75 research outputs found
A radical approach to promote multiferroic coupling in double perovskites
Double perovskites provide a unique opportunity to induce and control
multiferroic behaviors in oxide systems. The appealing possibility to design
materials with a strong coupling between the magnetization and the polarization
fields may be achieved in this family since these magnetic insulators can
present structural self-ordering in the appropriate growth conditions. We have
studied the functional properties of La2CoMnO6 and Bi2CoMnO6 epitaxial thin
films grown by pulsed laser deposition. Cation-ordered La2CoMnO6 films display
a magnetic Curie temperature of 250 K while cation-disordered Bi2CoMnO6 films
present ferromagnetism up to ~ 800 K. Such high transition temperature for
magnetic ordering can be further tuned by varying the strain in the films
indicating an important contribution from the structural characteristics of the
materials. Our approach might be generalized for other oxide systems. At this
end, our results are compared with other multiferroic systems. The roles of
various cations, their arrangements and structural effects are further
discussed.Comment: 12 pages, 5 fig
Relations between structural distortions and transport properties in NdCaMnO strained thin films
Strained thin films of charge/orbital ordered (CO/OO)
(NCMO) with various thickness have grown on (100)-SrTiO and (100)-LaAlO
substrates, by using the Pulsed Laser Deposition (PLD) technique. The thickness
of the films influences drastically the transport properties. As the thickness
decreases, the CO transition increases while at the same time the
insulator-to-metal transition temperature decreases under application of a 7T
magnetic field. Clear relationships between the structural distortions and the
transport properties are established. They are explained on the basis of the
elongation and the compression of the Mn-O-Mn and Mn-O bond angles and
distances of the \QTR{it}{Pnma} structure, which modify the bandwidth and the
Jahn-Teller distortion in these materialsComment: 11 pages, 6 figures. to be published in Journal Physics: Condensed
Matte
Scaling and commensurate-incommensurate crossover for the d=2, z=2 quantum critical point of itinerant antiferromagnets
Quantum critical points exist at zero temperature, yet, experimentally their
influence seems to extend over a large part of the phase diagram of systems
such as heavy-fermion compounds and high-temperature superconductors.
Theoretically, however, it is generally not known over what range of parameters
the physics is governed by the quantum critical point. We answer this question
for the spin-density wave to fermi-liquid quantum critical point in the
two-dimensional Hubbard model. This problem is in the universality
class. We use the Two-Particle Self-Consistent approach, which is accurate from
weak to intermediate coupling, and whose critical behavior is the same as for
the self-consistent-renormalized approach of Moriya. Despite the presence of
logarithmic corrections, numerical results demonstrate that quantum critical
scaling for the static magnetic susceptibility can extend up to very high
temperatures but that the commensurate to incommensurate crossover leads to
deviations to scaling.Comment: Unchanged numerical results. It is now shown analytically that the
approach includes logarithmic corrections and that the critical behavior is
equivalent to the theory of Moriya. 6 pages, 3 figures, Late
Redox reactivity at silver microparticle—glassy carbon contacts under a coating of polymer of intrinsic microporosity (PIM)
Morphology and Photoluminescence of HfO2Obtained by Microwave-Hydrothermal
In this letter, we report on the obtention of hafnium oxide (HfO2) nanostructures by the microwave-hydrothermal method. These nanostructures were analyzed by X-ray diffraction (XRD), field-emission gum scanning electron microscopy (FEG-SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDXS), ultraviolet–visible (UV–vis) spectroscopy, and photoluminescence (PL) measurements. XRD patterns confirmed that this material crystallizes in a monoclinic structure. FEG-SEM and TEM micrographs indicated that the rice-like morphologies were formed due to an increase in the effective collisions between the nanoparticles during the MH processing. The EDXS spectrum was used to verify the chemical compositional of this oxide. UV–vis spectrum revealed that this material have an indirect optical band gap. When excited with 488 nm wavelength at room temperature, the HfO2nanostructures exhibited only one broad PL band with a maximum at around 548 nm (green emission)
Recommended reading list of early publications on atomic layer deposition-Outcome of the "Virtual Project on the History of ALD"
Atomic layer deposition (ALD), a gas-phase thin film deposition technique based on repeated, self-terminating gas-solid reactions, has become the method of choice in semiconductor manufacturing and many other technological areas for depositing thin conformal inorganic material layers for various applications. ALD has been discovered and developed independently, at least twice, under different names: atomic layer epitaxy (ALE) and molecular layering. ALE, dating back to 1974 in Finland, has been commonly known as the origin of ALD, while work done since the 1960s in the Soviet Union under the name "molecular layering" (and sometimes other names) has remained much less known. The virtual project on the history of ALD (VPHA) is a volunteer-based effort with open participation, set up to make the early days of ALD more transparent. In VPHA, started in July 2013, the target is to list, read and comment on all early ALD academic and patent literature up to 1986. VPHA has resulted in two essays and several presentations at international conferences. This paper, based on a poster presentation at the 16th International Conference on Atomic Layer Deposition in Dublin, Ireland, 2016, presents a recommended reading list of early ALD publications, created collectively by the VPHA participants through voting. The list contains 22 publications from Finland, Japan, Soviet Union, United Kingdom, and United States. Up to now, a balanced overview regarding the early history of ALD has been missing; the current list is an attempt to remedy this deficiency. (C) 2016 Author(s).Peer reviewe
Time evolution of ZnO-CNT photoluminescence under variable ambient and temperature conditions
ZnO-CNT hybrid materials were prepared by non-aqueous sol-gel routes at 240ºC. The morphology and defects have been studied by transmission electron microscopy and photoluminescence spectroscopy. The hybrid nanostructures manifest a broad luminescence emission covering the visible spectrum. Variations in photoluminescence with time are observed for the ZnO-CNT hybrid structures exposed to different ambient and temperatures. The studies show that photoluminescence from adsorbed oxygen dominates the emission emanating from other intrinsic defects and also affects the stability of the latter over time
Selective photocurrent generation in HfO2 and carbon nanotube hybrid nanocomposites under Ultra-Violet and visible photoexcitations
International audienceWe report on the photocurrent generation in HfO2-carbon nanotube (CNT) nanocomposites under Ultra-Violet (UV) and visible excitations at zero bias. Cubic phase HfO2 nanoparticles have been combined with multi-walled carbon nanotubes in this work. The cubic phase of HfO2 has been stabilized by oxygen vacancies which act as luminescent band gap states. In a broad UV-visible range of below band gap photoexcitation, a photocurrent is generated which was found to be most efficient under UV illumination. We discuss the possible mechanism in terms of a CNT assisted charge transfer involving optically active surface states of the HfO2 nanoparticles. The abrupt generation and relaxation responses of the photocurrent on/off cycles along with a constant steady state current as high as 200nA for 1mg of the nanocomposite, has potential in energy harvesting and other applications requiring stable charge retention
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