Hydrothermal formation of heavy rare earth element (HREE)– xenotime deposits at 100 °C in a sedimentary basin

Most rare earth element deposits form from magmatic fluids, but there have also been discoveries of heavy rare earth element (HREE)– enriched hydrothermal xenotime deposits within sedimentary basins. As xenotime is notoriously insoluble, the question arises as to whether these lesser-known deposits form at typical basin temperatures or by influx of much hotter magmatic-hydrothermal fluids. The Browns Range District in northern Western Australia hosts deposits of xenotime that are enriched in HREEs and also uranium. The ore bodies consist of fault-controlled hydrothermal quartz-xenotime breccias that crosscut Archean basement rocks and overlying Paleoproterozoic sandstones. Analyses of fluid inclusions show that the xenotime precipitated at remarkably low temperatures, between 100 and 120 °C, in response to decompression boiling. The inclusions contain high excess concentrations of yttrium (10−3 mol/kg), REEs (1–7 × 10−5 mol/kg), and uranium (4 × 10−5 mol/kg) in equilibrium with xenotime at these low temperatures, showing that availability of phosphate limited the amount of xenotime precipitated. The analyses further identify SO4 2– and Cl– as the ligands that facilitated the elevated REE and uranium solubilities. These findings establish that significant REE transport and deposition is feasible at basin temperatures, and hence they raise the potential of unconformity settings for REE exploration. Moreover, the aqueous metal contents support a genetic link between this type of ore fluid and world-class Proterozoic unconformity-related uranium deposits elsewhere

Fixed points and vacuum energy of dynamically broken gauge theories

We show that if a gauge theory with dynamical symmetry breaking has non-trivial fixed points, they will correspond to extrema of the vacuum energy. This relationship provides a different method to determine fixed points.Comment: 17 pages, uuencoded latex file, 3 figures, uses epsf and epsfig. Submitted to Mod. Phys. Lett.

Posterior Contraction Rates for the Bayesian Approach to Linear Ill-Posed Inverse Problems

We consider a Bayesian nonparametric approach to a family of linear inverse problems in a separable Hilbert space setting with Gaussian noise. We assume Gaussian priors, which are conjugate to the model, and present a method of identifying the posterior using its precision operator. Working with the unbounded precision operator enables us to use partial differential equations (PDE) methodology to obtain rates of contraction of the posterior distribution to a Dirac measure centered on the true solution. Our methods assume a relatively weak relation between the prior covariance, noise covariance and forward operator, allowing for a wide range of applications

BS196: an old star cluster far from the SMC main body

We present B and V photometry of the outlying SMC star cluster BS196 with the 4.1-m SOAR telescope. The photometry is deep (to V~25) showing ~3 mag below the cluster turnoff point (TO) at Mv=2.5 (1.03 Msun). The cluster is located at the SMC distance. The CMD and isochrone fittings provide a cluster age of 5.0+-0.5 Gyr, indicating that this is one of the 12 oldest clusters so far detected in the SMC. The estimated metallicity is [Fe/H]=-1.68+-0.10. The structural analysis gives by means of King profile fittings a core radius Rc=8.7+-1.1 arcsec (2.66+-0.14 pc) and a tidal radius Rt=69.4+-1.7 arcsec (21.2+-1.2 pc). BS196 is rather loose with a concentration parameter c=0.90. With Mv=-1.89+-0.39, BS196 belongs to the class of intrinsically fainter SMC clusters, as compared to the well-known populous ones, which starts to be explored.Comment: 8 pages, 10 figures; accepted by MNRA

Exceptional Concentrations of Gold Nanoparticles in 1,7 Ga Fluid Inclusions From the Kola Superdeep Borehole, Northwest Russia

In the drill core of the Kola super-deep borehole (SG-3, 12,262 m depth) gold-bearing rocks of Archaean age have been located at depths of 9,500 to 11,000 m. In veins, between 9,052 and 10,744 m, within this gold zone, quartz contains fluid inclusions with gold nanoparticles. There are 4 types of fluid inclusions (1) gas inclusions of dense CO2, (2) liquid-vapor two-phase aqueous inclusions, (3) three-phase inclusions with NaCl daughter crystals, and (4) CO2-aqueous inclusions. In all inclusion types, there are extremely high concentrations of gold. The highest gold concentrations were found in the type 3 and 4 fluid inclusions with an average concentration of c. 750 ppm and may be as high as 6,000 ppm. The presence of gold as nanoparticles in the solutions of these fluid inclusions was determined by optical and spectroscopic methods. We suggest that these fluids could be a precursor of “orogenic gold fluids” which, at the gold concentrations determined, would reduce the requirements for large volumes of metamorphic fluids to form orogenic ore deposits. Further, as nanoparticles, gold could be transported in larger amounts than in true solution

Lithium isotopes in fluid inclusions as tracers of crustal fluids: An exploratory study

Lithium isotopes are extensively used to trace fluid migration and fluid-rock interactions in the shallow Earth's crust. Although, Li isotope systematics might give important information about deep crustal fluids, this stable isotope system remains surprisingly under exploited in fluid inclusions. Here, twenty-three samples from a variety of deep environments, from diagenetic, metamorphic to magmatic-hydrothermal conditions (~150 to 600°C), have been investigated in order to provide the first exploratory overview of the range in Li isotopic composition of fluid inclusions. From 1 to 2g of hydrothermal quartz or dolomite, cation analysis (Na, K, Ca, Mg, Sr, Li), Li fraction recovery and Li isotopic analysis of bulk fluid inclusion leachates were carried out by using an innovative approach coupling crush-leach extraction, high performance ion chromatography and MC-ICPMS analysis. Reconstructed Li concentrations and δ7Li values of these fluid inclusions (respectively 12 to 653mg/l and −1.4±0.2‰ to +41.3±0.8‰) are compatible with previously proposed models for the origin of the fluids and fluid-rock interactions. δ7Li values are independent from other tracers (Br/Cl, I/Cl) and parameters such as temperature, salinity, and cation content (Na/Ca, Na/K, Na/Mg, Na/Li, Na/Sr ratios). The results show that, in conjunction with other parameters, the Li isotopic compositions of fluid inclusions are potentially powerful source and process tracers of deep crustal fluids within a wide range of geological environments and related ore-forming systems, for example in from sedimentary basins, seafloor hydrothermal systems and subduction zones

Monitoring fluid migration using in-situ nuclear magnetic resonance core flooding system integrated with fiber optic sensors: A proof of concept

In-situ nuclear magnetic resonance (NMR) core flooding system has enabled researchers to monitor several rock properties such as porosity, pore size distribution, and fluid saturation along the tested samples with high resolutions and under reservoir conditions. However, spatially resolved rock strength/mechanical property alteration coupled to fluid migration/substitution remains poorly characterized. To this end, Fiber Bragg Grating (FBG) multiplex sensors were integrated with NMR core flooding system to monitor rock strength changes, or generally speaking, to observe hydro-mechanical-chemical coupling mechanisms during core flooding tests. In this study, we present a novel approach on how to conduct core flooding experiments, while simultaneously monitoring NMR and FBG strain response of the tested limestone plug. The NMR cell was modified to integrate FBG technology without impeding the NMR signal and core flooding high pressure/temperature capacity. A high spatial resolution optical fiber was attached onto the sample radial surface. The results show the successful association of NMR and FBG sensors to track any change at each stage of brine injection. The FBG is capable of measuring the rock strain variations induced by rock-fluid interactions during brine injection, allowing it to capture the fluid front location along with the sample and at a faster rate than the NMR

Sulfur-bearing monazite-(Ce) from the Eureka carbonatite, Namibia: oxidation state, substitution mechanism, and formation conditions

Sulfur-bearing monazite-(Ce) occurs in silicified carbonatite at Eureka, Namibia, forming rims up to ~0.5 mm thick on earlier-formed monazite-(Ce) megacrysts. We present X-ray photoelectron spectroscopy data demonstrating that sulfur is accommodated predominantly in monazite-(Ce) as sulfate, via a clino-anhydrite-type coupled substitution mechanism. Minor sulfide and sulfite peaks in the X-ray photoelectron spectra, however, also indicate that more complex substitution mechanisms incorporating S2– and S4+ are possible. Incorporation of S6+ through clino-anhydrite-type substitution results in an excess of M2+ cations, which previous workers have suggested is accommodated by auxiliary substitution of OH– for O2–. However, Raman data show no indication of OH–, and instead we suggest charge imbalance is accommodated through F– substituting for O2–. The accommodation of S in the monazite-(Ce) results in considerable structural distortion that may account for relatively high contents of ions with radii beyond those normally found in monazite-(Ce), such as the heavy rare earth elements, Mo, Zr and V. In contrast to S-bearing monazite-(Ce) in other carbonatites, S-bearing monazite-(Ce) at Eureka formed via a dissolution–precipitation mechanism during prolonged weathering, with S derived from an aeolian source. While large S-bearing monazite-(Ce) grains are likely to be rare in the geological record, formation of secondary S-bearing monazite-(Ce) in these conditions may be a feasible mineral for dating palaeo-weathering horizons

Radius Stabilization by Two-Loop Casimir Energy

It is well known that the Casimir energy of bulk fields induces a non-trivial potential for the compactification radius of higher-dimensional field theories. On dimensional grounds, the 1-loop potential is ~ 1/R^4. Since the 5d gauge coupling constant g^2 has the dimension of length, the two-loop correction is ~ g^2/R^5. The interplay of these two terms leads, under very general circumstances (including other interacting theories and more compact dimensions), to a stabilization at finite radius. Perturbative control or, equivalently, a parametrically large compact radius is ensured if the 1-loop coefficient is small because of an approximate fermion-boson cancellation. This is similar to the perturbativity argument underlying the Banks-Zaks fixed point proposal. Our analysis includes a scalar toy model, 5d Yang-Mills theory with charged matter, the examination of S^1 and S^1/Z_2 geometries, as well as a brief discussion of the supersymmetric case with Scherk-Schwarz SUSY breaking. 2-Loop calculability in the S^1/Z_2 case relies on the log-enhancement of boundary kinetic terms at the 1-loop level.Comment: 18 pages, 2 figures, uses axodraw, references adde

Impact of aperture separation on wind-driven single-sided natural ventilation

This paper presents a study of the impact of horizontal aperture separation in single-sided ventilation flows with two apertures (SS2). The study is based on wind tunnel measurements and dimensional analysis. The results show that the SS2 ventilation flow rate, scaled with incoming wind velocity and aperture area, depends on the incoming wind angle relative to the aperture façade, $θ$, and on the aperture separation scaled by building width, $s$′. For most wind angles, the ventilation flow increases as the square-root of $s$′. This study also identified a novel flow driving mechanism – vortex shedding: when the ventilation openings are on the leeward side of the building and the wind is nearly head-on, the flow is driven by a pumping mechanism due to vortex shedding.The authors gratefully acknowledge the contribution of staff at CPP Wind Engineering, Inc., for running the wind tunnel tests that produced the data used to develop our model; and financial support for one of us (GCG) from Instituto Dom Luiz (UID/GEO/50019/ 2013). The work described in this paper was carried out under California Energy Commission contract 500-10-025, and their financial support is gratefully acknowledged