Spectroscopic and redox properties of amine-unctionalized K_2[Os-^(II)(bpy)(CN)_4] complexes

We report the first examples of amine-functionalized K_2[Os^(II)(bpy)(CN)_4] (bpy = 2,2'-bipyridine) complexes. The tetracyanoosmate complexes were prepared by UV irradiation (λ = 254 nm) of K_4[Os^(II)(CN)_6] and primary amine-functionalized bpy ligands in acidic aqueous media. The aqueous solution pH dependences of the spectroscopic and redox properties of 4,4'- and 5,5'-substituted complexes have been investigated. The pendant amine functional groups and coordinated cyanide ligands are basic sites that can be sequentially protonated, thereby allowing systematic tuning of electrochemical and optical spectroscopic properties

Detection of an optical filament in the Monogem Ring

The Monogem Ring is a huge bright soft X-ray enhancement with a diameter of ~ 25\degr. This 0.3 kpc distant structure is a peculiar Galactic supernova remnant in that it is obviously visible only in X-rays, due to its expansion into a region of extremely low ambient density: hence, practically no optical emission or a neutral HI shell was expected to be detectable. - Here we report on the discovery of a very faint arc-like nebula on a POSS II R film copy, at the south-eastern borders of the MR. Spectroscopy revealed this filament to have a very large [SII]$\lambda$ 6716+6731/Halpha ratio of up to ~ 1.8, indicating shock excitation, and a low density of N_e <100 cm^{-3}. There is no hint of [OIII] emission in the spectra. On deep wide-field direct images in Halpha and in [SII] the nebula appears as a ~ 20 arcmin long, thin (~ 1 arcmin), structured filament, stretching N-S. We believe that this filament belongs to the MR and became visible due to the interaction of the expanding remnant with a mild density increase in the interstellar medium. Only one other possible optical filament of the MR has been reported in the literature, but no spectrum was provided.Comment: 6 pages, 4 figures, of which 2 in jpeg format and degraded because of size constraints. Accepted for publication in A&

Effect of nickel on the microstructure and mechanical property of die-cast Al–Mg–Si–Mn alloy

The effect of nickel on the microstructure and mechanical properties of a die-cast Al–Mg–Si–Mn alloy has been investigated. The results show that the presence of Ni in the alloy promotes the formation of Ni-rich intermetallics. These occur consistently during solidification in the die-cast Al–Mg–Si–Mn alloy across different levels of Ni content. The Ni-rich intermetallics exhibit dendritic morphology during the primary solidification and lamellar morphology during the eutectic solidification stage. Ni was found to be always associated with iron forming AlFeMnSiNi intermetallics, and no Al3Ni intermetallic was observed when Ni concentrations were up to 2.06 wt% in the alloy. Although with different morphologies, the Ni-rich intermetallics were identified as the same AlFeMnSiNi phase bearing a typical composition of Al[100–140](Fe,Mn)[2–7]SiNi[4–9]. With increasing Ni content, the spacing of the α-Al–Mg2Si eutectic phase was enlarged in the Al–Mg–Si–Mn alloy. The addition of Ni to the alloy resulted in a slight increase in the yield strength, but a significant decrease in the elongation. The ultimate tensile strength (UTS) increased slightly from 300 to 320 MPa when a small amount (e.g. 0.16 wt%) of Ni was added to the alloy, but further increase of the Ni content resulted in a decrease of the UTS.The Engineering and Physical Sciences Research Council (EPSRC), Technology Strategy Board (TSB) and Jaguar Land Rover (JLR) in the United Kingdom

Towards a Continuous Record of the Sky

It is currently feasible to start a continuous digital record of the entire sky sensitive to any visual magnitude brighter than 15 each night. Such a record could be created with a modest array of small telescopes, which collectively generate no more than a few Gigabytes of data daily. Alternatively, a few small telescopes could continually re-point to scan and reco rd the entire sky down to any visual magnitude brighter than 15 with a recurrence epoch of at most a few weeks, again always generating less than one Gigabyte of data each night. These estimates derive from CCD ability and budgets typical of university research projects. As a prototype, we have developed and are utilizing an inexpensive single-telescope system that obtains optical data from about 1500 square degrees. We discuss the general case of creating and storing data from a both an epochal survey, where a small number of telescopes continually scan the sky, and a continuous survey, composed of a constellation of telescopes dedicated each continually inspect a designated section of the sky. We compute specific limitations of canonical surveys in visible light, and estimate that all-sky continuous visual light surveys could be sensitive to magnitude 20 in a single night by about 2010. Possible scientific returns of continuous and epochal sky surveys include continued monitoring of most known variable stars, establishing case histories for variables of future interest, uncovering new forms of stellar variability, discovering the brightest cases of microlensing, discovering new novae and supernovae, discovering new counterparts to gamma-ray bursts, monitoring known Solar System objects, discovering new Solar System objects, and discovering objects that might strike the Earth.Comment: 38 pages, 9 postscript figures, 2 gif images. Revised and new section added. Accepted to PASP. Source code submitted to ASCL.ne

ACRF Ingest Software Status: New, Current, and Future - February 2007

The purpose of this report is to provide status of the ingest software used to process instrument data for the Atmospheric Radiation Measurement Program Climate Research Facility (ACRF). The report is divided into 4 sections: (1) for news about ingests currently under development, (2) for current production ingests, (3) for future ingest development plans, and (4) for information on retired ingests

A Measurement of the Angular Power Spectrum of the Anisotropy in the Cosmic Microwave Background

We report on a measurement of the angular power spectrum of the anisotropy in the Cosmic Microwave Background. The anisotropy is measured in 23 different multipole bands from l=54 (~3 deg) to l=404 (~0.45 deg) and in 6 frequency bands from 26 GHz to 46 GHz over three observing seasons. The measurements are consistent from year to year. The frequency spectral index of the fluctuations (measured at low l) is consistent with that of the CMB and inconsistent with either dust or Galactic free-free emission. Furthermore, the observations of the MSAM1-92 experiment (Cheng et al. 1994) are repeated and confirmed. The angular spectrum shows a distinct rise from dT_l = \sqrt{l(2l+1)/4pi} = 49(+8,-5) \uK at l=87 to dT_l=85(+10,-8) uK at l = 237. These values do not include an overall +/-14\% (1sigma) calibration uncertainty. The analysis and possible systematic errors are discussed.Comment: latex file is called spect.tex. 25 pages with 11 Postscript figures. Uses aas2pp4.sty (included). Submitted to Ap

A Robotic Wide-Angle H-Alpha Survey of the Southern Sky

We have completed a robotic wide-angle imaging survey of the southern sky (declination less than +15 degrees) at 656.3 nm wavelength, the H-alpha emission line of hydrogen. Each image of the resulting Southern H-Alpha Sky Survey Atlas (SHASSA) covers an area of the sky 13 degrees square at an angular resolution of approximately 0.8 arcminute, and reaches a sensitivity level of 2 rayleigh (1.2 x 10^-17 erg cm^-2 s^-1 arcsec^-2) per pixel, corresponding to an emission measure of 4 cm^-6 pc, and to a brightness temperature for microwave free-free emission of 12 microkelvins at 30 GHz. Smoothing over several pixels allows features as faint as 0.5 rayleigh to be detected.Comment: LATEX, 33 pages, 15 figures. Accepted for publication in PASP, 113, November 2001. Further information at http://amundsen.swarthmore.edu/SHASSA

The WHAM Northern Sky Survey and the Nature of the Warm Ionized Medium in the Galaxy

The Wisconsin H-Alpha Mapper (WHAM) has completed a velocity-resolved map of diffuse H-alpha emission of the entire northern sky, providing the first comprehensive picture of both the distribution and kinematics of diffuse ionized gas in the Galaxy. WHAM continues to advance our understanding of the physical conditions of the warm ionized medium through observations of other optical emission lines throughout the Galactic disk and halo. We discuss some highlights from the survey, including an optical window into the inner Galaxy and the relationship between HI and HII in the diffuse ISM.Comment: 9 pages, 3 figures. To be published in "How does the Galaxy work?", eds. E.J. Alfaro, E. Perez & J. Franco, Kluwer, held 23-27 June 2003 in Granada, Spain. Higher resolution version available at http://www.astro.wisc.edu/~madsen/prof/pubs.htm

Detection of Six Rapidly Scintillating AGNs and the Diminished Variability of J1819+3845

The extreme, intra-hour and > 10% rms flux density scintillation observed in AGNs such as PKS 0405-385, J1819+3845 and PKS 1257-326 at cm wavelengths has been attributed to scattering in highly turbulent, nearby regions in the interstellar medium. Such behavior has been found to be rare. We searched for rapid scintillators among 128 flat spectrum AGNs and analyzed their properties to determine the origin of such rapid and large amplitude radio scintillation. The sources were observed at the VLA at 4.9 and 8.4 GHz simultaneously at two hour intervals over 11 days. We detected six rapid scintillators with characteristic time-scales of 10%. We found strong lines of evidence linking rapid scintillation to the presence of nearby scattering regions, estimated to be < 12 pc away for ~ 200 muas sources and < 250 pc away for ~ 10 muas sources. We attribute the scarcity of rapid and large amplitude scintillators to the requirement of additional constraints, including large source compact fractions. J1819+3845 was found to display ~ 2% rms variations at ~ 6 hour time-scales superposed on longer > 11 day variations, suggesting that the highly turbulent cloud responsible for its extreme scintillation has moved away, with its scintillation now caused by a more distant screen ~ 50 to 150 pc away.Comment: 5 pages, 3 figures, accepted for publication in Astronomy and Astrophysic

The influence of binarity on dust obscuration events in the planetary nebula M 2-29 and its analogues

The central star of the planetary nebula (CSPN) M 2-29 shows an extraordinary R Coronae Borealis-like fading event in its optical lightcurve. The only other CSPN to show these events are CPD-568032 (Hen 3-1333) and V651 Mon (NGC 2346). Dust cloud formation in the line of sight appears responsible but the exact triggering mechanism is not well understood. Understanding how planetary nebulae (PNe) trigger dust obscuration events may help understand the same process in a wide range of objects including Population-I WC9 stars, symbiotic stars and perhaps Asymptotic Giant Branch (AGB) stars with long secondary periods (LSPs). A binary scenario involving an eccentric, wide companion that triggers dust formation via interaction at periastron is a potential explanation that has been suggested for LSP variables. Model fits to the lightcurves of CPD-568032 and M 2-29 show the dust forms in excess of 70 AU at the inner edge of a dust disk. In the case of CPD-568032 this radius is far too large to coincide with a binary companion trigger, although a binary may have been responsible for the formation of the dust disk. We find no direct evidence to support previous claims of binarity in M 2-29 either from the OGLE lightcurve or deep medium-resolution VLT FLAMES spectroscopy of the CSPN. We classify the CSPN as Of(H) with T_eff=50+-10 kK and log g=4.0+-0.3. We find a mean distance of 7.4+-1.8 kpc to M 2-29 at which the M_V=-0.9 mag CSPN could potentially hide a subgiant luminosity or fainter companion. A companion would help explain the multiple similarities with D'-type symbiotic stars whose outer nebulae are thought to be bona-fide PNe. The 7.4 kpc distance, oxygen abundance of 8.3 dex and Galactic coordinates (l=4.0, b=-3.0) prove that M 2-29 is a Galactic Bulge PN and not a Halo PN as commonly misconceived.Comment: 15 pages, 14 figures, 7 tables. Accepted for publication in A\&