Hydrotreating of Guaiacol and Acetic Acid Blends over Ni2P/ZSM-5 Catalysts: Elucidating Molecular Interactions during Bio-Oil Upgrading

[EN] Catalytic hydrodeoxygenation (HDO) is an effective technology for upgrading pyrolysis bio-oils. Although, in the past years, this process has been extensively studied, the relevance of the cross-reactivity between the numerous chemical components of bio-oil has been scarcely explored. However, molecular coupling can be beneficial for improving the bio-oil characteristics. With the aim of gaining a better understanding of these interactions, this work investigates the catalytic hydrodeoxygenation of mixtures of two typical components of pyrolysis bio-oils: guaiacol and acetic acid. The catalytic tests were carried out employing a bifunctional catalyst based on nickel phosphide (Ni2P) deposited over a commercial nanocrystalline ZSM-5 zeolite. The influence of both hydrogen availability and temperature on the activity and product distribution, was evaluated by carrying out reactions under different H2 pressures (40¿10 bar) and temperatures (between 260 and 300 °C). Using blends of both substrates, a partial inhibition of guaiacol HDO occurred because of the competence of acetic acid for the catalytic active sites. Nevertheless, positive interactions were also observed, mainly esterification and acylation reactions, which could enhance the bio-oil stability by reducing acidity, lowering the oxygen content, and increasing the chain length of the components. In this respect, formation of acetophenones, which can be further hydrogenated to yield ethyl phenols, is of particular interest for biorefinery applications. Increasing the temperature results in an increment of conversion but a decrease in the yield of fully deoxygenated molecules due to the production of higher proportion of catechol and related products. Additional experiments performed in the absence of hydrogen revealed that esterification reactions are homogeneously self-catalyzed by acetic acid, while acylation processes are mainly catalyzed by the acidic sites of the zeolitic support.The authors thank to the Spanish “Ministry of Economy and Competiveness” for their financial support through the project CATPLASBIO (CTQ2014-60209-R), as well as to the “Regional Government of Madrid” and European Structural Funds for the RESTOENE2 (S2013/MAE-2882) project

Tunable crossover between one- and three-dimensional magnetic dynamics in CoII single-chain magnets organized by halogen bonding

Low-temperature magnetometry, ac susceptibility, and calorimetry have been employed to study Co-based single-chain magnets (SCMs) organized through halogen bonding. Magnetic hysteresis and maxima in the dc and ac susceptibilities, respectively, confirm the SCM behavior of the system. Several characteristic magnetic relaxation regimes are observed at different temperatures, which can be associated with both intra- and interchain exchange interactions. Remarkably, tweaking the rate at which an external magnetic field is swept along the axis of the chains enables a controlled transition between the one- and three-dimensional dynamics. Experiments on an isostructural Co-based SCM system crystallized with different halogens do not show three-dimensional dynamics, illustrating the importance of halogen bonding on the control of interchain interactions.A.A. and E.d.B. acknowledge support from the National Science Foundation (DMR No. 1503627). G.M.E., J.M.C.- J., and E.C. acknowledge the Spanish MINECO (Excellence Unit Maria de Maeztu MDM-2015-0538 and Projects No. MAT2014-56143-R, No. CTQ2014-29509-P, and No. CTQ2014-52758-P, and the excellence network NANOMOLNet on molecular nanoscience, Project No. MAT2014-52919-REDC), the EU (COST Action MOLSPIN), and the Generalidad Valenciana (Prometeo Program). F.L. and M.E. acknowledge funding from the MINECO-FEDER through Grant No. MAT2015-68204-R and from Gobierno de Aragon, Grant No. E98-MOLCHIP.Peer Reviewe

Tunable crossover between one- and three-dimensional magnetic dynamics in C oII single-chain magnets organized by halogen bonding

Low-temperature magnetometry, ac susceptibility, and calorimetry have been employed to study Co-based single-chain magnets (SCMs) organized through halogen bonding. Magnetic hysteresis and maxima in the dc and ac susceptibilities, respectively, confirm the SCM behavior of the system. Several characteristic magnetic relaxation regimes are observed at different temperatures, which can be associated with both intra- and interchain exchange interactions. Remarkably, tweaking the rate at which an external magnetic field is swept along the axis of the chains enables a controlled transition between the one- and three-dimensional dynamics. Experiments on an isostructural Co-based SCM system crystallized with different halogens do not show three-dimensional dynamics, illustrating the importance of halogen bonding on the control of interchain interactions

Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]−3

The theory of the kinetic exchange in a pair of orbitally degenerate ions developed by the authors [J. Phys. Chem. A 102, 200 (1998)] is applied to the case of face-shared bioctahedral dimer (overall D3h-symmetry). The effective kinetic exchange Hamiltonian is found for a 2T2–2T2 system taking into account all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals involved in the kinetic exchange on the energy pattern and magnetic properties of the system is examined. The role of other related interactions (trigonal crystal field, spin–orbit coupling) is also discussed in detail. Using the pseudoangular momentum representation and the technique of the irreducible tensor operators of R3-group we give a general outlook on the nontrivial symmetry properties of the effective Hamiltonian for the D3h-pair, and on the magnetic anisotropy arising from the orbital interactions specific for the case of orbital degeneracy. The magnetic properties of the binuclear unit [Ti2Cl9]−3 in Cs3Ti2Cl9 are discussed with a special emphasis on the magnetic anisotropy experimentally observed in this system. The existing exchange models for [Ti2Cl9]−3 and the concept of the effective Hamiltonian are discussed in the context of the present [email protected] ; [email protected] ; [email protected] ; [email protected]

Inverted Solution Processable OLEDs Using a Metal Oxide as an Electron Injection Contact

A new type of bottom-emission electroluminescent device is described in which a metal oxide is used as the electron-injecting contact. The preparation of such a device is simple. It consists of the deposition of a thin layer of a metal oxide on top of an indium tin oxide covered glass substrate, followed by the solution processing of the light-emitting layer and subsequently the deposition of a high-workfunction (air-stable) metal anode. This architecture allows for a low-cost electroluminescent device because no rigorous encapsulation is required. Electroluminescence with a high brightness reaching 5700 cd m–2 is observed at voltages as low as 8 V, demonstrating the potential of this new approach to organic light-emitting diode (OLED) devices. Unfortunately the device efficiency is rather low because of the high current density flowing through the device. We show that the device only operates after the insertion of an additional hole-injection layer in between the light-emitting polymer (LEP) and the metal anode. A simple model that explains the experimental results and provides avenues for further optimization of these devices is described. It is based on the idea that the barrier for electron injection is lowered by the formation of a space–charge field over the metal-oxide–LEP interface due to the build up of holes in the LEP layer close to this interfac

18 años de gobiernos panistas en Jalisco: siete ensayos académicos

Tras seis décadas de que el Partido Revolucionario Institucional (PRI) gobernó a México como partido hegemónico, la democratización en el país ha sido objeto de estudio en distintos niveles. Este proceso comenzó en los gobiernos locales, pero aún es reducido el número de investigaciones que documentan la evolución en este plano. Esta obra aborda el caso de Jalisco, uno de los primeros estados en donde el PRI cedió el poder. Aconteció en 1995, cuando perdió la gubernatura frente al Partido Acción Nacional (PAN), que la retuvo por 18 años, para luego cederla de nuevo al partido tricolor. Lo acontecido en estos tres sexenios se reconstruye a través de siete ensayos, en los que se presentan las características de los gobiernos panistas y los avances y retrocesos en la entidad durante las administraciones blanquiazules en el ámbito económico y social, en materia de control y trasparencia de la información, así como de su relación con la prensa y con la sociedad civil. La transición política en Jalisco se repitió a escala federal, por lo que la lectura de los textos que conforman esta obra contribuye a entender mejor el complejo fenómeno de la democratización en México.ITESO, A.C

Determining the Role of Fe-Doping on Promoting the Thermochemical Energy Storage Performance of (Mn1-xFex)(3)O-4 Spinels

Mn oxides are promising materials for thermochemical heat store, but slow reoxidation of Mn3O4 to Mn2O3 limits efficiency. In contrast, (Mn1-xFex)(3)O-4 oxides show an enhanced transformation rate, but fundamental understanding of the role played by Fe cations is lacking. Here, nanoscale characterization of Fe-doped Mn oxides is performed to elucidate how Fe incorporation influences solid-state transformations. X-ray diffraction reveals the presence of two distinct spinel phases, cubic jacobsite and tetragonal hausmannite for samples with more than 10% of Fe. Chemical mapping exposes wide variation of Fe content between grains, but an even distribution within crystallites. Due to the similarities of spinels structures, high-resolution scanning transmission electron microscopy cannot discriminate unambiguously between them, but Fe-enriched crystallites likely correspond to jacobsite. In situ X-ray absorption spectroscopy confirms that increasing Fe content up to 20% boosts the reoxidation rate, leading to the transformation of Mn2+ in the spinel phase to Mn3+ in bixbyite. Extended X-ray absorption fine structure shows that Fe-O length is larger than Mn-O, but both electron energy loss spectroscopy and X-ray absorption near edge structure indicate that iron is always present as Fe3+ in octahedral sites. These structural modifications may facilitate ionic diffusion during bixbyite formation.The authors thank the financial support from "Ramon Areces" Foundation (project SOLARKITE), Comunidad de Madrid and European Structural Funds (project ACES2030 P2018/EMT-4319), and University of Cadiz and European Structural Funds (project FEDER-UCA18-107139). A.J.C. thanks the financial support by Juan de la Cierva Formacion Program (MICINN), grant FJCI-2017-33967. The authors acknowledge ALBA-CELLS Synchrotron facility for granting beamtime at CLAESS (experiment 2016021666-2) and Electron Microscopy division located in the Servicios Centrales de Investigacion Cientifica y Tecnologica (SC-ICYT) of the University of Cadiz. Assistance of Dr. Laura Simonelli during the XAS measurements in ALBA is fully appreciated

Prevalencia De Sobrepeso U Obesidad En Escolares De Una Población Urbana Del Estado De Jalisco, México

Introduction. Urban populations in Mexico have not escaped the influence of today's world with an increase in sedentary lifestyles and inadequate food consumption patterns. These conditions have exacerbated the emerging and alarming problem of overweight and obesity in the country. Objective. To diagnose the nutritional status and determine the overweight and obesity prevalence in children between ages of 5 to 14 years of an urban community in the state of Jalisco, Mexico. Material and methods. Through a cross-sectional study, 188 students were evaluated. Weight and height were measured and compared with reference standards of the World Health Organization, the values obtained from the measurement of waist circumference percentiles were compared with the percentile charts made by Fernandez et al, 2004. Results. The combined prevalence of overweight and obesity in the total population was 36.7% (n = 69); in males the prevalence was 20.7% (12.2% for overweight and 8.5% for obesity) and in females was 16% (9.6% and 6.4%, respectively). Children from the fifth and sixth grade had a higher prevalence of both overweight and obesity. Conclusions. Our study shows the current nutritional problems manifested in urban areas, which is accentuated on children with higher increase between the 5th and 6th grades