152 research outputs found
Intrinsic avalanches and collective phenomena in a Mn(II)-free radical ferrimagnetic chain
Magnetic hysteresis loops below 300 mK on single crystals of the Mn(II) -
nitronyl nitroxide free radical chain (Mn(hfac)_2({\it R})-3MLNN) present
abrupt reversals of the magnetization, or avalanches. We show that, below 200
mK, the avalanches occur at a constant field, independent of the sample and so
propose that this avalanche field is an intrinsic property. We compare this
field to the energy barrier existing in the sample and conclude that the
avalanches are provoked by multiple nucleation of domain-walls along the
chains. The different avalanche field observed in the zero field cooled
magnetization curves suggests that the avalanche mechanisms are related to the
competition between ferromagnetic and antiferromagnetic order in this compound.Comment: 9 pages, 7 fig, to be published in Phys. Rev.
Subtle competition between ferromagnetic and antiferromagnetic order in a Mn(II) - free radical ferrimagnetic chain
The macroscopic magnetic characterization of the Mn(II) - nitronyl nitroxide
free radical chain (Mn(hfac)2(R)-3MLNN) evidenced its transition from a
1-dimensional behavior of ferrimagnetic chains to a 3-dimensional ferromagnetic
long range order below 3 K. Neutron diffraction experiments, performed on a
single crystal around the transition temperature, led to a different conclusion
: the magnetic Bragg reflections detected below 3 K correspond to a canted
antiferromagnet where the magnetic moments are mainly oriented along the chain
axis. Surprisingly in the context of other compounds in this family of magnets,
the interchain coupling is antiferromagnetic. This state is shown to be very
fragile since a ferromagnetic interchain arrangement is recovered in a weak
magnetic field. This peculiar behavior might be explained by the competition
between dipolar interaction, shown to be responsible for the antiferromagnetic
long range order below 3 K, and exchange interaction, the balance between these
interactions being driven by the strong intrachain spin correlations. More
generally, this study underlines the need, in this kind of molecular compounds,
to go beyond macroscopic magnetization measurements.Comment: 12 pages, 10 figures, submitted to Phys. Rev.
Characterization of Shewanella oneidensis MtrC: a cell-surface decaheme cytochrome involved in respiratory electron transport to extracellular electron acceptors
MtrC is a decaheme c-type cytochrome associated with the outer cell membrane of Fe(III)-respiring species of the Shewanella genus. It is proposed to play a role in anaerobic respiration by mediating electron transfer to extracellular mineral oxides that can serve as terminal electron acceptors. The present work presents the first spectropotentiometric and voltammetric characterization of MtrC, using protein purified from Shewanella oneidensis MR-1. Potentiometric titrations, monitored by UVâvis absorption and electron paramagnetic resonance (EPR) spectroscopy, reveal that the hemes within MtrC titrate over a broad potential range spanning between approximately +100 and approximately -500 mV (vs. the standard hydrogen electrode). Across this potential window the UVâvis absorption spectra are characteristic of low-spin c-type hemes and the EPR spectra reveal broad, complex features that suggest the presence of magnetically spin-coupled low-spin c-hemes. Non-catalytic protein film voltammetry of MtrC demonstrates reversible electrochemistry over a potential window similar to that disclosed spectroscopically. The voltammetry also allows definition of kinetic properties of MtrC in direct electron exchange with a solid electrode surface and during reduction of a model Fe(III) substrate. Taken together, the data provide quantitative information on the potential domain in which MtrC can operate
Two images of Nantes as a âGreen Modelâ of Urban Planning and Governance: The âCollaborative Cityâ Versus the âSlow Cityâ
This article examines how the city of Nantes, European Green Capital in 2013, came to promote plans for a new international airport at Notre-Dame-des-Landes. Deploying poststructuralist discourse theory, it analyses how the highly politicised struggle against the airport reveals the limits of the Nantes model of urban sustainability and collaboration, giving rise to a counter model, which we provisionally characterise as the âslow cityâ. While the struggle against the airport can be understood as a rural social movement, we show how its ideals and logics have been progressively displaced to Nantes itself, disclosing new images and possibilities of urban governance
Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
A series of heteropentanuclear oxalate-bridged Ru(NO)-Ln (4d-4f) metal complexes of the general formula (nBu(4)N)(5)[Ln{RuCl3(-ox)(NO)}(4)], where Ln=Y (2), Gd (3), Tb (4), Dy (5) and ox=oxalate anion, were obtained by treatment of (nBu(4)N)(2)[RuCl3(ox)(NO)] (1) with the respective lanthanide salt in 4:1 molar ratio. The compounds were characterized by elemental analysis, IR spectroscopy, electrospray ionization (ESI) mass spectrometry, while 1, 2, and 5 were in addition analyzed by X-ray crystallography, 1 by Ru K-edge XAS and 1 and 2 by (CNMR)-C-13 spectroscopy. X-ray diffraction showed that in 2 and 5 four complex anions [RuCl3(ox)(NO)](2-) are coordinated to Y-III and Dy-III, respectively, with formation of [Ln{RuCl3(-ox)(NO)}(4)](5-) (Ln=Y, Dy). While Y-III is eight-coordinate in 2, Dy-III is nine-coordinate in 5, with an additional coordination of an EtOH molecule. The negative charge is counterbalanced by five nBu(4)N(+) ions present in the crystal structure. The stability of complexes 2 and 5 in aqueous medium was monitored by UV/Vis spectroscopy. The antiproliferative activity of ruthenium-lanthanide complexes 2-5 were assayed in two human cancer cell lines (HeLa and A549) and in a noncancerous cell line (MRC-5) and compared with those obtained for the previously reported Os(NO)-Ln (5d-4f) analogues (nBu(4)N)(5)[Ln{OsCl3(ox)(NO)}(4)] (Ln=Y (6), Gd (7), Tb (8), Dy (9)). Complexes 2-5 were found to be slightly more active than 1 in inhibiting the proliferation of HeLa and A549 cells, and significantly more cytotoxic than 5d-4f metal complexes 6-9 in terms of IC50 values. The highest antiproliferative activity with IC50 values of 20.0 and 22.4M was found for 4 in HeLa and A549 cell lines, respectively. These cytotoxicity results are in accord with the presented ICP-MS data, indicating five- to eightfold greater accumulation of ruthenium versus osmium in human A549 cancer cells
Risultati preliminari delle indagini archeologiche ed etnografiche presso il sito di Togolok 1
Modern Turkmenistan is mainly constituted by a desert landscape, yet despite its harsh climate, cultures have been able to construct networks of water channels since the Bronze Age. This has resulted in a man-made landscape that integrates towns and villages. Extensive surveys and recent archaeological excavations have highlighted that between 2400 and 2100 BC (Namazga V period), the region of the Murghab alluvial fan was characterised by the development of complex urban societies. However, starting from the Late Bronze Age, a new group of mobile pastoralists appeared in the Murghab region and settled along the edges of the sedentary sites. Although their presence is well-attested both by survey and excavation data, their degree of interaction with the sedentary farmers is still debated. In modern Turkmenistan, semi-mobile shepherds continue to drive their cattle across the Murghab, using mobile camps for different months. This paper presents the preliminary results of the excavation of the sedentary site of Togolok 1, as well as the first ethnographic study of the mobile communities of the Murghab region
EURECâŽA
The science guiding the EURECâŽA campaign and its measurements is presented. EURECâŽA comprised roughly 5 weeks of measurements in the downstream winter trades of the North Atlantic â eastward and southeastward of Barbados. Through its ability to characterize processes operating across a wide range of scales, EURECâŽA marked a turning point in our ability to observationally study factors influencing clouds in the trades, how they will respond to warming, and their link to other components of the earth system, such as upper-ocean processes or the life cycle of particulate matter. This characterization was made possible by thousands (2500) of sondes distributed to measure circulations on meso- (200âkm) and larger (500âkm) scales, roughly 400âh of flight time by four heavily instrumented research aircraft; four global-class research vessels; an advanced ground-based cloud observatory; scores of autonomous observing platforms operating in the upper ocean (nearly 10â000 profiles), lower atmosphere (continuous profiling), and along the airâsea interface; a network of water stable isotopologue measurements; targeted tasking of satellite remote sensing; and modeling with a new generation of weather and climate models. In addition to providing an outline of the novel measurements and their composition into a unified and coordinated campaign, the six distinct scientific facets that EURECâŽA explored â from North Brazil Current rings to turbulence-induced clustering of cloud droplets and its influence on warm-rain formation â are presented along with an overview of EURECâŽA's outreach activities, environmental impact, and guidelines for scientific practice. Track data for all platforms are standardized and accessible at https://doi.org/10.25326/165 (Stevens, 2021), and a film documenting the campaign is provided as a video supplement
EURECâŽA
The science guiding the EURECâŽA campaign and its measurements is presented. EURECâŽA comprised roughly 5 weeks of measurements in the downstream winter trades of the North Atlantic â eastward and southeastward of Barbados. Through its ability to characterize processes operating across a wide range of scales, EURECâŽA marked a turning point in our ability to observationally study factors influencing clouds in the trades, how they will respond to warming, and their link to other components of the earth system, such as upper-ocean processes or the life cycle of particulate matter. This characterization was made possible by thousands (2500) of sondes distributed to measure circulations on meso- (200âkm) and larger (500âkm) scales, roughly 400âh of flight time by four heavily instrumented research aircraft; four global-class research vessels; an advanced ground-based cloud observatory; scores of autonomous observing platforms operating in the upper ocean (nearly 10â000 profiles), lower atmosphere (continuous profiling), and along the airâsea interface; a network of water stable isotopologue measurements; targeted tasking of satellite remote sensing; and modeling with a new generation of weather and climate models. In addition to providing an outline of the novel measurements and their composition into a unified and coordinated campaign, the six distinct scientific facets that EURECâŽA explored â from North Brazil Current rings to turbulence-induced clustering of cloud droplets and its influence on warm-rain formation â are presented along with an overview of EURECâŽA's outreach activities, environmental impact, and guidelines for scientific practice. Track data for all platforms are standardized and accessible at https://doi.org/10.25326/165 (Stevens, 2021), and a film documenting the campaign is provided as a video supplement
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