EuO and Eu on metal crystals and graphene: interface effects and epitaxial films

Growth of the ferromagnetic semiconductor EuO was studied on the metal crystals Ni(100) and Ir(111) and on graphene. Primarily, characterisation was done by means of in-situ scanning tunnelling microscopy (STM) and low energy electron diffraction. The epitaxy on the metal crystals is strongly influenced by interface effects which lead to a complicated growth behaviour in the sub-monolayer regime, especially on Ni(100). Therefore, also films of sub-monolayer thickness were analysed in detail for these substrates. Eu oxide on Ni(100) shows a variety of different surface phases in the sub-monolayer regime, depending on the growth temperature and the ratio of the Eu and O fluxes. Hence, a careful selection of the initial growth parameters is decisive to obtain a surface oxide suitable for subsequent epitaxy of single phase EuO(100). After creation of a 3 layer thick coalesced oxide film, for subsequent growth a distillation technique can be applied. Ex-situ X-ray adsorption spectroscopy and magneto-optical Kerr effect microscopy measurements of thicker films on Ni(100) are consistent with stoichiometric single phase EuO with bulk properties. On Ir(111) initially only islands of polar EuO(111) grow, but formation of EuO(100) sets in before the first oxide layer is completed. The ratio of EuO(100) to EuO(111) is thereby influenced by the ratio of the Eu and O fluxes. Thus, the EuO films on Ir(111) consist of a phase mixture of EuO(111) and three rotational domains of EuO(100). The thinnest structure of the EuO(111) is a bilayer. Field emission resonances revealed a work function increase of 6 eV for this structure compared to EuO(100). Despite the polarity, the bilayer shows no obvious reconstruction which could reduce the high electric field. Triangular reconstruction motifs were found for the third EuO(111) layer. On graphene EuO can be grown as thin film of distinct, {100}-faceted grains which are oriented to the substrate at a sufficiently high growth temperature. As the EuO on graphene is not affected by interface effects, the initial growth stage is not crucial. Thus, the growth of these grains is far less sensitive to the ratio of Eu and O fluxes than the EuO growth on Ni(100). Appropriate annealing of EuO(100) films generates sufficient conductivity for STM and electron spectroscopies, even for films of 100 nm thickness. Oxygen vacancies were directly imaged by STM. They are of decisive importance for the metal-to-insulator transition of EuO around the temperature of the ferromagnetic-to-paramagnetic transition. Tunnelling spectra of EuO were recorded for the first time. For EuO(100) with 1% O vacancies in the topmost layer they exhibit states about 500 meV above the Fermi level which are most probably related to O vacancies. On all substrates, monolayer high EuO(100) films have a contracted lattice which expands with increasing film thickness. Even if the substrate applies compressive biaxial stress, the EuO bulk lattice constant is almost reached for 5 nm film thickness. This leaves little hope for an increase of the Curie temperature through epitaxial compression. During the investigation of the EuO on graphene, intercalation of Eu between the graphene and its Ir(111) substrate was observed and analysed further. For Eu deposition at 720 K a variety of equilibrium intercalate structures occur, dependent on the deposited Eu amount, all of which have a height of one monolayer. The dimensions and orientations of these structures are determined by binding energy differences within the unit cell of the graphene moiré on Ir(111). The energetically preferred lattice of the intercalated Eu is a p(2x2) structure, but intercalation continues until a denser (1.73x1.73)R30° structure is saturated. Angular resolved photoemission spectroscopy finds a shift of the graphene's Dirac cone by -1.5 eV for both of these structures. For closed graphene films, intercalation is hindered by a penetration barrier for temperatures below 400 K. The adsorption and equilibrium surface phases of Eu on graphene were investigated in the temperature range from 35 K to 400 K and for coverages ranging from a small fraction of a saturated monolayer to the second layer. Using density functional theory, including the 4f-shell Coulomb interactions and modelling of the electronic interactions, excellent agreement with the experimental results for the equilibrium adsorbate phase, adsorbate diffusion, and work function was obtained. Most remarkable, at 300 K in an intermediate coverage range a phase of uniformly distributed Eu clusters coexists in two dimensional equilibrium with large Eu-islands in a (1.73x1.73)R30° structure. The formation of the cluster phase is driven by the interplay of three effects: First, the metallic Eu-Eu binding leads to the local stability of (1.73x1.73)R30° structures. Second, electrons lower their kinetic energy by leaving the Eu clusters, thereby doping graphene. Third, the Coulomb energy penalty associated with the charge transfer from Eu to graphene is strongly reduced for smaller clusters

Europium Underneath Graphene on Ir(111): Intercalation Mechanism, Magnetism, and Band Structure

The intercalation of Eu underneath Gr on Ir(111) is comprehensively investigated by microscopic, magnetic, and spectroscopic measurements, as well as by density functional theory. Depending on the coverage, the intercalated Eu atoms form either a $(2 \times 2)$ or a $(\sqrt{3} \times \sqrt{3})$R$30^{\circ}$ superstructure with respect to Gr. We investigate the mechanisms of Eu penetration through a nominally closed Gr sheet and measure the electronic structures and magnetic properties of the two intercalation systems. Their electronic structures are rather similar. Compared to Gr on Ir(111), the Gr bands in both systems are essentially rigidly shifted to larger binding energies resulting in n-doping. The hybridization of the Ir surface state $S_1$ with Gr states is lifted, and the moire superperiodic potential is strongly reduced. In contrast, the magnetic behavior of the two intercalation systems differs substantially as found by X-ray magnetic circular dichroism. The $(2 \times 2)$ Eu structure displays plain paramagnetic behavior, whereas for the $(\sqrt{3} \times \sqrt{3})$R$30^{\circ}$ structure the large zero-field susceptibility indicates ferromagnetic coupling, despite the absence of hysteresis at 10 K. For the latter structure, a considerable easy-plane magnetic anisotropy is observed and interpreted as shape anisotropy.Comment: 18 pages with 14 figures, including Supplemental Materia

Is keV ion induced pattern formation on Si(001) caused by metal impurities?

We present ion beam erosion experiments performed in ultra high vacuum using a differentially pumped ion source and taking care that the ion beam hits the Si(001) sample only. Under these conditions no ion beam patterns form on Si for angles below 45 degrees with respect to the global surface normal using 2 keV Kr ions and fluences of 2 x 10^22 ions/m^2. In fact, the ion beam induces a smoothening of preformed patterns. Simultaneous sputter deposition of stainless steel in this angular range creates a variety of patterns, similar to those previously ascribed to clean ion beam induced destabilization of the surface profile. Only for grazing incidence with incident angles between 60 degrees and 83 degrees pronounced ion beam patterns form. It appears that the angular dependent stability of Si(001) against pattern formation under clean ion beam erosion conditions is related to the angular dependence of the sputtering yield, and not primarily to a curvature dependent yield as invoked frequently in continuum theory models.Comment: 15 pages, 7 figures. This is an author-created, un-copyedited version of an article published in Nanotechnology. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from i

The Majority of Compact Massive Galaxies at z~2 are Disk Dominated

We investigate the stellar structure of massive, quiescent galaxies at z~2, based on Hubble Space Telescope/WFC3 imaging from the Early Release Science program. Our sample of 14 galaxies has stellar masses of M* > 10^{10.8} Msol and photometric redshifts of 1.5 < z < 2.5. In agreement with previous work, their half-light radii are <2 kpc, much smaller than equally massive galaxies in the present-day universe. A significant subset of the sample appears highly flattened in projection, which implies, considering viewing angle statistics, that a significant fraction of the galaxies in our sample have pronounced disks. This is corroborated by two-dimensional surface brightness profile fits. We estimate that 65% +/- 15% of the population of massive, quiescent z~2 galaxies are disk-dominated. The median disk scale length is 1.5 kpc, substantially smaller than the disks of equally massive galaxies in the present-day universe. Our results provide strong observational evidence that the much-discussed ultra-dense high-redshift galaxies should generally be thought of as disk-like stellar systems with the majority of stars formed from gas that had time to settle into a disk.Comment: published versio

Priming by Chemokines Restricts Lateral Mobility of the Adhesion Receptor LFA-1 and Restores Adhesion to ICAM-1 Nano-Aggregates on Human Mature Dendritic Cells

LFA-1 is a leukocyte specific β2 integrin that plays a major role in regulating adhesion and migration of different immune cells. Recent data suggest that LFA-1 on mature dendritic cells (mDCs) may function as a chemokine-inducible anchor during homing of DCs through the afferent lymphatics into the lymph nodes, by transiently switching its molecular conformational state. However, the role of LFA-1 mobility in this process is not yet known, despite that the importance of lateral organization and dynamics for LFA-1-mediated adhesion regulation is broadly recognized. Using single particle tracking approaches we here show that LFA-1 exhibits higher mobility on resting mDCs compared to monocytes. Lymphoid chemokine CCL21 stimulation of the LFA-1 high affinity state on mDCs, led to a significant reduction of mobility and an increase on the fraction of stationary receptors, consistent with re-activation of the receptor. Addition of soluble monomeric ICAM-1 in the presence of CCL21 did not alter the diffusion profile of LFA-1 while soluble ICAM-1 nano-aggregates in the presence of CCL21 further reduced LFA-1 mobility and readily bound to the receptor. Overall, our results emphasize the importance of LFA-1 lateral mobility across the membrane on the regulation of integrin activation and its function as adhesion receptor. Importantly, our data show that chemokines alone are not sufficient to trigger the high affinity state of the integrin based on the strict definition that affinity refers to the adhesion capacity of a single receptor to its ligand in solution. Instead our data indicate that nanoclustering of the receptor, induced by multi-ligand binding, is required to maintain stable cell adhesion once LFA-1 high affinity state is transiently triggered by inside-out signals.Peer ReviewedPostprint (published version

Galaxy Zoo: CANDELS barred discs and bar fractions

The formation of bars in disc galaxies is a tracer of the dynamical maturity of the population. Previous studies have found that the incidence of bars in discs decreases from the local Universe to z ~ 1, and by z > 1 simulations predict that bar features in dynamically mature discs should be extremely rare. Here, we report the discovery of strong barred structures in massive disc galaxies at z ~ 1.5 in deep rest-frame optical images from the Cosmic Assembly Near-Infrared Deep Extragalactic Legacy Survey. From within a sample of 876 disc galaxies identified by visual classification in Galaxy Zoo, we identify 123 barred galaxies. Selecting a subsample within the same region of the evolving galaxy luminosity function (brighter than L*), we find that the bar fraction across the redshift range 0.5 ≤ z ≤ 2 (fbar = 10.7+6.3 -3.5 per cent after correcting for incompleteness) does not significantly evolve.We discuss the implications of this discovery in the context of existing simulations and our current understanding of the way disc galaxies have evolved over the last 11 billion yearsPeer reviewedFinal Accepted Versio

Exciton bimolecular annihilation dynamics in supramolecular nanostructures of conjugated oligomers

We present femtosecond transient absorption measurements on $\pi$-conjugated supramolecular assemblies in a high pump fluence regime. Oligo(\emph{p}-phenylenevinylene) monofunctionalized with ureido-\emph{s}-triazine (MOPV) self-assembles into chiral stacks in dodecane solution below 75$^{\circ}$C at a concentration of $4\times 10^{-4}$ M. We observe exciton bimolecular annihilation in MOPV stacks at high excitation fluence, indicated by the fluence-dependent decay of $1^1$B$_{u}$-exciton spectral signatures, and by the sub-linear fluence dependence of time- and wavelength-integrated photoluminescence (PL) intensity. These two characteristics are much less pronounced in MOPV solution where the phase equilibrium is shifted significantly away from supramolecular assembly, slightly below the transition temperature. A mesoscopic rate-equation model is applied to extract the bimolecular annihilation rate constant from the excitation fluence dependence of transient absorption and PL signals. The results demonstrate that the bimolecular annihilation rate is very high with a square-root dependence in time. The exciton annihilation results from a combination of fast exciton diffusion and resonance energy transfer. The supramolecular nanostructures studied here have electronic properties that are intermediate between molecular aggregates and polymeric semiconductors

CANDELS: The progenitors of compact quiescent galaxies at z~2

We combine high-resolution HST/WFC3 images with multi-wavelength photometry to track the evolution of structure and activity of massive (log(M*) > 10) galaxies at redshifts z = 1.4 - 3 in two fields of the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey (CANDELS). We detect compact, star-forming galaxies (cSFGs) whose number densities, masses, sizes, and star formation rates qualify them as likely progenitors of compact, quiescent, massive galaxies (cQGs) at z = 1.5 - 3. At z > 2 most cSFGs have specific star-formation rates (sSFR = 10^-9 yr^-1) half that of typical, massive SFGs at the same epoch, and host X-ray luminous AGN 30 times (~30%) more frequently. These properties suggest that cSFGs are formed by gas-rich processes (mergers or disk-instabilities) that induce a compact starburst and feed an AGN, which, in turn, quench the star formation on dynamical timescales (few 10^8 yr). The cSFGs are continuously being formed at z = 2 - 3 and fade to cQGs by z = 1.5. After this epoch, cSFGs are rare, thereby truncating the formation of new cQGs. Meanwhile, down to z = 1, existing cQGs continue to enlarge to match local QGs in size, while less-gas-rich mergers and other secular mechanisms shepherd (larger) SFGs as later arrivals to the red sequence. In summary, we propose two evolutionary scenarios of QG formation: an early (z > 2), fast-formation path of rapidly-quenched cSFGs that evolve into cQGs that later enlarge within the quiescent phase, and a slow, late-arrival (z < 2) path for SFGs to form QGs without passing through a compact state.Comment: Submitted to the Astrophysical Journal Letters, 6 pages, 4 figure

Phylogeography of red muntjacs reveals three distinct mitochondrial lineages

Background: The members of the genus Muntiacus are of particular interest to evolutionary biologists due to their extreme chromosomal rearrangements and the ongoing discussions about the number of living species. Red muntjacs have the largest distribution of all muntjacs and were formerly considered as one species. Karyotype differences led to the provisional split between the Southern Red Muntjac (Muntiacus muntjak) and the Northern Red Muntjac (M. vaginalis), but uncertainties remain as, so far, no phylogenetic study has been conducted. Here, we analysed whole mitochondrial genomes of 59 archival and 16 contemporaneous samples to resolve uncertainties about their taxonomy and used red muntjacs as model for understanding the evolutionary history of other species in Southeast Asia. Results: We found three distinct matrilineal groups of red muntjacs: Sri Lankan red muntjacs (including the Western Ghats) diverged first from other muntjacs about 1.5 Mya; later northern red muntjacs (including North India and Indochina) and southern red muntjacs (Sundaland) split around 1.12 Mya. The diversification of red muntjacs into these three main lineages was likely promoted by two Pleistocene barriers: one through the Indian subcontinent and one separating the Indochinese and Sundaic red muntjacs. Interestingly, we found a high level of gene flow within the populations of northern and southern red muntjacs, indicating gene flow between populations in Indochina and dispersal of red muntjacs over the exposed Sunda Shelf during the Last Glacial Maximum. Conclusions: Our results provide new insights into the evolution of species in South and Southeast Asia as we found clear genetic differentiation in a widespread and generalist species, corresponding to two known biogeographical barriers: The Isthmus of Kra and the central Indian dry zone. In addition, our molecular data support either the delineation of three monotypic species or three subspecies, but more importantly these data highlight the conservation importance of the Sri Lankan/South Indian red muntjac