Supporting variables for biological effects measurements in fish and blue mussels

Biological effects measurements in fish and blue mussel are fundamental in marine environmental monitoring. Nevertheless, currently used biomarkers may be confounded by basic physiological phenomena, such as growth, reproduction, and feeding, as well as thereby associated physiological variation. Here, we present a number of supporting variables, which are essential to measure in order to obtain reliable biological effects data, facilitate their interpretation, and make valid comparisons. For fish, these variables include: body weight, body length, condition, gonad maturation status, various somatic indices, age, and growth. For blue mussels, these variables include: volume, flesh weight, shell weight, and condition. Also, grossly visible anomalies, lesions, and parasites should be recorded for both fish and blue mussels. General confounding factors and their effects are described, as well as recommendations for how to handle themPostprint

Experimental study of emergent ground state behavior in Gd1-xCexNi5 (x = 0; 0.2; 0.5; 0.8 and 1) melt-spun ribbons

The ground state physical properties of Gd1-xCexNi5 (x = 0; 0.2; 0.5; 0.8 and 1) melt-spun ribbons were investigated by X-ray diffraction, magnetization and specific heat measurements. The produced ribbon samples are single phases with the hexagonal CaCu5-type crystal structure. The magnetic transition temperature decreases with increasing Ce content. At a temperature around 100 K for the CeNi5 melt-spun ribbon, the spin fluctuations effect is visible.This research work was supported partially by VEGA 1/0404/21; VEGA 1/0705/20; VEGA 1/0053/19, and APVV-16-0079

Nivel de formación sobre sexualidad humana en estudiantes del primer ciclo en la Universidad Católica Santo Toribio de Mogrovejo, año 2010

La sexualidad humana es un concepto que abarca distintos ámbitos. Generalmente la sociedad tiende a relacionarlo con la parte reproductiva, sin embargo no solo atañe a lo sexual propiamente dicho, pues también comprende a la parte afectiva, de allí que se hable de una salud sexual y afectiva. El presente trabajo tiene como finalidad determinar el nivel de formación sobre sexualidad humana en estudiantes del primer ciclo en la Universidad Católica Santo Toribio de Mogrovejo, año 2010. Para la realización de la investigación se empleó un estudio descriptivo primario de tipo transversal, utilizándose el consentimiento informado para proceder a la encuesta elaborada por los autores en conjunto con un experto en el tema, siendo ésta revisada por dos sacerdotes y una psicóloga, y previamente empleada en prueba piloto. Ésta se aplicó en el muestreo obtenido estadísticamente de una población total de 1496 estudiantes 2010-I. Resultando los sujetos a investigar 424 estudiantes, considerados según estratos según facultad: ciencias empresariales, derecho, humanidades, ingeniería y medicina. Sin embargo la muestra de estudio se incrementó durante el proceso, haciendo un total de 439 estudiantes. Para el análisis de los datos se empleó tablas de frecuencias, diagramas de barras, diagrama de sectores y el programa Estadístico Excel. Se concluyó que de los 439 estudiantes del primer ciclo de USAT 2010-I entrevistados: el 19% presentó nivel alto de formación sobre sexualidad humana; el 62%, predominante, presentó un nivel medio, mientras que el restante, 18%, presentó nivel bajo

Kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexesss

The cyclometallation reactions of dinuclear μ-acetato complexes of the type [Pd(AcO)(μ-AcO)L]2 (L = 4-RC6H4CH2NH2, R = H, Cl, F, CF3), a process found to occur readily even in the solid state, have been studied from a kinetico-mechanistic perspective. Data indicate that the dinuclear acetato bridged derivatives are excellent starting materials to activate carbon-hydrogen bonds in a facile way. In all cases the established concerted ambiphilic proton abstraction by a coordinated acetato ligand has been proved. The metallation has also been found to occur in a cooperative manner, with the metallation of the first palladium unit of the dimeric complex being rate determining; no intermediate mono-metallated compounds are observed in any of the processes. The kinetically favoured bis-cyclopalladated compound obtained after complete C-H bond activation does not correspond to the final isolated XRD-characterized complexes. This species, bearing the classical open-book dimeric form, has a much more complex structure than the final isolated compound, with different types of acetato ligand

Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer

We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.We are thankful for support from MICINN (MAT2013-46753-C2-1-P, MAT2013-46502-C2-1/2-P and CTQ2011-26507), Eusko Jaurlaritza (S-PE13UN016) and Generalitat Valenciana PrometeoII/2014/076

Assessing environmental quality status by integrating chemical and biological effect data: The Cartagena coastal zone as a case

En prensa1,953

Using radio astronomical receivers for molecular spectroscopic characterization in astrochemical laboratory simulations: A proof of concept

We present a proof of concept on the coupling of radio astronomical receivers and spectrometers with chemical reactorsand the performances of the resulting setup for spectroscopy and chemical simulations in laboratory astrophysics. Several experiments including cold plasma generation and UV photochemistry were performed in a 40\,cm long gas cell placed in the beam path of the Aries 40\,m radio telescope receivers operating in the 41-49 GHz frequency range interfaced with fast Fourier transform spectrometers providing 2 GHz bandwidth and 38 kHz resolution. The impedance matching of the cell windows has been studied using different materials. The choice of the material and its thickness was critical to obtain a sensitivity identical to that of standard radio astronomical observations. Spectroscopic signals arising from very low partial pressures of CH3OH, CH3CH2OH, HCOOH, OCS,CS, SO2 (<1E-03 mbar) were detected in a few seconds. Fast data acquisition was achieved allowing for kinetic measurements in fragmentation experiments using electron impact or UV irradiation. Time evolution of chemical reactions involving OCS, O2 and CS2 was also observed demonstrating that reactive species, such as CS, can be maintained with high abundance in the gas phase during these experiments.Comment: Accepted for publication in Astronomy and Astrophysics in September 21, 2017. 16 pages, 18 figure

Evolution of Group Galaxies from the First Red-Sequence Cluster Survey

We study the evolution of the red galaxy fraction (f_red) in 905 galaxy groups with 0.15 < z < 0.52. The galaxy groups are identified by the `probability Friends-of-Friends' algorithm from the first Red-Sequence Cluster Survey (RCS1) photometric-redshift sample. There is a high degree of uniformity in the properties of the red-sequence of the group galaxies, indicating that the luminous red-sequence galaxies in the groups are already in place by z~0.5 and that they have a formation epoch of z>2. In general, groups at lower redshifts exhibit larger f_red than those at higher redshifts, showing a group Butcher-Oemler effect. We investigate the evolution of f_red by examining its dependence on four parameters, which can be classified as one intrinsic and three environmental: galaxy stellar mass (M_*), total group stellar mass(M_{*,grp}, a proxy for group halo mass), normalized group-centric radius (r_grp), and local galaxy density (Sigma_5). We find that M_* is the dominant parameter such that there is a strong correlation between f_red and galaxy stellar mass. Furthermore, the dependence of f_red on the environmental parameters is also a strong function of M_*. Massive galaxies (M_* > 10^11 M_sun) show little dependence of f_red on r_grp, M_{*,grp}, and Sigma_5 over the redshift range. The dependence of f_red on these parameters is primarily seen for galaxies with lower masses, especially for M_* < 10^{10.6} M_{sun}. We observe an apparent `group down-sizing' effect, in that galaxies in lower-mass halos, after controlling for galaxy stellar mass, have lower f_red. We find a dependence of \fred on both \rgrp and \SigmaF after the other parameters are controlled. At a fixed \rgrp, there is a significant dependence of f_red on Sigma_5, while r_grp gradients of f_red are seen for galaxies in similar Sigma_5 regions. This indicates .....Comment: ApJ accepte

The curse of the uncultured fungus

The international DNA sequence databases abound in fungal sequences not annotated beyond the kingdom level, typically bearing names such as “uncultured fungus”. These sequences beget low-resolution mycological results and invite further deposition of similarly poorly annotated entries. What do these sequences represent? This study uses a 767,918-sequence corpus of public full-length fungal ITS sequences to estimate what proportion of the 95,055 “uncultured fungus” sequences that represent truly unidentifiable fungal taxa – and what proportion of them that would have been straightforward to annotate to some more meaningful taxonomic level at the time of sequence deposition. Our results suggest that more than 70% of these sequences would have been trivial to identify to at least the order/family level at the time of sequence deposition, hinting that factors other than poor availability of relevant reference sequences explain the low-resolution names. We speculate that researchers’ perceived lack of time and lack of insight into the ramifications of this problem are the main explanations for the low-resolution names. We were surprised to find that more than a fifth of these sequences seem to have been deposited by mycologists rather than researchers unfamiliar with the consequences of poorly annotated fungal sequences in molecular repositories. The proportion of these needlessly poorly annotated sequences does not decline over time, suggesting that this problem must not be left unchecked