Carbonates in space - The challenge of low temperature data

Carbonates have repeatedly been discussed as possible carriers of stardust emission bands. However, the band assignments proposed so far were mainly based on room temperature powder transmission spectra of the respective minerals. Since very cold calcite grains have been claimed to be present in protostars and in Planetary Nebulae such as NGC 6302, the changes of their dielectric functions at low temperatures are relevant from an astronomical point of view. We have derived the IR optical constants of calcite and dolomite from reflectance spectra - measured at 300, 200, 100 and 10K - and calculated small particle spectra for different grain shapes, with the following results: i) The absorption efficiency factors both of calcite and dolomite are extremely dependent on the particle shapes. This is due to the high peak values of the optical constants of CaCO3 and CaMg[CO3]2. ii) The far infrared properties of calcite and dolomite depend also very significantly on the temperature. Below 200K, a pronounced sharpening and increase in the band strengths of the FIR resonances occurs. iii) In view of the intrinsic strength and sharpening of the 44 mum band of calcite at 200-100K, the absence of this band -- inferred from Infrared Space Observatory data -- in PNe requires dust temperatures below 45K. iv) Calcite grains at such low temperatures can account for the '92' mum band, while our data rule out dolomite as the carrier of the 60-65 mum band. The optical constants here presented are publicly available in the electronic database http://www.astro.uni-jena.de/Laboratory/OCDBComment: 20 pages, 10 figures, accepted by ApJ, corrected typo

Tracing the development of dust around evolved stars: The case of 47 Tuc

We observed mid-infrared (7.5-22 mum) spectra of AGB stars in the globular cluster 47 Tuc with the Spitzer telescope and find significant dust features of various types. Comparison of the characteristics of the dust spectra with the location of the stars in a logP-K-diagram shows that dust mineralogy and position on the AGB are related. A 13 mum feature is seen in spectra of low luminosity AGB stars. More luminous AGB stars show a broad feature at 11.5 mum. The spectra of the most luminous stars are dominated by the amorphous silicate bending vibration centered at 9.7 mum. For 47 Tuc AGB stars, we conclude that early on the AGB dust consisting primarily of Mg-, Al- and Fe oxides is formed. With further AGB evolution amorphous silicates become the dominant species.Comment: 2 figures, accepted for publication in ApJ Letter

Dusty shells surrounding the carbon variables S Scuti and RT Capricorni

For the Mass-loss of Evolved StarS (MESS) programme, the unprecedented spatial resolution of the PACS photometer on board the Herschel space observatory was employed to map the dusty environments of asymptotic giant branch (AGB) and red supergiant (RSG) stars. Among the morphologically heterogeneous sample, a small fraction of targets is enclosed by spherically symmetric detached envelopes. Based on observations in the 70 {\mu}m and 160 {\mu}m wavelength bands, we investigated the surroundings of the two carbon semiregular variables S Sct and RT Cap, which both show evidence for a history of highly variable mass-loss. S Sct exhibits a bright, spherically symmetric detached shell, 138" in diameter and co-spatial with an already known CO structure. Moreover, weak emission is detected at the outskirts, where the morphology seems indicative of a mild shaping by interaction of the wind with the interstellar medium, which is also supported by the stellar space motion. Two shells are found around RT Cap that were not known so far in either dust emission or from molecular line observations. The inner shell with a diameter of 188" shows an almost immaculate spherical symmetry, while the outer ~5' structure is more irregularly shaped. MoD, a modification of the DUSTY radiative transfer code, was used to model the detached shells. Dust temperatures, shell dust masses, and mass-loss rates are derived for both targets

Herschel/PACS observations of the 69 μm\mu m band of crystalline olivine around evolved stars

We present 48 Herschel/PACS spectra of evolved stars in the wavelength range of 67-72 $\mu$m. This wavelength range covers the 69 $\mu$m band of crystalline olivine ($\text{Mg}_{2-2x}\text{Fe}_{(2x)}\text{SiO}_{4}$). The width and wavelength position of this band are sensitive to the temperature and composition of the crystalline olivine. Our sample covers a wide range of objects: from high mass-loss rate AGB stars (OH/IR stars, $\dot M \ge 10^{-5}$ M$_\odot$/yr), through post-AGB stars with and without circumbinary disks, to planetary nebulae and even a few massive evolved stars. The goal of this study is to exploit the spectral properties of the 69 $\mu$m band to determine the composition and temperature of the crystalline olivine. Since the objects cover a range of evolutionary phases, we study the physical and chemical properties in this range of physical environments. We fit the 69 $\mu$m band and use its width and position to probe the composition and temperature of the crystalline olivine. For 27 sources in the sample, we detected the 69 $\mu$m band of crystalline olivine ($\text{Mg}_{(2-2x)}\text{Fe}_{(2x)}\text{SiO}_{4}$). The 69 $\mu$m band shows that all the sources produce pure forsterite grains containing no iron in their lattice structure. The temperature of the crystalline olivine as indicated by the 69 $\mu$m band, shows that on average the temperature of the crystalline olivine is highest in the group of OH/IR stars and the post-AGB stars with confirmed Keplerian disks. The temperature is lower for the other post-AGB stars and lowest for the planetary nebulae. A couple of the detected 69 $\mu$m bands are broader than those of pure magnesium-rich crystalline olivine, which we show can be due to a temperature gradient in the circumstellar environment of these stars. continued...Comment: Accepted for publication in A&

Morphological effects on IR band profiles: Experimental spectroscopic analysis with application to observed spectra of oxygen-rich AGB stars

To trace the source of the unique 13, 19.5, and 28 $\mu$m emission features in the spectra of oxygen-rich circumstellar shells around AGB stars, we have compared dust extinction spectra obtained by aerosol measurements. We have measured the extinction spectra for 19 oxide powder samples of eight different types, such as Ti-compounds (TiO, TiO$_2$, Ti$_2$O$_3$, Ti$_3$O$_5$, Al$_2$TiO$_5$, CaTiO$_3$), $\alpha$-, $\gamma$-, $\chi$-$\delta$-$\kappa$-Al$_2$O$_3$, and MgAl$_2$O$_4$ in the infrared region (10 - 50 $\mu$m) paying special attention to the morphological (size, shape, and agglomeration) effects and the differences in crystal structure. Anatase (TiO$_2$) particles with rounded edges are the possible 13, 19.5 and 28 $\mu$m band carriers as the main contributor in the spectra of AGB stars, and spherically shaped nano-sized spinel and Al$_2$TiO$_5$ dust grains are possibly associated with the anatase, enhancing the prominence of the 13 $\mu$m feature and providing additional features at 28 $\mu$m. The extinction data sets obtained by the aerosol and CsI pellet measurements have been made available for public use at http://elbe.astro.uni-jena.deComment: 17 pages, 8 figures, Accepted 24 March 2009 for publication in A&

The Magellanic zoo: Mid-infrared Spitzer spectroscopy of evolved stars and circumstellar dust in the Magellanic Clouds

We observed a sample of evolved stars in the Large and Small Magellanic Clouds (LMC and SMC) with the Infrared Spectrograph on the Spitzer Space Telescope. Comparing samples from the SMC, LMC, and the Galaxy reveals that the dust-production rate depends on metallicity for oxygen-rich stars, but carbon stars with similar pulsation properties produce similar quantities of dust, regardless of their initial metallicity. Other properties of the oxygen-rich stars also depend on metallicity. As the metallicity decreases, the fraction of naked (i.e. dust-free) stars increases, and among the naked stars, the strength of the 8 um absorption band from SiO decreases. Our sample includes several massive stars in the LMC with long pulsation periods which produce significant amounts of dust, probably because they are young and relatively metal rich. Little alumina dust is seen in circumstellar shells in the SMC and LMC, unlike in Galactic samples. Three oxygen-rich sources also show emission from magnesium-rich crystalline silicates. Many also show an emission feature at 14 um. The one S star in our sample shows a newly detected emission feature centered at 13.5 um. At lower metallicity, carbon stars with similar amounts of amorphous carbon in their shells have stronger absorption from molecular acetylene (C_2H_2) and weaker emission from SiC and MgS dust, as discovered in previous studies.Comment: ApJ, in press, about 27 pages, 29 figure

The Spitzer Spectroscopic Survey of S-type Stars

S-type AGB stars are thought to be in the transitional phase between M-type and C-type AGB stars. Because of their peculiar chemical composition, one may expect a strong influence of the stellar C/O ratio on the molecular chemistry and the mineralogy of the circumstellar dust. In this paper, we present a large sample of 87 intrinsic galactic S-type AGB stars, observed at infrared wavelengths with the Spitzer Space Telescope, and supplemented with ground-based optical data. On the one hand, we derive the stellar parameters from the optical spectroscopy and photometry, using a grid of model atmospheres. On the other, we decompose the infrared spectra to quantify the flux-contributions from the different dust species. Finally, we compare the independently determined stellar parameters and dust properties. For the stars without significant dust emission, we detect a strict relation between the presence of SiS absorption in the Spitzer spectra and the C/O ratio of the stellar atmosphere. These absorption bands can thus be used as an additional diagnostic for the C/O ratio. For stars with significant dust emission, we define three groups, based on the relative contribution of certain dust species to the infrared flux. We find a strong link between group-membership and C/O ratio. We show that these groups can be explained by assuming that the dust-condensation can be cut short before silicates are produced, while the remaining free atoms and molecules can then form the observed magnesium sulfides or the carriers of the unidentified 13 and 20 micron features. Finally, we present the detection of emission features attributed to molecules and dust characteristic to C-type stars, such as molecular SiS, hydrocarbons and magnesium sulfide grains. We show that we often detect magnesium sulfides together with molecular SiS and we propose that it is formed by a reaction of SiS molecules with Mg.Comment: Accepted for publication in A&

X Her and TX Psc: Two cases of ISM interaction with stellar winds observed by Herschel

The asymptotic giant branch (AGB) stars X Her and TX Psc have been imaged at 70 and 160 microns with the PACS instrument onboard the Herschel satellite, as part of the large MESS (Mass loss of Evolved StarS) Guaranteed Time Key Program. The images reveal an axisymmetric extended structure with its axis oriented along the space motion of the stars. This extended structure is very likely to be shaped by the interaction of the wind ejected by the AGB star with the surrounding interstellar medium (ISM). As predicted by numerical simulations, the detailed structure of the wind-ISM interface depends upon the relative velocity between star+wind and the ISM, which is large for these two stars (108 and 55 km/s for X Her and TX Psc, respectively). In both cases, there is a compact blob upstream whose origin is not fully elucidated, but that could be the signature of some instability in the wind-ISM shock. Deconvolved images of X Her and TX Psc reveal several discrete structures along the outermost filaments, which could be Kelvin-Helmholtz vortices. Finally, TX Psc is surrounded by an almost circular ring (the signature of the termination shock?) that contrasts with the outer, more structured filaments. A similar inner circular structure seems to be present in X Her as well, albeit less clearly.Comment: 11 pages, Astronomy & Astrophysics, in pres

Herschel's view into Mira's head

Herschel's PACS instrument observed the environment of the binary system Mira Ceti in the 70 and 160 micron bands. These images reveal bright structures shaped as five broken arcs and fainter filaments in the ejected material of Mira's primary star. The overall shape of the IR emission around Mira deviates significantly from the expected alignment with Mira's exceptionally high space velocity. The observed broken arcs are neither connected to each other nor are they of a circular shape; they stretch over angular ranges of 80 to 100 degrees. By comparing Herschel and GALEX data, we found evidence for the disruption of the IR arcs by the fast outflow visible in both Halpha and the far UV. Radial intensity profiles are derived, which place the arcs at distances of 6-85" (550 - 8000 AU) from the binary. Mira's IR environment appears to be shaped by the complex interaction of Mira's wind with its companion, the bipolar jet, and the ISM.Comment: 4 page

Unifying generative and discriminative learning principles

<p>Abstract</p> <p>Background</p> <p>The recognition of functional binding sites in genomic DNA remains one of the fundamental challenges of genome research. During the last decades, a plethora of different and well-adapted models has been developed, but only little attention has been payed to the development of different and similarly well-adapted learning principles. Only recently it was noticed that discriminative learning principles can be superior over generative ones in diverse bioinformatics applications, too.</p> <p>Results</p> <p>Here, we propose a generalization of generative and discriminative learning principles containing the maximum likelihood, maximum a posteriori, maximum conditional likelihood, maximum supervised posterior, generative-discriminative trade-off, and penalized generative-discriminative trade-off learning principles as special cases, and we illustrate its efficacy for the recognition of vertebrate transcription factor binding sites.</p> <p>Conclusions</p> <p>We find that the proposed learning principle helps to improve the recognition of transcription factor binding sites, enabling better computational approaches for extracting as much information as possible from valuable wet-lab data. We make all implementations available in the open-source library Jstacs so that this learning principle can be easily applied to other classification problems in the field of genome and epigenome analysis.</p