Joint meeting of CORE Organic Pilot Research Projects and CORE Organic Funding Body Network (8 June 2009 - Rome, Italy)

The ERA-NET CORE Organic, conducted in 2004-2007, launched 8 transnational pilot projects, funded by the participants’ funding bodies. These projects are running for the period 2007-2010 and reached their mid-term at the end of 2008. The meeting was an opportunity to present the projects and their preliminary results at mid-term, including new research needs and how research may benefit the organic sector, and to have a discussion between project coordinators, CORE Organic Funding Body Network and other participants on experiences with transnational research arising from such projects

In situ monitoring of corrosion processes by coupled micro-XRF/micro-XRD mapping to understand the degradation mechanisms of reinforcing bars in hydraulic binders from historic monuments

International audienceHistoric monuments have been partly built since antiquity with iron or steel reinforcements sealed in mortars or hydraulic binders. But the presence of chloride in the environment can weaken the structures due to the corrosion of these metallic parts, leading to the cracking of the binder. In this context, in order to better understand the first steps of these corrosion mechanisms a chemical cell was designed to operate in situ analyses of the phases precipitated when a chlorinated solution is introduced in the vicinity of the bar. The chemical and structural characterization (micro-XRF and micro-XRD respectively) was performed under synchrotron radiation at the SOLEIL-DiffAbs beamline. Moreover, complementary SEM-EDS analyses were carried out before and after the in situ cell experiment in order to determine the final localisation of the corrosion products inside the crack network. The results show that iron can spread up to 1 mm away from the metallic bar inside the pores of the binder after 44 h of corrosion. Moreover, in accordance with laboratory experiments conducted in solution in the presence of Fe2+ and Cl- ions the reaction pathways conduct to the successive formation of an intermediate Fe(ii)-Fe(iii) chlorinated green rust which transforms into ferric oxyhydroxides such as akaganeite or goethite depending on the local concentration of iron

Icebergs in the North Atlantic: Modelling circulation changes and glacio-marine deposition

In order to investigate meltwater events in the North Atlantic, a simple iceberg generation, drift, and melting routine was implemented in a high-resolution OGCM. Starting from the modelled last glacial state, every 25th day cylindrical model icebergs 300 meters high were released at 32 specific points along the coasts. Icebergs launched at the Barents Shelf margin spread a light meltwater lid over the Norwegian and Greenland Seas, shutting down the deep convection and the anti-clockwise circulation in this area. Due to the constraining ocean circulation, the icebergs produce a tongue of relatively cold and fresh water extending eastward from Hudson Strait that must develop at this location, regardless of iceberg origin. From the total amount of freshwater inferred by the icebergs, the thickness of the deposited IRD could be calculated in dependance of iceberg sediment concentration. In this way, typical extent and thickness of Heinrich layers could be reproduced, running the model for 250 years of steady state with constant iceberg meltwater inflow

Asian dust input in the western Philippine Sea: Evidence from radiogenic Sr and Nd isotopes

The radiogenic strontium (Sr) and neodymium (Nd) isotope compositions of the detrital fraction of surface and subsurface sediments have been determined to trace sediment provenance and contributions from Asian dust off the east coast of Luzon Islands in the western Philippine Sea. The Sr and Nd isotope compositions have been very homogenous near the east coast of the Luzon Islands during the latest Quaternary yielding relatively least radiogenic Sr (87Sr/86Sr = 0.70453 to 0.70491) and more radiogenic Nd isotope compositions (εNd(0) = +5.3 to +5.5). These isotope compositions are similar to Luzon rocks and show that these sediments were mainly derived from the Luzon Islands. In contrast, the Sr and Nd isotope compositions of sediments on the Benham Rise and in the Philippine Basin are markedly different in that they are characterized by overall more variable and more radiogenic Sr isotope compositions (87Sr/86Sr = 0.70452 to 0.70723) and less radiogenic Nd isotope compositions (εNd(0) = −5.3 to +2.4). The Sr isotope composition in the Huatung Basin is intermediate between those of the east coast of Luzon and Benham Rise, but shows the least radiogenic Nd isotope compositions. The data are consistent with a two end-member mixing relationship between Luzon volcanic rocks and eolian dust from the Asian continent, which is characterized by highly radiogenic Sr and unradiogenic Nd isotope compositions. The results show that Asian continental dust contributes about 10–50% of the detrital fraction of the sediments on Benham Rise in the western Philippine Sea, which offers the potentials to reconstruct the climatic evolution of eastern Asia from these sediments and compare this information to the records from the central and northern Pacific

Spatio-temporal evolution of the West African monsoon during the last deglaciation

On the basis of a multi-proxy data set from the Gulf of Guinea (eastern equatorial Atlantic) we reconstruct the spatio-temporal evolution of the West African monsoon (WAM) and present evidence for a decoupling between latitudinal shifts of the rain belt and WAM intensification. The onset of deglacial monsoon invigoration at ∼16,600 years before present lagged northward migration of a weak rainfall zone by ∼2800 years. Conversely, during the Younger Dryas (YD) time interval, WAM precipitation was severely reduced but we find no evidence for a large-scale retreat of the rainfall front. This observation is not in agreement with the hypothesis of a large-scale shift of the intertropical convergence zone south of the tropical WAM region during the YD. Our results can be better reconciled with the newly emerging concept of a strong influence of Tropical Easterly and African Easterly Jets on modern WAM

Position of the Polar Front along the western Iberian margin during key cold episodes of the last 45 ka

This paper documents the migration of the Polar Front (PF) over the Iberian margin during some of the cold climatic extremes of the last 45 ka. It is based on a compilation of robust and coherent paleohydrological proxies obtained from eleven cores distributed between 36 and 42°N. Planktonic δ18O (Globigerina bulloides), ice-rafted detritus concentrations, and the relative abundance of the polar foraminifera Neogloboquadrina pachyderma sinistral were used to track the PF position. These three data sets, compared from core to core, show a consistent evolution of the sea surface paleohydrology along the Iberian margin over the last 45 ka. We focused on five time slices representative of cold periods under distinct paleoenvironmental forcings: the 8.2 ka event and the Younger Dryas (two recent cold events occurring within high values of summer insolation), Heinrich events 1 and 4 (reflecting major episodes of massive iceberg discharges into the North Atlantic), and the Last Glacial Maximum (typifying the highest ice volume accumulated in the Northern Hemisphere). For each event, we generated schematic maps mirroring past sea surface hydrological conditions. The maps revealed that the Polar Front presence along the Iberian margin was restricted to Heinrich events. The sea surface conditions during the Last Glacial Maximum were close to those at present day, except for the northern sites which briefly experienced subarctic conditions

Surface water temperature, salinity, and density changes in the northeast Atlantic during the last 45,000 years: Heinrich events, deep water formation, and climatic rebounds

We developed a new method to calculate sea surface salinities (SSS) and densities (SSD) from planktonic foraminiferal delta(18)O and sea surface temperatures (SST) as determined from planktonic foraminiferal species abundances. SST, SSS, and SSD records were calculated for the last 45,000 years for Biogeochemical Oceanic Flux Study (BOFS) cores 5K and 8K recovered from the northeast Atlantic. The strongest feature is the dramatic drop in all three parameters during the Heinrich ''ice-rafting'' events. We modelled the possibility of deepwater formation in the northeast Atlantic from the SSD records, by assuming that the surface waters at our sites cooled as they flowed further north. Comparison with modelled North Atlantic deepwater densities indicates that there could have been periods of deepwater formation between 45,000 and 30,000 C-14 years B.P. (interrupted by iceberg meltwater input of Heinrich event 3 and 4, at 27,000 and 38,000 C-14 years B.P.) and during the Holocene. No amount of cooling in the northeast Atlantic between 30,000 and 13,000 years could cause deep water to form, because of the low salinities resulting from the high meltwater inputs from icebergs. Our records indicate that after each Heinrich event there were periods of climatic rebound, with milder conditions persisting for up to 2000 years, as indicated by the presence of warmer and more saline water masses. After these warm periods conditions returned to average glacial levels. These short term cold and warm episodes in the northeast Atlantic ate superimposed on the general trend towards colder conditions of the Last Glacial Maximum (LGM). Heinrich event 1 appears to be unique as it occurs as insolation rose and was coeval with the initial melting of the Fennoscandian ice sheet. We propose that meltwater input of Heinrich event 1 significantly reduced North Atlantic Deep Water formation reducing the heat exchange between the low and high latitudes, thus delaying deglaciation by about 1500 radiocarbon years (2000 calendar years)

Neodymium isotope constraints on provenance, dispersal, and climate-driven supply of Zambezi sediments along the Mozambique Margin during the past ∼45,000 years

Marine sediments deposited off the Zambezi River that drains a considerable part of the southeast African continent provide continuous records of the continental climatic and environmental conditions. Here we present time series of neodymium (Nd) isotope signatures of the detrital sediment fraction during the past ~45,000 years, to reconstruct climate-driven changes in the provenance of clays deposited along the Mozambique Margin. Coherent with the surface current regime, the Nd isotope distribution in surface sediments reveals mixing of the alongshore flowing Zambezi suspension load with sediments supplied by smaller rivers located further north. To reconstruct past changes in sediment provenances, Nd isotope signatures of clays that are not significantly fractionated during weathering processes have been obtained from core 64PE304-80, which was recovered just north of the Zambezi mouth at 1329 m water depth. Distinctly unradiogenic clay signatures (ENd values <214.2) are found during the Last Glacial Maximum, Heinrich Stadial 1, and Younger Dryas. In contrast, the Nd isotope record shows higher, more radiogenic isotope signatures during Marine Isotope Stage 3 and between ~15 and ~5 ka BP, the latter coinciding with the timing of the northern hemisphere African Humid Period. The clay-sized sediment fraction with the least radiogenic Nd isotope signatures was deposited during the Holocene, when the adjacent Mozambique Shelf became completely flooded. In general, the contribution of the distinctly unradiogenic Zambezi suspension load has followed the intensity of precession-forced monsoonal precipitation and enhanced during periods of increased southern hemisphere insolation and high-latitude northern hemispheric climate variability