Importancia del conocimiento empírico en obras civiles

This article is presented on the importance of empirical knowledge in order to make known the need, incidence and application of such knowledge in civil works. In addition, it is made with the purpose of documenting the subject that involves masters of work, engineers, workers and other participants of work, but that does not count with diffusion. The article was mostly written at the Universidad Distrital Francisco José de Caldas, Facultad Tecnológica, with the support of workers from the area, master builders, civil engineers and other participants in the work at the university and in the surrounding areas. It established the need for empirical thinking and made it clear that it is not the only thing necessary for good performance in civil works, reaching the conclusion that empirical knowledge and academic knowledge are necessary to perform in the best way in civil works because both knowledge are important for certain moments of working life.Se presenta este artículo sobre la importancia del conocimiento empírico con el fin de dar a conocer la necesidad, incidencia y aplicación de dicho conocimiento en obras civiles. Además, se realiza con el fin de documentar sobre el tema que involucra a maestros de obra, ingenieros, obreros y demás participantes de obra, pero que no cuanta con difusión. El artículo se realizó mayormente en la Universidad Distrital Francisco José de Caldas, Facultad Tecnológica con el apoyo de obreros de la zona, maestros de obra, ingenieros civiles y demás participantes de obras en la universidad y en zonas aledañas. Se establecieron necesidades del pensamiento empírico y se dejó claro que no es lo único necesario para un buen desempeño en obra civiles, llegando a la conclusión de que el conocimiento empírico y el conocimiento académico son necesarios para desempeñarse de la mejor manera en obras civiles pues ambos conocimientos son importantes para ciertos momentos de la vida laboral

Identifying Stagnation Zones and Reverse Flow Caused by River-Aquifer Interaction: An Approach Based on Polynomial Chaos Expansions

Fluctuating stream stages and peak-flow events can significantly influence the interactions between streams and aquifers and modify the hydraulic gradient, the flux exchange and the subsurface flow paths. As a result, stagnation zones and reverse flow may appear in different parts of an aquifer and at different times. These features of the flow field play a relevant role in the transport, transformation, and residence time of solutes, pollutants, and nutrients in the subsurface. However, their identification using numerical models is complex not only because of highly nonlinear dynamics, but also due to significant uncertainties in the model input data which propagate into the quantities of interest. In this work, we use an approach based on polynomial chaos expansions to map the probability of occurrence of stagnation zones and reverse flow during a flood event. We quantify the propagation of uncertainty into the groundwater flow field due to the applied river boundary conditions. Then, we evaluate the responses of the posterior probabilities in an element-wise fashion using a set of flow classification criteria and kernel density estimations. The proposed methodology is flexible because it employs a nonintrusive pseudo-spectral technique and, consequently, it can be applied straightforwardly in preexisting models. The regions near the confluence of two streams in the studied area are prone to present transient stagnation and reverse flow.publishedVersio

1-Heptene hydroformylation over phosphinated silica-anchored rhodium thiolate complexes.

[EN]The rhodium (I) pentaflurophenylthiolate complexes [Rh(μ-SC6F5)(COD)]2 and [Rh(μ-SC6F5)(CO)2]2 were anchored on phosphinated silica. These catalysts were tested in the hydroformylation reaction of 1-heptene in toluene at 343–393 K using a gas feed ratio of CO:H2=1 mole. The conversion of 1-heptene versus the reaction time followed S-shaped curves in which the induction period depended on the catalyst precursor and number of cycles in the reaction. Selectivity towards linear aldehyde was high, although the extent of isomerisation to internal olefins was found to be important. The addition of free PPh3 to the reaction medium markedly increased the yield to linear aldehyde but the rate of the reaction appeared to be retarded. The results are compared with those obtained on using these complexes in homogeneous phase under similar conditions. The effects of temperature, pressure and the phosphine/Rh mole ratio on the reaction rate and selectivity are discussed

Seed-specific transcription factor HSFA9 links embryogenesis and photomorphogenesis

Poster presentado en la XIII Reunión de Biología Molecular de Plantas. Oviedo 22-24 de junio de 2016 Posler 14/ $IV P14HSFA9, a seed-specific factor, enhances the expression of light receptors and genes required for chlorophyll biosynthesis before germinating seeds are illuminated. HSFA9 subsequently augments phytochrome-mediated responses and stimulates seedling greening.This work has been funded by FEDER (European Regional Development Fund) and by “Secretaría de Estado de Investigación, Desarrollo e Innovación” (projects BIO2011-23440 and BIO2014-52303-R). Additional funds were obtained from “Junta de Andalucía” (Group BIO148).Peer reviewe

Seed-specific transcription factor HSFA9 links late embryogenesis and early photomorphogenesis

HSFA9 is a seed-specific transcription factor that in sunflower (Helianthus annuus) is involved in desiccation tolerance and longevity. Here we show that the constitutive overexpression of HSFA9 in tobacco (Nicotiana tabacum) seedlings attenuated hypocotyl growth under darkness and accelerated the initial photosynthetic development. Plants overexpressing HSFA9 increased accumulation of carotenoids, chlorophyllide, and chlorophyll, and displayed earlier unfolding of the cotyledons. HSFA9 enhanced phytochrome-dependent light responses, as shown by an intensified hypocotyl length reduction after treatments with continuous far-red or red light. This observation indicated the involvement of at least two phytochromes: PHYA and PHYB. Reduced hypocotyl length under darkness did not depend on phytochrome photo-activation; this was inferred from the lack of effect observed using far-red light pulses applied before the dark treatment. HSFA9 increased the expression of genes that activate photomorphogenesis, including PHYA, PHYB, and HY5. HSFA9 might directly upregulate PHYA and indirectly affect PHYB transcription, as suggested by transient expression assays. Converse effects on gene expression, greening, and cotyledon unfolding were observed using a dominant-negative form of HSFA9, which was overexpressed under a seed-specific promoter. This work uncovers a novel transcriptional link, through HSFA9, between seed maturation and early photomorphogenesis. In all, our data suggest that HSFA9 enhances photomorphogenesis via early transcriptional effects that start in seeds under darkness

Physicochemical behavior of Riesling x Silvaner grapevine fruit under the high altitude conditions of Colombia (South America)

The Valle del Sol (Sun Valley) of the Boyacá department is a zone with temperate tropical climate conditions (2,500 m above sea level) that is suitable for the production of grapes for quality wine. The objective of this investigation was to study the physical and chemical behavior during growth and development of the grapevine fruit var. Riesling x Silvaner, produced for winemaking, in the municipality of Corrales (Boyacá, Colombia). To determine the physical and chemical characteristics of the fruit starting at 28 days after anthesis (daa), 14 weekly samplings were carried out, in each of which three clusters were taken from randomly selected plants. The development of the berry lasted 119 daa in which three stages were defi ned: herbaceous, veraison and maturation1. The herbaceous stage ended at 63 daa, the veraison period lasted 14 days and ended at 77 daa, whereas the maturation and ripening stage lasted 42 days; no period of overmaturity was observed. The behavior of the fresh mass, dry mass and diameter of the fruit followed a double sigmoid curve. During berry development, total soluble solids (from 5.03 to 23.73 °Brix at the harvest point), pH (from 2.88 to 3.71) and technological maturity index (from 2.27 to 21.84) all increased, whereas total titratable acidity decreased from 3.96 to 1.11%

Tryptophan depletion affects compulsive behaviour in rats:strain dependent effects and associated neuromechanisms

RATIONALE: Compulsive behaviour, present in different psychiatric disorders, such as obsessive-compulsive disorder, schizophrenia and drug abuse, is associated with altered levels of monoamines, particularly serotonin (5-hydroxytryptamine) and its receptor system. OBJECTIVES: The present study investigated whether 5-HT manipulation, through a tryptophan (TRP) depletion by diet in Wistar and Lister Hooded rats, modulates compulsive drinking in schedule-induced polydipsia (SIP) and locomotor activity in the open-field test. The levels of dopamine, noradrenaline, serotonin and its metabolite were evaluated, as well as the 5-HT(2A) and 5-HT(1A) receptor binding, in different brain regions. METHODS: Wistar rats were selected as high (HD) or low (LD) drinkers according to their SIP behaviour, while Lister hooded rats did not show SIP acquisition. Both strains were fed for 14 days with either a TRP-free diet (T−) or a TRP-supplemented diet (T+) RESULTS: The TRP depletion diet effectively reduced 5-HT levels in the frontal cortex, amygdala and hippocampus in both strains of rats. The TRP-depleted HD Wistar rats were more sensitive to 5-HT manipulation, exhibiting more licks on SIP than did the non-depleted HD Wistar rats, while the LD Wistar and the Lister Hooded rats did not exhibit differences in SIP. In contrast, the TRP-depleted Lister Hooded rats increased locomotor activity compared to the non-depleted rats, while no differences were found in the Wistar rats. Serotonin 2A receptor binding in the striatum was significantly reduced in the TRP-depleted HD Wistar rats. CONCLUSIONS: These results suggest that alterations of the serotonergic system could be involved in compulsive behaviour in vulnerable populations

Rhodium(I) fluorothiolate complexes as hydroformylation catalyst precursors. Crystal structure of two polymorphs of trans-[Rh(SC6F5)(CO)(PPh3)2]

[EN]The perfluorothiolate dinuclear compounds [Rh( ]A,-SC6E5XCOD)] 2 1 and [Rh( ]J~-SC6F5XCO)2] 2 2 react with PPh 3 to give monomeric and dimeric complexes, the particular product depending upon the PR3/Rh ratio and reaction conditions. Reaction of 2 with 2 moles of PPh 3 renders cis-7 and trans-[Rh(/x-SC6Fs)((CO)(PPh3)] z 8, while with 4 moles of PPh 3 trans[Rh(SC6FsXCO)(PPh3)E]lOa is obtained. This latter product can otherwise be prepared by C1 metathesis from trans-[RhCl(CO(PPh3) 2] in toluene. This same reaction in dichloromethane however yields the cis isomer 10b. When a larger excess of PPh 3 is used, a mixture of compounds 11a and llb is formed. An X-ray crystal structure study shows trans[Rh(SC6Fs)(CO)(PPh3) 2] to exit as two polymorphs. 11a crystallises in the space group P2t/n of the monoclinic system with a = 12.489(1), b = 15.430(5), c = 19.719(1) A, te = y= 90, /3 = 92.84(1) °, and llb is triclinic, space group P1 with a = 9.764(2), b = 12.197(6), c = 17.880 ]k, a = 100.18(5), /3 = 101.92(2), T= 113.61(2) °. Both PPh 3 ligands are mutually trans and the difference in u(CO) stretching frequencies, 1989 and 1939 cm -1, can be explained in terms of o-phenyl H... CO interactions in the latter. The [Rh(/z-SC6Fs)(COD)] 2 1 and [Rh(/.£-SC6FsXCO)2] 2 2/nPPh 3 systems have been studied as catalyst precursors for the hydroformylation of l-heptene in toluene at 30 bar and 343 K. Selectivity towards the linear aldehyde is enhanced when dimeric complexes are used

Radial and tangential migration of telencephalic somatostatin neurons originated from the mouse diagonal area

The telencephalic subpallium is the source of various GABAergic interneuron cohorts that invade the pallium via tangential migration. Based on genoarchitectonic studies, the subpallium has been subdivided into four major domains: striatum, pallidum, diagonal area and preoptic area (Puelles et al. 2013; Allen Developing Mouse Brain Atlas), and a larger set of molecularly distinct progenitor areas (Flames et al. 2007). Fate mapping, genetic lineage-tracing studies, and other approaches have suggested that each subpallial subdivision produces specific sorts of inhibitory interneurons, distinguished by differential peptidic content, which are distributed tangentially to pallial and subpallial target territories (e.g., olfactory bulb, isocortex, hippocampus, pallial and subpallial amygdala, striatum, pallidum, septum). In this report, we map descriptively the early differentiation and apparent migratory dispersion of mouse subpallial somatostatin-expressing (Sst) cells from E10.5 onward, comparing their topography with the expression patterns of the genes Dlx5, Gbx2, Lhx7-8, Nkx2.1, Nkx5.1 (Hmx3), and Shh, which variously label parts of the subpallium. Whereas some experimental results suggest that Sst cells are pallidal, our data reveal that many, if not most, telencephalic Sst cells derive from de diagonal area (Dg). Sst-positive cells initially only present at the embryonic Dg selectively populate radially the medial part of the bed nucleus striae terminalis (from paraseptal to amygdaloid regions) and part of the central amygdala; they also invade tangentially the striatum, while eschewing the globus pallidum and the preoptic area, and integrate within most cortical and nuclear pallial areas between E10.5 and E16.5.This work was funded by the Spanish Ministry of Science and Innovation grant BFU2008-04156, and SENECA Foundation contract 0458/GERM/06-10891 to L.P.; and the Local Government of Castilla-La Mancha grant PII1I09-0065-8194 to C.D. Infrastructure support provided by the University of Murcia and Castilla-La Mancha is also acknowledged

The spectral-type/luminosity and the spectral type/satellite-density relations in the 2dFGRS

We examine the relative fractions of passive (Type 1), quiet-SF (Type 2) and active-SF (Type 3+4) galaxies as a function of luminosity and number of neighbours in several volume limited samples selected from the 2dFGRS. Neighbours are counted within 1 $h_{75}^{-1}$ Mpc projected distance, and $\pm$ 1000 km s$^{-1}$ depth. We apply a maximum magnitude difference criterion and require neighbours to be fainter than the galaxy itself. We show that, whatever the environment, passive galaxies dominate in bright samples and active-SF galaxies in faint samples, whereas quiet-SF galaxies never dominate. We further show that in bright samples (M$_{B}$ -- 5 $\log$ $h_{75}$ $\leq$$- 19$) the fraction of passive galaxies grows steadily with fainter neighbour density, whereas in faint samples a threshold like dependence is observed. This suggests that the spectral-type / density ($\approx$ morphology / density) relation extends to intermediate dense environment, but only in the surrounding of luminous galaxies and that it reflects an enhancement of the number of satellites rather than stronger clustering among galaxies themselves. Our analysis indicates that, in general, luminosity is a good tracer of a galaxy halo mass and that it dominates over environment (satellite density) in setting the spectral type mix of a population. However, minority populations exist, such as luminous SF galaxies and faint passive galaxies, whose luminosity is an unfair tracer of halo mass.Comment: 8 pages, 5 figur