3,822 research outputs found
Statistical Theory of Spin Relaxation and Diffusion in Solids
A comprehensive theoretical description is given for the spin relaxation and
diffusion in solids. The formulation is made in a general
statistical-mechanical way. The method of the nonequilibrium statistical
operator (NSO) developed by D. N. Zubarev is employed to analyze a relaxation
dynamics of a spin subsystem. Perturbation of this subsystem in solids may
produce a nonequilibrium state which is then relaxed to an equilibrium state
due to the interaction between the particles or with a thermal bath (lattice).
The generalized kinetic equations were derived previously for a system weakly
coupled to a thermal bath to elucidate the nature of transport and relaxation
processes. In this paper, these results are used to describe the relaxation and
diffusion of nuclear spins in solids. The aim is to formulate a successive and
coherent microscopic description of the nuclear magnetic relaxation and
diffusion in solids. The nuclear spin-lattice relaxation is considered and the
Gorter relation is derived. As an example, a theory of spin diffusion of the
nuclear magnetic moment in dilute alloys (like Cu-Mn) is developed. It is shown
that due to the dipolar interaction between host nuclear spins and impurity
spins, a nonuniform distribution in the host nuclear spin system will occur and
consequently the macroscopic relaxation time will be strongly determined by the
spin diffusion. The explicit expressions for the relaxation time in certain
physically relevant cases are given.Comment: 41 pages, 119 Refs. Corrected typos, added reference
Core reconstruction in pseudopotential calculations
A new method is presented for obtaining all-electron results from a
pseudopotential calculation. This is achieved by carrying out a localised
calculation in the region of an atomic nucleus using the embedding potential
method of Inglesfield [J.Phys. C {\bf 14}, 3795 (1981)]. In this method the
core region is \emph{reconstructed}, and none of the simplifying approximations
(such as spherical symmetry of the charge density/potential or frozen core
electrons) that previous solutions to this problem have required are made. The
embedding method requires an accurate real space Green function, and an
analysis of the errors introduced in constructing this from a set of numerical
eigenstates is given. Results are presented for an all-electron reconstruction
of bulk aluminium, for both the charge density and the density of states.Comment: 14 pages, 5 figure
Scale-free static and dynamical correlations in melts of monodisperse and Flory-distributed homopolymers: A review of recent bond-fluctuation model studies
It has been assumed until very recently that all long-range correlations are
screened in three-dimensional melts of linear homopolymers on distances beyond
the correlation length characterizing the decay of the density
fluctuations. Summarizing simulation results obtained by means of a variant of
the bond-fluctuation model with finite monomer excluded volume interactions and
topology violating local and global Monte Carlo moves, we show that due to an
interplay of the chain connectivity and the incompressibility constraint, both
static and dynamical correlations arise on distances . These
correlations are scale-free and, surprisingly, do not depend explicitly on the
compressibility of the solution. Both monodisperse and (essentially)
Flory-distributed equilibrium polymers are considered.Comment: 60 pages, 49 figure
Optimization of a high work function solution processed vanadium oxide hole-extracting layer for small molecule and polymer organic photovoltaic cells
We report a method of fabricating a high work function, solution processable vanadium oxide (V2Ox(sol)) hole-extracting layer. The atmospheric processing conditions of film preparation have a critical influence on the electronic structure and stoichiometry of the V2Ox(sol), with a direct impact on organic photovoltaic (OPV) cell performance. Combined Kelvin probe (KP) and ultraviolet photoemission spectroscopy (UPS) measurements reveal a high work function, n-type character for the thin films, analogous to previously reported thermally evaporated transition metal oxides. Additional states within the band gap of V2Ox(sol) are observed in the UPS spectra and are demonstrated using X-ray photoelectron spectroscopy (XPS) to be due to the substoichiometric nature of V2Ox(sol). The optimized V2Ox(sol) layer performance is compared directly to bare indiumâtin oxide (ITO), poly(ethyleneoxythiophene):poly(styrenesulfonate) (PEDOT:PSS), and thermally evaporated molybdenum oxide (MoOx) interfaces in both small molecule/fullerene and polymer/fullerene structures. OPV cells incorporating V2Ox(sol) are reported to achieve favorable initial cell performance and cell stability attributes
Multiple light scattering in anisotropic random media
In the last decade Diffusing Wave Spectroscopy (DWS) has emerged as a
powerful tool to study turbid media. In this article we develop the formalism
to describe light diffusion in general anisotropic turbid media. We give
explicit formulas to calculate the diffusion tensor and the dynamic absorption
coefficient, measured in DWS experiments. We apply our theory to uniaxial
systems, namely nematic liquid crystals, where light is scattered from thermal
fluctuations of the local optical axis, called director. We perform a detailed
analysis of the two essential diffusion constants, parallel and perpendicular
to the director, in terms of Frank elastic constants, dielectric anisotropy,
and applied magnetic field. We also point out the relevance of our results to
different liquid crystalline systems, such as discotic nematics, smectic-A
phases, and polymer liquid crystals. Finally, we show that the dynamic
absorption coefficient is the angular average over the inverse viscosity, which
governs the dynamics of director fluctuations.Comment: 23 pages, 12 ps figures, to be published in Phys. Rev.
Constraints on the Ď_(c1) versus Ď_(c2) polarizations in proton-proton collisions at âs = 8 TeV
The polarizations of promptly produced Ď_(c1) and Ď_(c2) mesons are studied using data collected by the CMS experiment at the LHC, in proton-proton collisions at âs=8ââTeV. The Ď_c states are reconstructed via their radiative decays Ď_c â J/ĎÎł, with the photons being measured through conversions to eâşeâť, which allows the two states to be well resolved. The polarizations are measured in the helicity frame, through the analysis of the Ď_(c2) to Ď_(c1) yield ratio as a function of the polar or azimuthal angle of the positive muon emitted in the J/Ď â ÎźâşÎźâť decay, in three bins of J/Ď transverse momentum. While no differences are seen between the two states in terms of azimuthal decay angle distributions, they are observed to have significantly different polar anisotropies. The measurement favors a scenario where at least one of the two states is strongly polarized along the helicity quantization axis, in agreement with nonrelativistic quantum chromodynamics predictions. This is the first measurement of significantly polarized quarkonia produced at high transverse momentum
Azimuthal anisotropy of charged particles at high transverse momenta in PbPb collisions at sqrt(s[NN]) = 2.76 TeV
The azimuthal anisotropy of charged particles in PbPb collisions at
nucleon-nucleon center-of-mass energy of 2.76 TeV is measured with the CMS
detector at the LHC over an extended transverse momentum (pt) range up to
approximately 60 GeV. The data cover both the low-pt region associated with
hydrodynamic flow phenomena and the high-pt region where the anisotropies may
reflect the path-length dependence of parton energy loss in the created medium.
The anisotropy parameter (v2) of the particles is extracted by correlating
charged tracks with respect to the event-plane reconstructed by using the
energy deposited in forward-angle calorimeters. For the six bins of collision
centrality studied, spanning the range of 0-60% most-central events, the
observed v2 values are found to first increase with pt, reaching a maximum
around pt = 3 GeV, and then to gradually decrease to almost zero, with the
decline persisting up to at least pt = 40 GeV over the full centrality range
measured.Comment: Replaced with published version. Added journal reference and DO
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