444 research outputs found

    Wall Street Trading Firms as Securities Insiders

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    The purpose of this article is to examine this view of the Blau case, the implications of the SEC\u27s decision In The Matter of Cady, Roberts and Co. and the possible ramifications of this view and of the Cady, Roberts decision on the future trading activities of investment banking firms

    Community-specific "desired" states for seagrasses through cycles of loss and recovery

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    Seagrass habitats provide critical ecosystem services, yet there is ongoing concern over mounting pressures and continuing degradation. Defining a desired state for these habitats is a key step in implementing appropriate management but is often difficult given the challenges of available data and an evaluation of where to set benchmarks. We use more than 20 years of historical seagrass biomass data (1995–2018) for the diverse seagrass communities of Australia's Great Barrier Reef World Heritage Area (GBRWHA) to develop desired state benchmarks. Desired state for seagrass biomass was estimated for 25 of 36 previously defined seagrass communities with the remainder having insufficient data. Desired state varied by more than one order of magnitude between community types and was influenced by the mix of species in the communities and the range of environmental conditions. We identify a historical, decadal-scale cycle of decline with recovery to desired state in coastal intertidal communities. In contrast a number of the estuary and coastal subtidal communities have not recovered to desired state biomass. Understanding a historical context is critically important for setting benchmarks and making informed management decisions on the present state of seagrass in the GBRWHA. The approach we have developed is scalable for monitoring, management and assessment of pressures for other management areas and for other jurisdictions. Our results guide conservation planning through prioritization of the at-risk seagrass communities that are continuing to fall below their desired state

    On the inadequacy of N-point correlation functions to describe nonlinear cosmological fields: explicit examples and connection to simulations

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    Motivated by recent results on lognormal statistics showing that the moment hierarchy of a lognormal variable completely fails at capturing its information content in the large variance regime, we discuss in this work the inadequacy of the hierarchy of correlation functions to describe a correlated lognormal field, which provides a roughly accurate description of the non-linear cosmological matter density field. We present families of fields having the same hierarchy of correlation functions than the lognormal field at all orders. This explicitly demonstrates the little studied though known fact that the correlation function hierarchy never provides a complete description of a lognormal field, and that it fails to capture information in the non-linear regime, where other simple observables are left totally unconstrained. We discuss why perturbative, Edgeworth-like approaches to statistics in the non-linear regime, common in cosmology, can never reproduce or predict that effect, and why it is however generic for tailed fields, hinting at a breakdown of the perturbation theory based on the field fluctuations. We make a rough but successful quantitative connection to N-body simulations results, that showed that the spectrum of the log-density field carries more information than the spectrum of the field entering the non-linear regime.Comment: 10 pages, 3 figures, matches version accepted for publication by ApJ. Some editing in the conclusion and minor changes w.r.t. v

    Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H2

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    Three structural isomers of tris{bis(trifluoromethyl)phenyl}borane have been studied as the acidic com- ponent of frustrated Lewis pairs. While the 3,5-substituted isomer is already known to heterolytically cleave H2 to generate a bridging-hydride; ortho-substituents in the 2,4- and 2,5-isomers quench such reactivity through electron donation into the vacant boron pz orbital and steric blocking of the boron centre; as shown by electrochemical, structural and computational studies. Electrochemical studies of the corresponding borohydrides identify that the two-electron oxidation of terminal-hydrides occurs at more positive potentials than observed for [HB(C6F5)3]−, while the bridging-hydride oxidizes at a higher poten- tial still, comparable to that of free H2

    Perturbation Theory of the Cosmological Log-Density Field

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    The matter density field exhibits a nearly lognormal probability density distribution (PDF) after entering into the nonlinear regime. Recently, it has been shown that the shape of the power spectrum of a logarithmically transformed density field is very close to the linear density power spectrum, motivating an analytic study of it. In this paper, we develop cosmological perturbation theory for the power spectrum of this field. Our formalism is developed in the context of renormalized perturbation theory, which helps to regulate the convergence behavior of the perturbation series, and of the Taylor- series expansion we use of the logarithmic mapping. This approach allows us to handle the critical issue of density smoothing in a straightforward way. We also compare our perturbative results with simulation measurements.Comment: Minor clarifications to match version accepted in ApJ. 15 pages, 10 figure

    A spatial analysis of seagrass habitat and community diversity in the Great Barrier Reef World Heritage Area

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    The Great Barrier Reef World Heritage Area (GBRWHA) in north eastern Australia spans 2,500 km of coastline and covers an area of ~350,000 km2. It includes one of the world’s largest seagrass resources. To provide a foundation to monitor, establish trends and manage the protection of seagrass meadows in the GBRWHA we quantified potential seagrass community extent using six random forest models that include environmental data and seagrass sampling history. We identified 88,331 km2 of potential seagrass habitat in intertidal and subtidal areas: 1,111 km2 in estuaries, 16,276 km2 in coastal areas, and 70,934 km2 in reef areas. Thirty-six seagrass community types were defined by species assemblages within these habitat types using multivariate regression tree models. We show that the structure, location and distribution of the seagrass communities is the result of complex environmental interactions. These environmental conditions include depth, tidal exposure, latitude, current speed, benthic light, proportion of mud in the sediment, water type, water temperature, salinity, and wind speed. Our analysis will underpin spatial planning, can be used in the design of monitoring programs to represent the diversity of seagrass communities and will facilitate our understanding of environmental risk to these habitats

    Reactivity of Sodium Pentaphospholide Na[cyclo-P5] towards C≡E (E=C, N, P) Triple Bonds

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    A diglyme solution of Na[cyclo-P5] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2 a–c, 4 a,b, and 6. The reaction of Na[cyclo-P5] with alkynes and nitriles was studied by means of DFT methods, which suggested a concerted mechanism for the formation of 2 a and 4 b. The anions 2 a–c, 4 a,b, and 6 coordinate in an η5-fashion towards FeII to give the sandwich (aza)phosphametallocenes 3 a–c, 5 a,b and 7 in moderate to good yields. The new compounds were characterized by means of multinuclear NMR spectroscopy, single-crystal X-ray diffraction and cyclic voltammetry

    Electronics with shape actuation for minimally invasive spinal cord stimulation.

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    Spinal cord stimulation is one of the oldest and most established neuromodulation therapies. However, today, clinicians need to choose between bulky paddle-type devices, requiring invasive surgery under general anesthetic, and percutaneous lead-type devices, which can be implanted via simple needle puncture under local anesthetic but offer clinical drawbacks when compared with paddle devices. By applying photo- and soft lithography fabrication, we have developed a device that features thin, flexible electronics and integrated fluidic channels. This device can be rolled up into the shape of a standard percutaneous needle then implanted on the site of interest before being expanded in situ, unfurling into its paddle-type conformation. The device and implantation procedure have been validated in vitro and on human cadaver models. This device paves the way for shape-changing bioelectronic devices that offer a large footprint for sensing or stimulation but are implanted in patients percutaneously in a minimally invasive fashion

    Gravitational Lensing Simulations I : Covariance Matrices and Halo Catalogues

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    Gravitational lensing surveys have now become large and precise enough that the interpretation of the lensing signal has to take into account an increasing number of theoretical limitations and observational biases. Since the lensing signal is the strongest at small angular scales, only numerical simulations can reproduce faithfully the non-linear dynamics and secondary effects at play. This work is the first of a series in which all gravitational lensing corrections known so far will be implemented in the same set of simulations, using realistic mock catalogues and non-Gaussian statistics. In this first paper, we present the TCS simulation suite and compute basic statistics such as the second and third order convergence and shear correlation functions. These simple tests set the range of validity of our simulations, which are resolving most of the signals at the sub-arc minute level (or 104\ell \sim 10^4). We also compute the non-Gaussian covariance matrix of several statistical estimators, including many that are used in the Canada France Hawaii Telescope Lensing Survey (CFHTLenS). From the same realizations, we construct halo catalogues, computing a series of properties that are required by most galaxy population algorithms. These simulation products are publicly available for download.Comment: 19 pages, 19 figures. This version matches the accepted MNRAS manuscript. It also includes a web address to download the weak lensing simulation product

    Structural basis for cell surface patterning through NetrinG-NGL interactions

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    Brain wiring depends on cells making highly localized and selective connections through surface protein-protein interactions, including those between NetrinGs and NetrinG ligands (NGLs). The NetrinGs are members of the structurally uncharacterized netrin family. We present a comprehensive crystallographic analysis comprising NetrinG1-NGL1 and NetrinG2-NGL2 complexes, unliganded NetrinG2 and NGL3. Cognate NetrinG-NGL interactions depend on three specificity-conferring NetrinG loops, clasped tightly by matching NGL surfaces. We engineered these NGL surfaces to implant custom-made affinities for NetrinG1 and NetrinG2. In a cellular patterning assay, we demonstrate that NetrinG-binding selectivity can direct the sorting of a mixed population of NGLs into discrete cell surface subdomains. These results provide a molecular model for selectivity-based patterning in a neuronal recognition system, dysregulation of which is associated with severe neuropsychological disorders
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