Brazilian elections: voting for a scaling democracy

The proportional elections held in Brazil in 1998 and 2002 display identical statistical signatures. In particular, the distribution of votes among candidates includes a power-law regimen. We suggest that the rationale behind this robust scaling invariance is a multiplicative process in which the voter's choice for a candidate is governed by a product of probabilities.Comment: 4 pages, 2 figure

Inventario de la macrofauna bentónica de sedimentos submareales de la Ensenada de Baiona (Galicia, NO Península Ibérica)

Se presenta un inventario de la macrofauna submareal de fondos blandos de la Ensenada de Baiona (Ría de Vigo, Galicia) a partir de los resultados obtenidos en una serie de campañas de muestreo realizadas entre 1995 y 1997. El muestreo comprendió todos los tipos de sustratos sedimentarios submareales presentes en la ensenada, desde fango a grava, entre 2 y 12 m de profundidad. En total, se han identificado a nivel específico 474 taxones pertenecientes a 11 filos, repartidos del siguiente modo: Porifera (1 especie), Cnidaria (5), Nemertea (1), Annelida (169), Sipuncula (1), Arthropoda (158), Mollusca (119), Phoronida (1), Brachiopoda (1), Echinodermata (12) y Chordata (6)

The Complex Topology of Chemical Plants

We show that flowsheets of oil refineries can be associated to complex network topologies that are scale-free, display small-world effect and possess hierarchical organization. The emergence of these properties from such man-made networks is explained as a consequence of the currently used principles for process design, which include heuristics as well as algorithmic techniques. We expect these results to be valid for chemical plants of different types and capacities.Comment: 7 pages, 5 figures and 1 tabl

A mineralogical and organic geochemical overview of the effects of Holocene changes in Amazon River flow on three floodplain lakes

A synthesis of the impacts of the Amazon River hydrological changes on the sedimentation process of organic matter (OM) in three different floodplain lakes (Santa Ninha, Maracá, and Comprido lakes) is presented in this study. Today the Santa Ninha and Maracá lakes are directly and permanently connected with the main channel of the Amazon River, in contrast to Comprido Lake, which is indirectly and periodically influenced by the Amazon River due to its greater distance from the main channel. All three lake sediment records showed a reduced river inflow due to dry climatic conditions during the early and middle Holocene followed by an increased fluvial input during the wetter late Holocene. In Santa Ninha and Maraca Lakes, the reduced river inflow period was recorded by sediments with a low abundance of smectite (on average ~ 20 wt.%), a clay mineral mainly transported by the fluvial system, high total organic carbon (TOC) contents (on average ~ 8.2 wt.%), and a predominantly acidic soil OM input evidenced by high concentrations (on average 180 µg gTOC- 1) of branched glycerol dialkyl glycerol tetraethers (GDGT). During the late Holocene, a higher smectite abundance (on average ~ 43 wt.%) and a lower TOC content (on average ~ 1.4 wt.%) pointed to greater dilution by riverine lithogenic matter. This change was accompanied by a proportional increase in the aquatically produced crenarchaeol, suggesting a higher lake water level. In Comprido Lake, a sedimentation gap occurred during the early and middle Holocene. The wetter late Holocene, since 3000 cal years BP, was characterized by high TOC values (on average ~ 9 wt.%) and a sharp increase in soil OM input as recorded by an increase in branched GDGT concentrations (on average ~ 81 µg gTOC- 1), but the smectite content was low (on average ~ 14%). This combination suggests that the soil OM input to Comprido Lake from the local catchment area became dominant during the wet-climate late Holocene due to the large distance of the lake from the Amazon River main channel. Consequently, our study shows that the sedimentation processes of OM in Amazonian floodplain lakes were strongly influenced by variations in the hydrodynamic regime of the Amazon River during the Holocene. However, the impacts of the variations on the three floodplain lakes were different depending on the distance of each lake from the main channel of the Amazon River

Traveling length and minimal traveling time for flow through percolation networks with long-range spatial correlations

We study the distributions of traveling length l and minimal traveling time t through two-dimensional percolation porous media characterized by long-range spatial correlations. We model the dynamics of fluid displacement by the convective movement of tracer particles driven by a pressure difference between two fixed sites (''wells'') separated by Euclidean distance r. For strongly correlated pore networks at criticality, we find that the probability distribution functions P(l) and P(t) follow the same scaling Ansatz originally proposed for the uncorrelated case, but with quite different scaling exponents. We relate these changes in dynamical behavior to the main morphological difference between correlated and uncorrelated clusters, namely, the compactness of their backbones. Our simulations reveal that the dynamical scaling exponents for correlated geometries take values intermediate between the uncorrelated and homogeneous limiting cases

An innovative framework for probabilistic-based structural assessment with an application to existing reinforced concrete structures

A novel framework for probabilistic-based structural assessment of existing structures, which combines model identification and reliability assessment procedures, considering in an objective way different sources of uncertainty, is presented in this paper. A short description of structural assessment applications, provided in literature, is initially given. Then, the developed model identification procedure, supported in a robust optimization algorithm, is presented. Special attention is given to both experimental and numerical errors, to be considered in this algorithm convergence criterion. An updated numerical model is obtained from this process. The reliability assessment procedure, which considers a probabilistic model for the structure in analysis, is then introduced, incorporating the results of the model identification procedure. The developed model is then updated, as new data is acquired, through a Bayesian inference algorithm, explicitly addressing statistical uncertainty. Finally, the developed framework is validated with a set of reinforced concrete beams, which were loaded up to failure in laboratory

The unexpected 1,2,3,5-tetrahydroxybenzene central pathway

Funding Information: The authors are grateful to Maria C. Leitão (ITQB-NOVA Small Molecules Analysis) for the implementation and support in the chromatographic analyses. Mass spectrometry data were generated by the Mass Spectrometry Unit (UniMS), ITQB/iBET, Oeiras, Portugal. All members of the Silva Pereira lab are also thanked for useful discussions. Publisher Copyright: © 2023 The Authors. Microbial Biotechnology published by Applied Microbiology International and John Wiley & Sons Ltd.Saprophytic fungi are able to catabolize many plant-derived aromatics, including, for example, gallate. The catabolism of gallate in fungi is assumed to depend on the five main central pathways, i.e., of the central intermediates' catechol, protocatechuate, hydroxyquinol, homogentisate and gentisate, but a definitive demonstration is lacking. To shed light on this process, we analysed the transcriptional reprogramming of the growth of Aspergillus terreus on gallate compared with acetate as the control condition. Surprisingly, the results revealed that the five main central pathways did not exhibit significant positive regulation. Instead, an in-depth analysis identified four highly expressed and upregulated genes that are part of a conserved gene cluster found in numerous species of fungi, though not in Aspergilli. The cluster comprises a monooxygenase gene and a fumarylacetoacetate hydrolase-like gene, which are recognized as key components of catabolic pathways responsible for aromatic compound degradation. The other two genes encode proteins with no reported enzymatic activities. Through functional analyses of gene deletion mutants in Aspergillus nidulans, the conserved short protein with no known domains could be linked to the conversion of the novel metabolite 5-hydroxydienelatone, whereas the DUF3500 gene likely encodes a ring-cleavage enzyme for 1,2,3,5-tetrahydroxybenzene. These significant findings establish the existence of a new 1,2,3,5-tetrahydroxybenzene central pathway for the catabolism of gallate and related compounds (e.g. 2,4,6-trihydroxybenzoate) in numerous fungi where this catabolic gene cluster was observed.publishersversionpublishe

Spatial and seasonal contrasts of sedimentary organic matter in floodplain lakes of the central Amazon basin

In this study, we investigated the seasonal andspatial pattern of sedimentary organic matter (SOM) in fivefloodplain lakes of the central Amazon basin (Cabaliana,Janauaca, Canaçari, Mirituba and Curuai) which have differentmorphologies, hydrodynamics and vegetation coverages.Surface sediments were collected in four hydrologicalseasons: low water (LW), rising water (RW), high water(HW) and falling water (FW) in 2009 and 2010.We investigatedcommonly used bulk geochemical tracers such as theC V N ratio and the stable isotopic composition of organic carbon(?13Corg/. These results were compared with lignin phenolparameters as an indicator of vascular plant detritus andbranched glycerol dialkyl glycerol tetraethers (brGDGTs) totrace the input of soil organic matter (OM) from land to theaquatic settings. We also applied the crenarchaeol as an indicatorof aquatic (rivers and lakes) OM. Our data showed thatduring the RW and FW seasons, the surface sediments wereenriched in lignin and brGDGTs in comparison to other seasons.Our study also indicated that floodplain lake sedimentsprimarily consisted of allochthonous, C3 plant-derived OM.However, a downstream increase in C4 macrophyte-derivedOM contribution was observed along the gradient of increasingopen waters – i.e., from upstream to downstream. Accordingly,we attribute the temporal and spatial difference inSOM composition to the hydrological dynamics between thefloodplain lakes and the surrounding flooded forests

Cutin-derived oligomers induce hallmark plant immune responses

8003). RE and IM are grateful for FCT funding for the PhD scholarship BD/06435/2021 and for the working contract financed by national funds under norma transit\u00F3ria D.L. no. 57/2016, respectively. Publisher Copyright: © 2024 The Author(s). Published by Oxford University Press on behalf of the Society for Experimental Biology.The cuticle constitutes the outermost defensive barrier of most land plants. It comprises a polymeric matrix - cutin, surrounded by soluble waxes. Moreover, the cuticle constitutes the first line of defense against pathogen invasion, while also protecting the plant from many abiotic stresses. Aliphatic monomers in cutin have been suggested to act as immune elicitors in plants. This study analyses the potential of cutin oligomers to activate rapid signaling outputs reminiscent of pattern-triggered immunity in the model plant Arabidopsis. Cutin oligomeric mixtures led to Ca2+ influx and mitogen-activated protein kinase activation. Comparable responses were measured for cutin, which was also able to induce a reactive oxygen species burst. Furthermore, cutin oligomer treatment resulted in a unique transcriptional reprogramming profile, having many archetypal features of pattern-triggered immunity. Targeted spectroscopic and spectrometric analyses of the cutin oligomers suggest that the elicitor compounds consist mostly of two up to three 10,16-dihydroxyhexadecanoic acid monomers linked together through ester bonds. This study demonstrates that cutin breakdown products can act as inducers of early plant immune responses. Further investigation is needed to understand how cutin breakdowns are perceived and to explore their potential use in agriculture.publishersversionpublishe