La liberté de penser son identité professionnelle : la résistance des responsables de formation au discours managérial en France

Cet article explore comment les responsables de formation professionnelle continue (RFPC) préservent leur subjectivité de la colonisation d’une idéologie libérale. Pour conserver leur liberté de penser leur activité et ne pas se réduire à des prestataires internes de service, l’analyse de 33 entretiens avec des RFPC montre qu’ils développent un travail identitaire complexe articulant détournement du discours de contrainte, mobilisation de valeurs professionnelles et comportements d’oppositions manifestes. Cette recherche ouvre des pistes d’investigation complémentaires en donnant à comprendre la résistance tant d’un public, les cadres, que d’un contexte, la fonction RH, rarement mobilisés.This article explores how continuous professional training professionals resist colonization of their subjectivity by neo-liberal market ideology. The analysis of 33 interviews with professional training professionals shows how they develop complex identity work, which articulates diverting constraining discourse, mobilizing professional values and manifest oppositional behavior in order to maintain their freedom to conceive their activity and avoid being reduced to the role of internal service provider. This research opens complementary research tracks for a better understanding of resistance within a given population: managers, as well as within the context of the human resources function, areas which are seldom mobilized.Este articulo examina la forma como los responsables de formación profesional continua (RFPC) preservan su subjetividad frente a la colonización de une ideología liberal. Para mantener libertad personal de concebir su actividad y no limitarse a ser prestatarios internos de servicio, el análisis de 33 entrevistas con RFPC destaca que ellos desarrollan un trabajo identitario complejo que articula desvió del discurso impuesto, movilización de los valores profesionales y comportamientos de oposiciones manifiestas. Esta investigación brinda pistas de investigación adicionales que permiten entender la resistencia tanto de un público, los ejecutivos, como de un contexto, la función RR.HH., que casi nunca son solicitados

Structural Behavior of Tc and I Ions in Nuclear Waste Glass

AbstractTechnetium-99 (Tc) and iodine-129 (I) are two long-lived fission products of high volatility, which makes their study in glass structure challenging. Both technetium and iodine have broad ranging multivalent chemistry and complex reactivity dependent on redox conditions; technetium and iodine redox may vary from Tc0 to Tc7+ and from I- to I7+. Relatively few studies have been done on their speciation in glass, in part because of their low retention at the temperatures required for glass melting. To better understand the redox and structural behavior of Tc and I in various nuclear waste glasses, a series of technetium- and iodine-containing borosilicate glasses of varied chemistry were prepared at scales ranging from a few grams to hundreds of kilograms. Technetium was included in both high-level and low-level nuclear waste glass formulations under a variety of redox conditions at concentrations ranging from 0.003 wt% to 0.06 wt%. Non-radioactive iodine glass samples were prepared in crucible melts using excess amounts of sodium or potassium iodide salts or ammonium iodate that resulted in concentrations ranging from 0.04 to 1.27 wt% iodine. These samples were also compared to glasses prepared in pilot-scale experiments in which the overall retentions reached 48% and 34% for technetium and iodine, respectively. Tc and I speciation in the resulting glasses were determined by X-ray absorption spectroscopy (XAS). While technetium was found as Tc0, Tc4+, and Tc7+, only I- was identified in these glasses. Previous studies of Tc local environment information inferred from K-edge XAS and Raman spectroscopy identified pertechnetate tetrahedra surrounded by network-modifying cations in oxidized glasses and octahedral TcO6 units in glasses prepared under reducing conditions. Conversely, iodine K-edge XAS of all glasses studied indicate iodide environments with lithium or sodium nearest-neighbors resembling disordered versions of octahedral sites in crystalline lithium or sodium iodide

Formation and thermal evolution of insoluble reservoir bitumen in Angolan carbonate reservoirs.

Pyrobitumen resulting from the thermal cracking of crude oil is a frequent occurrence in petroleum reservoirs. Despite the detrimental implications of pyrobitumen for the poroperm qualities of the reservoir; little is known about the evolution of pyrobitumen properties as a function of increasing thermal stress. A suite of pyrobitumen-bearing reservoir cores from the carbonate Jurassic Pinda formation in offshore Angola has been studied using geochemical and petrographic techniques (including elemental analysis, Rock Eval pyrolysis, GC, FTIR, XRD, SEM, TEM) in order to characterise the physical, chemical, and optical properties of the pyrobitumen as fully as possible. The 11 core samples contain pyrobitumen at reflectance values ranging from 0.55-2.24%Ro and display varying degrees of solubility in dichloromethane from 98% insoluble bitumen to 45% insoluble, indicating a substantial spread of maturity. However, these indicators of maturity, and further classical maturity indicators such as the H/C and Tmax show surprisingly poor mutual agreement

WE-HML: hybrid WCET estimation using machine learning for architectures with caches

International audienceModern processors raise a challenge for WCET estimation, since detailed knowledge of the processor microarchitecture is not available. This paper proposes a novel hybrid WCET estimation technique, WE-HML, in which the longest path is estimated using static techniques, whereas machine learning (ML) is used to determine the WCET of basic blocks. In contrast to existing literature using ML techniques for WCET estimation, WE-HML (i) operates on binary code for improved precision of learning, as compared to the related techniques operating at source code or intermediate code level; (ii) trains the ML algorithms on a large set of automatically generated programs for improved quality of learning; (iii) proposes a technique to take into account data caches. Experiments on an ARM Cortex-A53 processor show that for all benchmarks, WCET estimates obtained by WE-HML are larger than all possible execution times. Moreover, the cache modeling technique of WE-HML allows an improvement of 65 percent on average of WCET estimates compared to its cache-agnostic equivalent

Comparative Long-Term Effect of Three Anti-P2Y12 Drugs after Percutaneous Angioplasty: An Observational Study Based on Electronic Drug Adherence Monitoring

Aims: Dual platelet inhibition using anti-P2Y12 drugs and aspirin is the standard of care in patients after percutaneous coronary interventions (PCI). Prasugrel and ticagrelor have been shown to be more potent than clopidogrel with less high on-treatment platelet reactivity. Whether differences in long-term adherence to these drugs can partly explain different antiplatelet efficacy has not been studied so far. The objective was to compare the long-term P2Y12 receptor inhibition and drug adherence to different anti-P2Y12 drugs, and to assess the impact of adherence on the pharmacodynamic effect.Methods: Monocentric, prospective, observational study. Stable outpatients treated with clopidogrel 75 mg once daily, prasugrel 10 mg once daily or ticagrelor 90 mg twice daily after PCI with stent implantation were included. Drug adherence was recorded during 6 months using electronic monitoring. Platelet responsiveness was assessed with the vasodilator-stimulated phosphoprotein platelet reactivity index (VASP-PRI) at inclusion, 3 and 6 months.Results: 120 patients had VASP-PRI and adherence data available. At 6-months, mean VASP-PRI (±SD) was 17.7 ± 11.0% with ticagrelor, 29.2 ± 15.5% with prasugrel and 47.2 ± 17.6% with clopidogrel (ANOVA, P < 0.0001).Median [IQR] taking adherence was 96 [82–100]% with ticagrelor, 100 [97–101]% with prasugrel and 100 [99–101]% with clopidogrel (p = 0.0001). Median [IQR] correct dosing was 88 [73–95]% with ticagrelor, 97 [92.5–98]% with prasugrel and 98 [96–99]% with clopidogrel (p = 0.0001).Anti-P2Y12 drug (p ≤ 0.001) and diabetes (p = 0.014) emerged as predictors of poor antiplatelet response after adjusting for age, BMI, sex, and CYP2C19∗2 carriers status.Conclusion: Drug adherence to anti-P2Y12 drugs assessed with electronic monitoring was very high. However, anti-P2Y12 drugs showed significant differences in antiplatelet activity, with newer anti-P2Y12 drugs ticagrelor and prasugrel exerting a stronger P2Y12 receptor inhibition.These data suggest that pharmacokinetic-pharmacodynamic differences between oral anti-P2Y12 drugs are more important than adherence in determining antiplatelet efficacy when adherence to prescription is high.The study was registered (Current Controlled Trials ISRCTN85949729)

Preparation and deep characterization of composite/hybrid multi-scale and multi-domain polymeric microparticles

Polymeric microparticles were produced following a three-step procedure involving (i) the production of an aqueous nanoemulsion of tri and monofunctional acrylate-based monomers droplets by an elongational-flow microemulsifier, (ii) the production of a nanosuspension upon the continuous-flow UV-initiated miniemulsion polymerization of the above nanoemulsion and (iii) the production of core-shell polymeric microparticles by means of a microfluidic capillaries-based double droplets generator; the core phase was composed of the above nanosuspension admixed with a water-soluble monomer and gold salt, the shell phase comprised a trifunctional monomer, diethylene glycol and a silver salt; both phases were photopolymerized on-the-fly upon droplet formation. Resulting microparticles were extensively analyzed by energy dispersive X-rays spectrometry and scanning electron microscopy to reveal the core-shell morphology, the presence of silver nanoparticles in the shell, organic nanoparticles in the core but failed to reveal the presence of the gold nanoparticles in the core presumably due to their too small size (c.a. 2.5 nm). Nevertheless, the reddish appearance of the as such prepared polymer microparticles emphasized that this three-step procedure allowed the easy elaboration of composite/hybrid multi-scale and multi-domain polymeric microparticles

Fresh air in the 21st century?

Ozone is an air quality problem today for much of the world's population. Regions can exceed the ozone air quality standards (AQS) through a combination of local emissions, meteorology favoring pollution episodes, and the clean-air baseline levels of ozone upon which pollution builds. The IPCC 2001 assessment studied a range of global emission scenarios and found that all but one projects increases in global tropospheric ozone during the 21st century. By 2030, near-surface increases over much of the northern hemisphere are estimated to be about 5 ppb (+2 to +7 ppb over the range of scenarios). By 2100 the two more extreme scenarios project baseline ozone increases of >20 ppb, while the other four scenarios give changes of -4 to +10 ppb. Even modest increases in the background abundance of tropospheric ozone might defeat current AQS strategies. The larger increases, however, would gravely threaten both urban and rural air quality over most of the northern hemisphere

Women’s experiences of receiving care for pelvic organ prolapse: a qualitative study

Background Pelvic organ prolapse is a common urogenital condition affecting 41–50% of women over the age of 40. To achieve early diagnosis and appropriate treatment, it is important that care is sensitive to and meets women’s needs, throughout their patient journey. This study explored women’s experiences of seeking diagnosis and treatment for prolapse and their needs and priorities for improving person-centred care. Methods Twenty-two women receiving prolapse care through urogynaecology services across three purposefully selected NHS UK sites took part in three focus groups and four telephone interviews. A topic guide facilitated discussions about women’s experiences of prolapse, diagnosis, treatment, follow-up, interactions with healthcare professionals, overall service delivery, and ideals for future services to meet their needs. Data were analysed thematically. Results Three themes emerged relating to women’s experiences of a) Evaluating what is normal b) Hobson’s choice of treatment decisions, and c) The trial and error of treatment and technique. Women often delayed seeking help for their symptoms due to lack of awareness, embarrassment and stigma. When presented to GPs, their symptoms were often dismissed and unaddressed until they became more severe. Women reported receiving little or no choice in treatment decisions. Choices were often influenced by health professionals’ preferences which were subtly reflected through the framing of the offer. Women’s embodied knowledge of their condition and treatment was largely unheeded, resulting in decisions that were inconsistent with women’s preferences and needs. Physiotherapy based interventions were reported as helping women regain control over their symptoms and life. A need for greater awareness of prolapse and physiotherapy interventions among women, GPs and consultants was identified alongside greater focus on prevention, early diagnosis and regular follow-up. Greater choice and involvement in treatment decision making was desired. Conclusions As prolapse treatment options expand to include more conservative choices, greater awareness and education is needed among women and professionals about these as a first line treatment and preventive measure, alongside a multi-professional team approach to treatment decision making. Women presenting with prolapse symptoms need to be listened to by the health care team, offered better information about treatment choices, and supported to make a decision that is right for them

Development of the vitrification compositional envelope to support complex-wide application of MAWS technology

This report presents the results from a study of the application of the Minimum Additive Waste Stabilization (MAWS) approach using vitrification as a treatment technology to a variety of waste streams across the DOE complex. This work has involved both experimental vitrification work using actual mixed wastes and surrogate waste streams from several DOE sites (Hanford, Idaho, and Oak Ridge) as well as the development of a computer-based, integrated glass property-composition database. The long-term objective is that this data base will assist glass formulation studies with single waste streams or combinations of waste streams subject to a variety of user-imposed constraints including waste stream usage priorities, process related constraints (e.g., melt viscosity, electrical conductivity, etc.), and waste form performance related constraints (e.g., TCLP and PCT leaching results). 79 refs., 143 figs., 65 tabs