711 research outputs found
Synthesis and crystal structure of 1,4,10,13-tetraoxa-7,16-diazoniumcyclo-octadecane bis(4-chloro-2-methyl-phenoxyacetate)
The title compound was prepared by the reaction of 1,4,10,13-tetraoxa-7,16-diazacyclo-octadecane with 4-chloro-2-methyl-phenoxyacetic acid in a ratio of 1:2. The structure has been proved by the data of elemental analysis, IR spectroscopy, NMR (1H, 13C) technique and by X-ray diffraction analysis. Intermolecular hydrogen bonds between the azonium protons and oxygen atoms of the carboxylate groups were found. Immunoactive properties of the title compound have been screened. The compound has the ability to suppress spontaneous and Con A-stimulated cell proliferation in vitro and therefore can be considered as immunodepressant
Elastic Mid-Infrared Light Scattering: a Basis for Microscopy of Large-Scale Electrically Active Defects in Semiconducting Materials
A method of the mid-IR-laser microscopy has been proposed for the
investigation of the large-scale electrically and recombination active defects
in semiconductors and non-destructive inspection of semiconductor materials and
structures in the industries of microelectronics and photovoltaics. The basis
for this development was laid with a wide cycle of the investigations on the
low-angle mid-IR-light scattering in semiconductors. The essence of the
technical idea was to apply the dark-field method for spatial filtering of the
scattered light in the scanning mid-IR-laser microscope. This approach enabled
the visualization of large-scale electrically active defects which are the
regions enriched with ionized electrically active centers. The photoexcitation
of excess carriers within a small volume located in the probe mid-IR-laser beam
enabled the visualization of the large-scale recombination-active defects like
those revealed in the optical or electron beam induced current methods. Both
these methods of the scanning mid-IR-laser microscopy are now introduced in
detail in the present paper as well as a summary of techniques used in the
standard method of the lowangle mid-IR-light scattering itself. Besides the
techniques for direct observations, methods for analyses of the defect
composition associated with the mid-IR-laser microscopy are also discussed in
the paper.Comment: 44 pages, 13 figures. A good oldi
Characterisation of the Mopra Radio Telescope at 16--50 GHz
We present the results of a programme of scanning and mapping observations of
astronomical masers and Jupiter designed to characterise the performance of the
Mopra Radio Telescope at frequencies between 16-50 GHz using the 12-mm and 7-mm
receivers. We use these observations to determine the telescope beam size, beam
shape and overall telescope beam efficiency as a function of frequency. We find
that the beam size is well fit by / over the frequency range with a
correlation coefficient of ~90%. We determine the telescope main beam
efficiencies are between ~48-64% for the 12-mm receiver and reasonably flat at
~50% for the 7-mm receiver. Beam maps of strong HO (22 GHz) and SiO masers
(43 GHz) provide a means to examine the radial beam pattern of the telescope.
At both frequencies the radial beam pattern reveals the presence of three
components, a central `core', which is well fit by a Gaussian and constitutes
the telescopes main beam, and inner and outer error beams. At both frequencies
the inner and outer error beams extend out to approximately 2 and 3.4 times the
full-width half maximum of the main beam respectively. Sources with angular
sizes a factor of two or more larger than the telescope main beam will couple
to the main and error beams, and therefore the power contributed by the error
beams needs to be considered. From measurements of the radial beam power
pattern we estimate the amount of power contained in the inner and outer error
beams is of order one-fifth at 22 GHz rising slightly to one-third at 43 GHz.Comment: Accepted for publication in PAS
A search for ionized jets towards massive young stellar objects
Radio continuum observations using the Australia telescope compact array at 5.5, 9.0, 17.0 and 22.8 GHz have detected free-free emission associated with 45 of 49 massive young stellar objects and H II regions. Of these, 26 sources are classified as ionized jets (12 of which are candidates), 2 as ambiguous jets or disc winds, 1 as a disc-wind, 14 as H II regions and 2 were unable to be categorized. Classification as ionized jets is based upon morphology, radio flux and spectral index, in conjunction with previous observational results at other wavelengths. Radio luminosity and momentum are found to scale with bolometric luminosity in the same way as low-mass jets, indicating a common mechanism for jet production across all masses. In 13 of the jets, we see associated non-thermal/optically thin lobes resulting from shocks either internal to the jet and/or at working surfaces. 10 jets display non-thermal (synchrotron emission) spectra in their lobes, with an average spectral index of ? =-0.55 consistent with Fermi acceleration in shocks. This shows that magnetic fields are present, in agreement with models of jet formation incorporatingmagnetic fields. Since the production of collimated radio jets is associated with accretion processes, the results presented in this paper support the picture of disc-mediated accretion for the formation of massive stars with an upper limit on the jet phase lasting approximately 6.5Ă104 yr. Typical mass-loss rates in the jet are found to be 1.4Ă 10-5M? yr-1 with associated momentum rates of the order of (1-2) Ă 10-2M? km s-1 yr-1. © 2016 The Authors. Published by Oxford University Press on behalf of The Royal Astronomical Society
Cold gas outflows from the Small Magellanic Cloud traced with ASKAP
Feedback from massive stars plays a critical role in the evolution of the
Universe by driving powerful outflows from galaxies that enrich the
intergalactic medium and regulate star formation. An important source of
outflows may be the most numerous galaxies in the Universe: dwarf galaxies.
With small gravitational potential wells, these galaxies easily lose their
star-forming material in the presence of intense stellar feedback. Here, we
show that the nearby dwarf galaxy, the Small Magellanic Cloud (SMC), has atomic
hydrogen outflows extending at least 2 kiloparsecs (kpc) from the star-forming
bar of the galaxy. The outflows are cold, , and may have formed
during a period of active star formation million years (Myr) ago. The
total mass of atomic gas in the outflow is solar masses, , or % of the total atomic gas of the galaxy. The inferred
mass flux in atomic gas alone, , is up to an order of magnitude greater than the star
formation rate. We suggest that most of the observed outflow will be stripped
from the SMC through its interaction with its companion, the Large Magellanic
Cloud (LMC), and the Milky Way, feeding the Magellanic Stream of hydrogen
encircling the Milky Way.Comment: Published in Nature Astronomy, 29 October 2018,
http://dx.doi.org/10.1038/s41550-018-0608-
Opportunities for improving personnel situation assessment in community pediatric services: a retrospective analytical descriptive study
Background. The variety of current methods for assessing the healthcare personnel resources remains insufficient to completely evaluate the actual staffing and needs of certain medical institutions. Using a combination of different sources of data enables a more comprehensive picture of the healthcare personnel situation to be obtained. Objective. To identify the potential for improving approaches to assessment of the personnel situation in community pediatric services at the regional level. Methods. The present study involved data from Krasnodar Krai, Astrakhan and Volgograd Oblasts: Federal Statistical Monitoring form No. 30 âInformation on Medical Organizationâ for 2007â2022, as well as depersonalized data from the regional registers of medical workers and assigned population of Krasnodar Krai as of 01.01.2023. The methodology involved statistical and analytical methods. The study estimated the following parameters: community pediatric staffing in relation to? the child population, the staffing level of pediatric full-time positions, the rate of part-time jobs, and the average number of children per pediatrician. Results. The study justified the possibility of using additional sources of data to evaluate the personnel situation in local, municipal or regional healthcare institutions. The authors suggested an interactive analytical board for graphical visualization of the current state of healthcare human resources. Conclusion. The introduction of additional sources of information and monitoring in the healthcare human resources policy encourages a systematic comprehensive approach to estimating the staffing requirements
The politics of in/visibility: carving out queer space in Ul'yanovsk
<p>In spite of a growing interest within sexualities studies in the concept of queer space (Oswin 2008), existing literature focuses almost exclusively on its most visible and territorialised forms, such as the gay scene, thus privileging Western metropolitan areas as hubs of queer consumer culture (Binnie 2004). While the literature has emphasised the political significance of queer space as a site of resistance to hegemonic gender and sexual norms, it has again predominantly focused on overt claims to public space embodied in Pride events, neglecting other less open forms of resistance.</p><p>
This article contributes new insights to current debates about the construction and meaning of queer space by considering how city space is appropriated by an informal queer network in Ulâianovsk. The group routinely occupied very public locations meeting and socialising on the street or in mainstream cafĂ©s in central Ulâianovsk, although claims to these spaces as queer were mostly contingent, precarious or invisible to outsiders. The article considers how provincial location affects tactics used to carve out communal space, foregrounding the importance of local context and collective agency in shaping specific forms of resistance, and questioning ethnocentric assumptions about the empowering potential of visibility.</p>
MALT-45: a 7 mm survey of the southern Galaxy - I. Techniques and spectral line data
We present the first results from the MALT-45 (Millimetre Astronomer's Legacy Team-45 GHz) Galactic Plane survey. We have observed 5 square degrees (l = 330°â335°, b = ±0 â . 5) for spectral lines in the 7 mm band (42â44 and 48â49 GHz), including CS (1â0), class I CH3OH masers in the 7(0,7)â6(1,6) A+ transition and SiO (1â0) v = 0, 1, 2, 3. MALT-45 is the first unbiased, large-scale, sensitive spectral line survey in this frequency range. In this paper, we present data from the survey as well as a few intriguing results; rigorous analyses of these science cases are reserved for future publications. Across the survey region, we detected 77 class I CH3OH masers, of which 58 are new detections, along with many sites of thermal and maser SiO emission and thermal CS. We found that 35 class I CH3OH masers were associated with the published locations of class II CH3OH, H2O and OH masers but 42 have no known masers within 60 arcsec. We compared the MALT-45 CS with NH3 (1,1) to reveal regions of CS depletion and high opacity, as well as evolved star-forming regions with a high ratio of CS to NH3. All SiO masers are new detections, and appear to be associated with evolved stars from the Spitzer Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (GLIMPSE). Generally, within SiO regions of multiple vibrational modes, the intensity decreases as v = 1, 2, 3, but there are a few exceptions where v = 2 is stronger than v = 1
Black-hole concept of a point-like nucleus with supercritical charge
The Dirac equation for an electron in the central Coulomb field of a
point-like nucleus with the charge greater than 137 is considered. This
singular problem, to which the fall-down onto the centre is inherent, is
addressed using a new approach, based on a black-hole concept of the singular
centre and capable of producing cut-off-free results. To this end the Dirac
equation is presented as a generalized eigenvalue boundary problem of a
self-adjoint operator. The eigenfunctions make complete sets, orthogonal with a
singular measure, and describe particles, asymptotically free and
delta-function-normalizable both at infinity and near the singular centre
. The barrier transmission coefficient for these particles responsible for
the effects of electron absorption and spontaneous electron-positron pair
production is found analytically as a function of electron energy and charge of
the nucleus. The singular threshold behaviour of the corresponding amplitudes
substitutes for the resonance behaviour, typical of the conventional theory,
which appeals to a finite-size nucleus.Comment: 22 pages, 5 figures, LATEX requires IOPAR
GASKAP -- The Galactic ASKAP Survey
A survey of the Milky Way disk and the Magellanic System at the wavelengths
of the 21-cm atomic hydrogen (HI) line and three 18-cm lines of the OH molecule
will be carried out with the Australian Square Kilometre Array Pathfinder
telescope. The survey will study the distribution of HI emission and absorption
with unprecedented angular and velocity resolution, as well as molecular line
thermal emission, absorption, and maser lines. The area to be covered includes
the Galactic plane (|b|< 10deg) at all declinations south of delta = +40deg,
spanning longitudes 167deg through 360deg to 79deg at b=0deg, plus the entire
area of the Magellanic Stream and Clouds, a total of 13,020 square degrees. The
brightness temperature sensitivity will be very good, typically sigma_T ~ 1 K
at resolution 30arcsec and 1 km/s. The survey has a wide spectrum of scientific
goals, from studies of galaxy evolution to star formation, with particular
contributions to understanding stellar wind kinematics, the thermal phases of
the interstellar medium, the interaction between gas in the disk and halo, and
the dynamical and thermal states of gas at various positions along the
Magellanic Stream.Comment: 45 pages, 8 figures, Pub. Astron. Soc. Australia (in press
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