Study of the Brazil and Falkland currents using their images of Nimbus 5 and oceanographic data in 1972 - 1973

The Western Edge of the Sub-tropical Convergence of the South-western Atlantic Ocean, called the Front, which is a thermal discontinuity between the Brazil and Falkland Currents, was studied utilizing the Temperature Humidity Infrared Radiometer (THIR) of Nimbus V in the 10.5 to 12.5 micrometers channel and historical oceanographic data. Some important results obtained are: the oceanographic Front could be detected from Nimbus THIR data; oceanographic charts showed that the transition zone where the Brazil and the Falkland Currents meet was the Front detected from satellite data; ocean current speeds calculated with THIR data were of the same order of magnitude as those calculated oceanographically; fisheries statistics for Pargo Roseo showed that the maximum catches were in September of 1973, in the period when the Front was observed most distinctly and clearly. The results showed the great potentiality of satellite data to study surface thermal structures, surface currents and oceanic fisheries

Corrente do Brasil: estrutura térmica entre 19º e 25ºS e circulação geostrófica

In April 1982, an océanographie investigation was conducted off the Brazilian coast in order to obtain the spatial characteristics of the thermal structure and to locate the Brazil Current flow both north and south of the seamount chain at 20º30'S. Dining the survey, remote sensing satellite data were also obtained on several occasions to assist in the delineation of the surface thermal structure. A 23ºC thermostad was observed along most sections. Along sections with stronger baroclinic signatures, such as the one in Cabo Frio, the thermostad seems to be pinched off somewhat similar to the pinching off the 18ºC water in the Gulf Stream North wall. The current structure and volume transports, relative to the 500 dbar isobaric surface, were calculated using both hydrographie station data and the closely spaced XBT measurements. A comparison of these results, for the data observed along the section of Cabo Frio, indicates that some details of the geostrophic currents are lost when the hydrographie data are used; the corresponding volume transports agree within 17% (33 Sv using hydrographie data against 2.8 Sv using XBT data). A volume transport budget, obtained through the transport computation along all sections between 19º and 22ºS, indicates that the Brazil Current appears to flow through the passage between the most inshore banks and not to the east. The net volume transport (2.9 Sv) is in close agreement with the Cabo Frio section volume transport, where the total flow of the Brazil Current was supposedly bracketed by the station sampling.Para obter informações sobre a variação espacial da estrutura térmica e localizar a Corrente do Brasil, ao norte e ao sul dos bancos submarinos localizados a 20º30'S realizou-se, em abril de 1982, um levantamento oceanográfico nessa região. Dados de sensoriamento remoto foram também obtidos durante os trabalhos experimentais para um delineamento sinótico da estrutura térmica de superficie. Observou-se, ao longo da maioria das secções, um "thermostad" de 23ºC na termoclina principal. Ao longo das secções com intenso sinal baroclfnico, tal como na secção ao largo de Cabo Frio, o "thermostad" atenua-se e finalmente desaparece nas proximidades da costa, de forma semelhante ao desaparecimento da água de 18ºC na parede norte da Corrente do Golfo. A estrutura da corrente e o transporte de volume, relativos à superfície isobárica de 500 dbar, foram obtidos usando-se os dados hidrográficos e também as medidas com XBX as quais foram realizadas com espaçamentos muito menores do que o das estações hidrográficas. A comparação desses resultados, para o conjunto de observações conduzidas ao largo de Cabo Frio, indica que detalhes da corrente geostrófica não são delineados quando da utilização dos dados hidrográficos; os correspondentes valores do transporte de volume diferem em aproximadamente 17% (33 e 2,8 Sv, calculados com dados hidrográficos'e de XBX respectivamente). O balanço do transporte de volume, através de todas as secções entre 19 e 22º5, indica que a Corrente do Brasil flui através da passagem entre os bancos localizados mais próximos da costa. O transporte de volume resultante (2,9 Sv) é muito próximo do valor obtido através da secção ao largo de Cabo Frio, onde supõe-se que a extensão transversal da Corrente do Brasil foi delimitada pelo conjunto de observações

A Metabolomic Approach to the Study of Wine Micro-Oxygenation

Wine micro-oxygenation is a globally used treatment and its effects were studied here by analysing by untargeted LC-MS the wine metabolomic fingerprint. Eight different procedural variations, marked by the addition of oxygen (four levels) and iron (two levels) were applied to Sangiovese wine, before and after malolactic fermentation

Application of Approximate Pattern Matching in Two Dimensional Spaces to Grid Layout for Biochemical Network Maps

Background For visualizing large-scale biochemical network maps, it is important to calculate the coordinates of molecular nodes quickly and to enhance the understanding or traceability of them. The grid layout is effective in drawing compact, orderly, balanced network maps with node label spaces, but existing grid layout algorithms often require a high computational cost because they have to consider complicated positional constraints through the entire optimization process. Results We propose a hybrid grid layout algorithm that consists of a non-grid, fast layout (preprocessor) algorithm and an approximate pattern matching algorithm that distributes the resultant preprocessed nodes on square grid points. To demonstrate the feasibility of the hybrid layout algorithm, it is characterized in terms of the calculation time, numbers of edge-edge and node-edge crossings, relative edge lengths, and F-measures. The proposed algorithm achieves outstanding performances compared with other existing grid layouts. Conclusions Use of an approximate pattern matching algorithm quickly redistributes the laid-out nodes by fast, non-grid algorithms on the square grid points, while preserving the topological relationships among the nodes. The proposed algorithm is a novel use of the pattern matching, thereby providing a breakthrough for grid layout. This application program can be freely downloaded from http://www.cadlive.jp/hybridlayout/hybridlayout.html

Advances in structure elucidation of small molecules using mass spectrometry

The structural elucidation of small molecules using mass spectrometry plays an important role in modern life sciences and bioanalytical approaches. This review covers different soft and hard ionization techniques and figures of merit for modern mass spectrometers, such as mass resolving power, mass accuracy, isotopic abundance accuracy, accurate mass multiple-stage MS(n) capability, as well as hybrid mass spectrometric and orthogonal chromatographic approaches. The latter part discusses mass spectral data handling strategies, which includes background and noise subtraction, adduct formation and detection, charge state determination, accurate mass measurements, elemental composition determinations, and complex data-dependent setups with ion maps and ion trees. The importance of mass spectral library search algorithms for tandem mass spectra and multiple-stage MS(n) mass spectra as well as mass spectral tree libraries that combine multiple-stage mass spectra are outlined. The successive chapter discusses mass spectral fragmentation pathways, biotransformation reactions and drug metabolism studies, the mass spectral simulation and generation of in silico mass spectra, expert systems for mass spectral interpretation, and the use of computational chemistry to explain gas-phase phenomena. A single chapter discusses data handling for hyphenated approaches including mass spectral deconvolution for clean mass spectra, cheminformatics approaches and structure retention relationships, and retention index predictions for gas and liquid chromatography. The last section reviews the current state of electronic data sharing of mass spectra and discusses the importance of software development for the advancement of structure elucidation of small molecules

An update of the Worldwide Integrated Assessment (WIA) on systemic insecticides. Part 2: impacts on organisms and ecosystems

New information on the lethal and sublethal effects of neonicotinoids and fipronil on organisms is presented in this review, complementing the previous WIA in 2015. The high toxicity of these systemic insecticides to invertebrates has been confirmed and expanded to include more species and compounds. Most of the recent research has focused on bees and the sublethal and ecological impacts these insecticides have on pollinators. Toxic effects on other invertebrate taxa also covered predatory and parasitoid natural enemies and aquatic arthropods. Little, while not much new information has been gathered on soil organisms. The impact on marine coastal ecosystems is still largely uncharted. The chronic lethality of neonicotinoids to insects and crustaceans, and the strengthened evidence that these chemicals also impair the immune system and reproduction, highlights the dangers of this particular insecticidal classneonicotinoids and fipronil. , withContinued large scale – mostly prophylactic – use of these persistent organochlorine pesticides has the potential to greatly decreasecompletely eliminate populations of arthropods in both terrestrial and aquatic environments. Sublethal effects on fish, reptiles, frogs, birds and mammals are also reported, showing a better understanding of the mechanisms of toxicity of these insecticides in vertebrates, and their deleterious impacts on growth, reproduction and neurobehaviour of most of the species tested. This review concludes with a summary of impacts on the ecosystem services and functioning, particularly on pollination, soil biota and aquatic invertebrate communities, thus reinforcing the previous WIA conclusions (van der Sluijs et al. 2015)

Group‑wise ANOVA simultaneous component analysis for designed omics experiments

Modern omics experiments pertain not only to the measurement of many variables but also follow complex experimental designs where many factors are manipulated at the same time. This data can be conveniently analyzed using multivariate tools like ANOVA-simultaneous component analysis (ASCA) which allows interpretation of the variation induced by the different factors in a principal component analysis fashion. However, while in general only a subset of the measured variables may be related to the problem studied, all variables contribute to the final model and this may hamper interpretatio

Sleep’s Role in Schema Learning and Creative Insights

Purpose of Review A recent resurgence of interest in schema theory has influenced research on sleep-dependent memory consolidation and led to a new understanding of how schemata might be activated during sleep and play a role in the reorganisation of memories. This review aims to synthesise recent findings into a coherent narrative and draw overall conclusions. Recent Findings Rapid consolidation of schematic memories has been shown to benefit from an interval containing sleep. These memories have shown reduced reliance on the hippocampus following consolidation in both humans and rodents. Using a variety of methodologies, notably including the DRM paradigm, it has been shown that activation of a schema can increase the rate of false memory as a result of activation of semantic associates during slow wave sleep (SWS). Memories making use of a schema have shown increased activity in the medial prefrontal cortex, which may reflect both the schematic activation itself and a cognitive control component selecting an appropriate schema to use. SWS seems to be involved in assimilation of new memories within existing semantic frameworks and in making memories more explicit, while REM sleep may be more associated with creating entirely novel associations while keeping memories implicit. Summary Sleep plays an important role in schematic memory consolidation, with more rapid consolidation, reduced hippocampal involvement and increased prefrontal involvement as the key characteristics. Both SWS and REM sleep may have a role to play

Corrente do Brasil: estrutura térmica entre 19º e 25ºS e circulação geostrófica Brazil Current: thermal structure between 19º-25ºS and geostrophlc circulation

Para obter informações sobre a variação espacial da estrutura térmica e localizar a Corrente do Brasil, ao norte e ao sul dos bancos submarinos localizados a 20º30'S realizou-se, em abril de 1982, um levantamento oceanográfico nessa região. Dados de sensoriamento remoto foram também obtidos durante os trabalhos experimentais para um delineamento sinótico da estrutura térmica de superficie. Observou-se, ao longo da maioria das secções, um "thermostad" de 23ºC na termoclina principal. Ao longo das secções com intenso sinal baroclfnico, tal como na secção ao largo de Cabo Frio, o "thermostad" atenua-se e finalmente desaparece nas proximidades da costa, de forma semelhante ao desaparecimento da água de 18ºC na parede norte da Corrente do Golfo. A estrutura da corrente e o transporte de volume, relativos à superfície isobárica de 500 dbar, foram obtidos usando-se os dados hidrográficos e também as medidas com XBX as quais foram realizadas com espaçamentos muito menores do que o das estações hidrográficas. A comparação desses resultados, para o conjunto de observações conduzidas ao largo de Cabo Frio, indica que detalhes da corrente geostrófica não são delineados quando da utilização dos dados hidrográficos; os correspondentes valores do transporte de volume diferem em aproximadamente 17% (33 e 2,8 Sv, calculados com dados hidrográficos'e de XBX respectivamente). O balanço do transporte de volume, através de todas as secções entre 19 e 22º5, indica que a Corrente do Brasil flui através da passagem entre os bancos localizados mais próximos da costa. O transporte de volume resultante (2,9 Sv) é muito próximo do valor obtido através da secção ao largo de Cabo Frio, onde supõe-se que a extensão transversal da Corrente do Brasil foi delimitada pelo conjunto de observações.<br>In April 1982, an océanographie investigation was conducted off the Brazilian coast in order to obtain the spatial characteristics of the thermal structure and to locate the Brazil Current flow both north and south of the seamount chain at 20º30'S. Dining the survey, remote sensing satellite data were also obtained on several occasions to assist in the delineation of the surface thermal structure. A 23ºC thermostad was observed along most sections. Along sections with stronger baroclinic signatures, such as the one in Cabo Frio, the thermostad seems to be pinched off somewhat similar to the pinching off the 18ºC water in the Gulf Stream North wall. The current structure and volume transports, relative to the 500 dbar isobaric surface, were calculated using both hydrographie station data and the closely spaced XBT measurements. A comparison of these results, for the data observed along the section of Cabo Frio, indicates that some details of the geostrophic currents are lost when the hydrographie data are used; the corresponding volume transports agree within 17% (33 Sv using hydrographie data against 2.8 Sv using XBT data). A volume transport budget, obtained through the transport computation along all sections between 19º and 22ºS, indicates that the Brazil Current appears to flow through the passage between the most inshore banks and not to the east. The net volume transport (2.9 Sv) is in close agreement with the Cabo Frio section volume transport, where the total flow of the Brazil Current was supposedly bracketed by the station sampling