87 research outputs found

    Domain adaptation for social localisation-based SMT: a Case study using the Trommons platform

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    Social localisation is a kind of community action, which matches communities and the content they need, and supports their localisation efforts. The goal of social localisation-based statistical machine translation (SL-SMT) is to support and bridge global communities exchanging any type of digital content across different languages and cultures. Trommons is an open platform maintained by The Rosetta Foundation to connect non-profit translation projects and organisations with the skills and interests of volunteer translators, where they can translate, post-edit or proofread different types of documents. Using Trommons as the experimental platform, this paper focuses on domain adaptation techniques to augment SL-SMT to facilitate translators/post-editors. Specifically, the Cross Entropy Difference algorithm is used to adapt Europarl data to the social localisation data. Experimental results on English–Spanish show that the domain adaptation techniques can significantly improve translation performance by 6.82 absolute BLEU points and 5.99 absolute TER points compared to the baseline

    Organometallic complexes for nonlinear optics.66. Synthesis and quadratic nonlinear optical studies of trans-[Ru{C=C{2,5-C4H2S-( E )-CH=CH}n-2,5-C4H2S(NO2 )}Cl(dppe)2](n1/40-2)

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    Oligo(2,5-thienylenevinylene)s (OTVs) end-functionalized with a ligated ruthenium alkynyl unit as adonor and a nitro as acceptor, namelytrans-[Ru{C^C-2,5-C4H2S(NO2)}Cl(dppe)2](Ru1T),trans-[Ru{C^C-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S(NO2)}Cl(dppe)2](Ru2T), andtrans-[Ru{C^C-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S(NO2)}Cl(dppe)2](Ru3T), have been synthesized, their elec-trochemical properties have been assessed by cyclic voltammetry (CV), their linear optical and quadratic nonlinear optical (NLO) properties have been assayed by UVeviseNIR spectroscopy and hyper-Rayleighscattering studies at 1300 nm, respectively, and their linear optical properties in the formally RuIII state have been examined by UVeviseNIR spectroelectrochemistry. The data for Ru1T-Ru3Thave beencompared to those of the oligo(p-phenylenevinylene) (OPV) analoguestrans-[Ru(C^C-1,4-C6H4NO2)Cl(dppe)2](Ru1P),trans-[Ru{C^C-1,4-C6H4-(E)-CH]CH-1,4-C6H4NO2}Cl(dppe)2](Ru2P), andtrans-[Ru{C^C-1,4-C6H4-(E)-CH]CH-1,4-C6H4-(E)-CH]CH-1,4-C6H4NO2}Cl(dppe)2](Ru3P). The RuII/IIIoxidationpotentials decrease on proceeding fromRu1TtoRu3T, while the wavelength of the UVevislmaxbandincreases on proceeding fromRu1TtoRu2T, but thereafter decreases on further progression toRu3T, similar trends to those seen proceeding fromRu1PtoRu3P. The quadratic nonlinearityb1300 increases on OTV lengthening from Ru1TthroughRu2TtoRu3T; the data are significantly larger than those of the Ru1PeRu3Panalogues which peak atRu2P. The formally RuIIIcomplexes exhibit low-energy bands thatred-shift significantly on proceeding fromRu1TtoRu3T. Computational studies employing time-dependent density functional theory were undertaken on model complexes to rationalize the optical observations and explore the impact of further OTV bridge lengthening. Computational studies on modelcomplexesRu1Tâ€Č-Ru6Tâ€Čare consistent with decreasing contributions of the electron donor (ligated Ru) and acceptor (NO2) groups to the HOMO and LUMO, respectively, up n-bridge lengthening.btotvalues increase on progression fromRu1Tâ€ČtoRu3Tâ€Č, but thereafter further bridge lengthening affords little further increase in b-tot, consistent with a saturation in quadratic NLO response.We thank the Australian Research Council (ARC: DP170100408),the National Natural Science Foundation of China (51432006), theChinese Government Ministry of Education, and the Chinese Gov-ernment State Administration of Foreign Experts Affairs (111 Proj-ect: B13025). J. D. thanks the China Scholarship Council and theAustralian National University for a CSC-ANU PhD Scholarship

    La bibliothĂšque de Johann Philipp von Wessenberg-Ampringen : un don fondateur de l’identitĂ© europĂ©enne de la BNU

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    Portrait gravĂ© de Johann Philipp von Wessenberg-Ampringen dans la biographie que lui a consacrĂ© Alfred von Arneth en 1898 (Johann Freiherr von Wessenberg: ein österreichischer Staatsmann des neunzehnten Jahrhunderts, Wien, W. BraumĂŒller ; coll. BNU) ClichĂ© Jean-Pierre Rosenkranz Avant-propos Comment Ă©clairer la personnalitĂ© de celui qui se cache derriĂšre la collection de livres ? Dans le cas du baron Johann Philipp von Wessenberg, il est particuliĂšrement important de tenir compte de la situa..

    Palladium–mediated organofluorine chemistry

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    Producción CientíficaThe substitution of fluorine for hydrogen in a molecule may result in profound changes in its properties and behaviour. Fluorine does not introduce special steric constraints since the F atom has a small size. However, the changes in bond polarity and the possibility of forming hydrogen bonds with other hydrogen donor fragments in the same or other molecules, may change the solubility and physical properties of the fluorinated compound when compared to the non-fluorinated one. Fluorine forms strong bonds to other elements and this ensures a good chemical stability. Altogether, fluorinated compounds are very attractive in materials chemistry and in medicinal chemistry, where many biologically active molecules and pharmaceuticals do contain fluorine in their structure and this has been shown to be essential for their activityJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA302U13)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA256U13

    Traitement des fractures complexes de l'humérus proximal par enclouage verrouillé (Telegraph). Résultats d'une étude prospective préliminaire.

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    Treatment of complex fractures of the proximal humerus is still controversial. This prospective study was designed to evaluate the results of open reduction and proximal nailing in complex fractures of the proximal humerus. Fifteen patients aged 39 to 83 years (average: 59 years) presenting severely displaced fractures of the proximal humerus were observed after open reduction and fixation by proximal nailing (Telegraph) combined with screwing and/or osteosuture of the tuberosities. The patients were evaluated at one year clinically and radiologically. The Constant score, DASH score and Simple Shoulder Test were calculated. Complementarily, patients were submitted to an isokinetic test. At one year follow-up, the average range of motion was 85 degrees (40 degrees-170 degrees) for elevation, 82 degrees (40 degrees-170 degrees) for abduction, L3 for internal rotation and 34 degrees (10-60 degrees) for external rotation. The average visual analog score was 3 points (0-8 points). The Constant score varied from 17 to 92 points (average: 48 points). Isokinetic evaluation showed mostly a strength deficit in abduction even for patients presenting an excellent result. Functional results were related to the quality of the surgical reduction but also to patients' collaboration. Various treatment methods for complex fracture of the proximal humerus are reported in the literature. When a nearly anatomical reduction is achieved, the here-described method of open reduction and proximal nailing permits to obtain good functional results in most patients. This option should be considered for young patients and even in the elderly where results are comparable to that obtained with hemiarthroplasty in the same condition.English AbstractJournal ArticleSCOPUS: ar.jinfo:eu-repo/semantics/publishe
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