Ridge-trench collision-induced switching of arc tectonics and magma sources: clues from Antarctic Peninsula mafic dykes

Compositions and distributions of mafic dykes in the Antarctic Peninsula continental arc show that tapping of several mantle sources was tectonically controlled. In the Cretaceous to Tertiary, between 135 Ma and 55 Ma, calc-alkaline dykes intruded the arc. In the late Cretaceous, however, between 95 Ma and 65 Ma, there was a pulse of compositionally diverse magmatism. This change resulted from collision of an ocean spreading centre with the trench. As a consequence, non-partitioned dextral transtensional shear in the overriding plate became partitioned into strike-slip and extensional domains. Calc-alkaline magmatism was, therefore, replaced by strike-slip-related shoshonitic magmatism towards the rear-arc and extensionrelated tholeiitic magmatism towards the fore-arc. OIB-like dykes were emplaced because of the break in otherwise continuous subduction. During the early Tertiary subduction continued but ceased after a late Tertiary ridge-trench collision

Maximum extent and readvance dynamics of the Irish Sea Ice Stream since the Last Glacial Maximum

International audienceThe Irish Sea Ice Stream (ISIS) has long had one of the best documented retreat histories of the British-Irish Ice Sheet (BIIS) and was the first ice stream to be constrained by Bayesian analysis of geochronological data. These attributes made it a model system for the BRITICE-CHRONO research project, which aims to produce the best constrained retreat record of any palaeo-ice sheet contributing key observational constraints for ice sheet modelling. The project has generated a suite of new radiocarbon ages from deglacial sequences offshore in the Celtic and Irish seas and terrestrial cosmogenic nuclide and optically-stimulated luminescence ages from ice-marginal sites in the Isles of Scilly, Ireland, Wales and NW England. The ISIS was unusual within the former BIIS, in that it was a compound ice stream with two outlets, one marine terminating that flowed through the Irish Sea Basin into the Celtic Sea, and a terrestrial terminus that flowed southwards through Cheshire-Shropshire lowlands into the English Midlands around 25.5 ka. Here we assess the retreat dynamics across the entirety of the ISIS, integrating the new chronology in a revised Bayesian analysis that constrains the pattern and timing ice marginal fluctuations. The retreat chronology in the Irish Sea is better constrained than in the Celtic Sea, where the ISIS is now recognised to have extended as far as the continental shelf break to the SW of Britain and Ireland between 24 and 27 ka; this advance was synchronous with independently-dated ice-rafted detritus from ISIS in adjacent deep-sea cores. The ISIS then retreated rapidly northwards through the Celtic Sea, with evidence for readvance phases, deglaciating the Isles of Scilly at 25.5 ka, reaching St Georges Channel by 24.3 ka and the Llŷn Peninsula by 23.9 ka. The initiation of retreat from both the eastern (terrestrial) and western (marine) components of ISIS was synchronous. The eastern terrestrial lobe had vacated the Cheshire-Shropshire lowlands by 22-21 ka. The complex readvance sequences identified on the Llŷn (24-20ka) and in eastern Ireland have now been tightly constrained to register centennial-scale oscillations of the ice front driven by internal ice dynamics over topographic pinning points and constrictions of the ice-stream. Retreat northwards into the northern Irish Sea then accelerated, first evacuating the deeper water of the western Irish Sea, and developing pronounced ice margins across the northern Isle of Man by 19.1 ka. The final retreat phase, with ice margins pulling back onto terrestrial settings in the English Lake District, the north of Ireland and SW Scotland around 17 ka, was a deglaciation accomplished in a fully marine context evidenced by the preservation on the seabed of subglacial landforms and by increasing influence of local ice sources with flow realignment during draw-down and ice margin retreat

Electrochemical behaviour and surface analysis of chalcopyrite in alkaline glycine solutions

© 2018 Elsevier B.V. Electrochemical experiments with a chalcopyrite rotating disk electrode were carried out in alkaline glycine solutions. This showed no apparent passivation behaviour during anodic dissolution that is observed in acid solutions. The current increased with applied potential from the open circuit potential with no resemblance to the passivation region seen in acid solutions. A loosely held porous layer developed on the surface consisting largely of iron oxyhydroxides that had a limited effect on the anodic current. Elemental sulfur and a disulfide species were detected using XPS and Raman spectroscopy but did not passivate the surface as has been proposed for acid solutions. The disulfide species is sometimes used to infer a metal deficient sulfide or polysulfide that is responsible for passivation but in this study it had no passivating influence. Current-potential curves showed features of a non-ideal semiconductor that were explained by charge transfer via surface states

Growth and retreat of the last British–Irish Ice Sheet, 31 000 to 15 000 years ago: the BRITICE‐CHRONO reconstruction

The BRITICE-CHRONO consortium of researchers undertook a dating programme to constrain the timing of advance, maximum extent and retreat of the British–Irish Ice Sheet between 31 000 and 15 000 years before present. The dating campaign across Ireland and Britain and their continental shelves, and across the North Sea included 1500 days of field investigation yielding 18 000 km of marine geophysical data, 377 cores of sea floor sediments, and geomorphological and stratigraphical information at 121 sites on land; generating 690 new geochronometric ages. These findings are reported in 28 publications including synthesis into eight transect reconstructions. Here we build ice sheet-wide reconstructions consistent with these findings and using retreat patterns and dates for the inter-transect areas. Two reconstructions are presented, a wholly empirical version and a version that combines modelling with the new empirical evidence. Palaeoglaciological maps of ice extent, thickness, velocity, and flow geometry at thousand-year timesteps are presented. The maximum ice volume of 1.8 m sea level equivalent occurred at 23 ka. A larger extent than previously defined is found and widespread advance of ice to the continental shelf break is confirmed during the last glacial. Asynchrony occurred in the timing of maximum extent and onset of retreat, ranging from 30 to 22 ka. The tipping point of deglaciation at 22 ka was triggered by ice stream retreat and saddle collapses. Analysis of retreat rates leads us to accept our hypothesis that the marine-influenced sectors collapsed rapidly. First order controls on ice-sheet demise were glacio-isostatic loading triggering retreat of marine sectors, aided by glaciological instabilities and then climate warming finished off the smaller, terrestrial ice sheet. Overprinted on this signal were second order controls arising from variations in trough topographies and with sector-scale ice geometric readjustments arising from dispositions in the geography of the landscape. These second order controls produced a stepped deglaciation. The retreat of the British–Irish Ice Sheet is now the world’s most well-constrained and a valuable data-rich environment for improving ice-sheet modelling