover of three enzymes — a quinol reductase, a Rieske/cytb complex and a terminal oxidase. Despite this universal usability of the enzyme a variety of phylogenetically distant organisms have multiple copies thereof and no reason for this redundancy is obvious. In this review we present an overview of the distribution of multiple copies among species and describe their properties from the scarce experimental results, analysis of their amino acid sequences and genomic context. We discuss the predicted redox properties of the Rieske cluster in relation to the nature of the pool quinone. It appears that acidophilic iron-oxidizing bacteria specialized one of their two copies for reverse electron transfer, archaeal Thermoprotei adapted their three copies to the interaction with different oxidases and several, phylogenetically unrelated species imported a second complex with a putative heme ci that may confer some yet to be determined properties to the complex. These hypothesis and all the more the so far completely unexplained cases call for further studies and we put forward a number of suggestions for future research that we hope to be stimulating for the field. This article is part of a Special Issue entitled: Respiratory complex III and related bc complexes
OH emission from warm and dense gas in the Orion Bar PDR
As part of a far-infrared (FIR) spectral scan with Herschel/PACS, we present
the first detection of the hydroxyl radical (OH) towards the Orion Bar
photodissociation region (PDR). Five OH rotational Lambda-doublets involving
energy levels out to E_u/k~511 K have been detected (at ~65, ~79, ~84, ~119 and
~163um). The total intensity of the OH lines is I(OH)~5x10^-4 erg s^-1 cm^-2
sr^-1. The observed emission of rotationally excited OH lines is extended and
correlates well with the high-J CO and CH^+ J=3-2 line emission (but apparently
not with water vapour), pointing towards a common origin. Nonlocal, non-LTE
radiative transfer models including excitation by the ambient FIR radiation
field suggest that OH arises in a small filling factor component of warm
(Tk~160-220 K) and dense (n_H~10^{6-7} cm^-3) gas with source-averaged OH
column densities of ~10^15 cm^-2. High density and temperature photochemical
models predict such enhanced OH columns at low depths (A_V<1) and small spatial
scales (~10^15 cm), where OH formation is driven by gas-phase endothermic
reactions of atomic oxygen with molecular hydrogen. We interpret the extended
OH emission as coming from unresolved structures exposed to far-ultraviolet
(FUV) radiation near the Bar edge (photoevaporating clumps or filaments) and
not from the lower density "interclump" medium. Photodissociation leads to
OH/H2O abundance ratios (>1) much higher than those expected in equally warm
regions without enhanced FUV radiation fields.Comment: Accepted for publication in A&A Letters. Figure B.2. is bitmapped to
lower resolutio
Interpretation of radio continuum and molecular line observations of Sgr B2: free-free and synchrotron emission, and implications for cosmic rays
Recent ammonia (1,1) inversion line data on the Galactic star forming region
Sgr B2 show that the column density is consistent with a radial Gaussian
density profile with a standard deviation of 2.75 pc. Deriving a formula for
the virial mass of spherical Gaussian clouds, we obtain a virial mass of 1.9
million solar masses for Sgr B2. For this matter distribution, a reasonable
magnetic field and an impinging flux of cosmic rays of solar neighbourhood
intensity, we predict the expected synchrotron emission from the Sgr B2 giant
molecular cloud due to secondary electrons and positrons resulting from cosmic
ray interactions, including effects of losses due to pion production collisions
during diffusive propagation into the cloud complex.
We assemble radio continuum data at frequencies between 330 MHz and 230 GHz.
From the spectral energy distribution the emission appears to be thermal at
all frequencies. Before using these data to constrain the predicted synchrotron
flux, we first model the spectrum as free-free emission from the known ultra
compact HII regions plus emission from an envelope or wind with a radial
density gradient. This severely constrains the possible synchrotron emission by
secondary electrons to quite low flux levels. The absence of a significant
contribution by secondary electrons is almost certainly due to multi-GeV energy
cosmic rays being unable to penetrate far into giant molecular clouds. This
would also explain why 100 MeV--GeV gamma-rays (from neutral pion decay or
bremsstrahlung by secondary electrons) were not observed from Sgr B2 by EGRET,
while TeV energy gamma-rays were observed, being produced by higher energy
cosmic rays which more readily penetrate giant molecular clouds.Comment: 11 pages, 10 figures. New section on diffusion of primary and
secondary cosmic ray electrons into and within the Sgr B2 Giant Molecular
Cloud added. Main corrections to proofs made in this versio
Herschel HIFI observations of O toward Orion: special conditions for shock enhanced emission
We report observations of molecular oxygen (O) rotational transitions at
487 GHz, 774 GHz, and 1121 GHz toward Orion Peak A. The O2 lines at 487 GHz and
774 GHz are detected at velocities of 10-12 km/s with line widths 3 km/s;
however, the transition at 1121 GHz is not detected. The observed line
characteristics, combined with the results of earlier observations, suggest
that the region responsible for the O emission is 9" (6e16 cm) in size, and
is located close to the H2 Peak 1position (where vibrationally-excited H
emission peaks), and not at Peak A, 23" away. The peak O2 column density is
1.1e18/cm2. The line velocity is close to that of 621 GHz water maser emission
found in this portion of the Orion Molecular Cloud, and having a shock with
velocity vector lying nearly in the plane of the sky is consistent with
producing maximum maser gain along the line-of-sight. The enhanced O
abundance compared to that generally found in dense interstellar clouds can be
explained by passage of a low-velocity C-shock through a clump with preshock
density 2e4/cm3, if a reasonable flux of UV radiation is present. The postshock
O can explain the emission from the source if its line of sight dimension
is ~10 times larger than its size on the plane of the sky. The special geometry
and conditions required may explain why O emission has not been detected in
the cores of other massive star-forming molecular clouds.Comment: 28 pages, 13 figure
Molecular line survey of the high-mass star-forming region NGC 6334I with Herschel/HIFI and the SMA
We aim at deriving the molecular abundances and temperatures of the hot
molecular cores in the high-mass star-forming region NGC 6334I and consequently
deriving their physical and astrochemical conditions. In the framework of the
Herschel guaranteed time key program CHESS, NGC 6334I is investigated by using
HIFI aboard the Herschel Space Observatory. A spectral line survey is carried
out in the frequency range 480-1907 GHz, and auxiliary interferometric data
from the SMA in the 230 GHz band provide spatial information for disentangling
the different physical components contributing to the HIFI spectrum. The
spectral lines are identified with the aid of former surveys and spectral line
catalogs. The observed spectrum is then compared to a simulated synthetic
spectrum with XCLASS, assuming local thermal equilibrium, and best fit
parameters are derived using the model optimization package MAGIX. A total of
46 molecules are identified, with 31 isotopologues, resulting in about 4300
emission and absorption lines. High- energy levels of the dominant emitter
methanol and vibrationally excited HCN are detected. The number of unidentified
lines remains low with 75, or less than 2 percent of the lines detected. The
modeling suggests that several spectral features need two or more components to
be fitted properly. Other components could be assigned to cold foreground
clouds or to outflows, most visible in the SiO emission. A chemical variation
between the two embedded hot cores is found, with more N-bearing molecules
identified in SMA1 and O-bearing molecules in SMA2. Spectral line surveys give
powerful insights into the study of the interstellar medium. Different
molecules trace different physical conditions like the inner hot core, the
envelope, the outflows or the cold foreground clouds. The derived molecular
abundances provide further constraints for astrochemical models.Comment: 30 pages including appendix, 49 figures, accepted for publication in
Astronomy and Astrophysic
HERSCHEL-HIFI spectroscopy of the intermediate mass protostar NGC7129 FIRS 2
HERSCHEL-HIFI observations of water from the intermediate mass protostar
NGC7129 FIRS 2 provide a powerful diagnostic of the physical conditions in this
star formation environment. Six spectral settings, covering four H216O and two
H218O lines, were observed and all but one H218O line were detected. The four
H2 16 O lines discussed here share a similar morphology: a narrower, \approx 6
km/s, component centered slightly redward of the systemic velocity of NGC7129
FIRS 2 and a much broader, \approx 25 km/s component centered blueward and
likely associated with powerful outflows. The narrower components are
consistent with emission from water arising in the envelope around the
intermediate mass protostar, and the abundance of H2O is constrained to \approx
10-7 for the outer envelope. Additionally, the presence of a narrow
self-absorption component for the lowest energy lines is likely due to
self-absorption from colder water in the outer envelope. The broader component,
where the H2O/CO relative abundance is found to be \approx 0.2, appears to be
tracing the same energetic region that produces strong CO emission at high J.Comment: 6 pages, 4 figures, accepted by A&
Response of a soil bacterial community to grassland succession as monitored by 16S rRNA levels of the predominant ribotypes
The composition of predominant soil bacteria during grassland succession was investigated in the Dutch Drentse A area. Five meadows, taken out of agricultural production at different time points, and one currently fertilized plot represented different stages of grassland succession. Since fertilization and agricultural production were stopped, the six plots showed a constant decline in the levels of nutrients and vegetation changes. The activity of the predominant bacteria was monitored by direct ribosome isolation from soil and temperature gradient gel electrophoresis of reverse transcription (RT)-PCR products generated from bacterial 16S rRNA. The amounts of 16S rRNA of 20 predominant ribosome types per gram of soil were monitored via multiple competitive RT-PCR in six plots at different succession stages. These ribosome types mainly represented Bacillus and members of the Acidobacterium cluster and the subclass of the class Proteobacteria. The 20 16S rRNA molecules monitored represented approximately half of all bacterial soil rRNA which was estimated by dot blot hybridizations of soil rRNA with the Bacteria probe EUB338. The grasslands showed highly reproducible and specific shifts of bacterial ribosome type composition. The total bacterial ribosome level increased during the first years after agricultural production and fertilization stopped. This correlated with the collapse of the dominant Lolium perenne population and an increased rate of mineralization of organic matter. The results indicate that there is a true correlation between the total activity of the bacterial community in soil and the amount of bacterial ribosomes
Water in massive star-forming regions: HIFI observations of W3 IRS5
We present Herschel observations of the water molecule in the massive
star-forming region W3 IRS5. The o-H17O 110-101, p-H18O 111-000, p-H2O 22
202-111, p-H2O 111-000, o-H2O 221-212, and o-H2O 212-101 lines, covering a
frequency range from 552 up to 1669 GHz, have been detected at high spectral
resolution with HIFI. The water lines in W3 IRS5 show well-defined
high-velocity wings that indicate a clear contribution by outflows. Moreover,
the systematically blue-shifted absorption in the H2O lines suggests expansion,
presumably driven by the outflow. No infall signatures are detected. The p-H2O
111-000 and o-H2O 212-101 lines show absorption from the cold material (T ~ 10
K) in which the high-mass protostellar envelope is embedded. One-dimensional
radiative transfer models are used to estimate water abundances and to further
study the kinematics of the region. We show that the emission in the rare
isotopologues comes directly from the inner parts of the envelope (T > 100 K)
where water ices in the dust mantles evaporate and the gas-phase abundance
increases. The resulting jump in the water abundance (with a constant inner
abundance of 10^{-4}) is needed to reproduce the o-H17O 110-101 and p-H18O
111-000 spectra in our models. We estimate water abundances of 10^{-8} to
10^{-9} in the outer parts of the envelope (T < 100 K). The possibility of two
protostellar objects contributing to the emission is discussed.Comment: Accepted for publication in the A&A HIFI special issu
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