Fortress with Sticky Moats: the Functional Role of Small Particles around Tetragonisca angustula Latreille (Apidae: Hymenoptera) Nest Entrance

Many bee species are able to defend themselves against pollen or honey thievery. We herein report the functional role of small sticky particles deposited by Tetragonisca angustula Latreille in its nest entrance external side. This strategy was very effective to prevent ants from invading the bees’ nest. We reported many dead ants attached to the nest entrance and different ant species easily immobilized after being moved onto the entrance tube containing sticky particles. This is the first description of the functional role played by the nest entrance sticky particles under natural conditions.

Systematic study of luminescent properties of new lanthanide complexes using crown ethers as ligand

AbstractThis is a report on the synthesis, characterization and spectroscopic study of 24 lanthanide-crown ether coordination compounds, where Eu(III), Tb(III) and Gd(III) were complexes to 12-crown-4 (12C4), 15-crown-5 (15C5), 1,10-phenanthroline (phen) and 2,2′-dipyridyl (dipy). The compounds were synthesized in an ethanol/acetone solution at room temperature and analyzed using CHN elemental analysis and infrared, absorption and emission spectroscopies. The polarizability that the ligand exerts on the emission process was verified and found remarkable. The Eu-15C5-phen complex showed the highest quantum efficiency (71.6%) because of its low non-radiative rate and highest polarizability with reference to the ligands system

Cassava starch coatings for postharvest control of papaya anthracnose

The effects of coating papaya fruit (Carica papaya) with cassava starch were studied, to determine the best concentration and mode of action of this material in postharvest control of anthracnose. The concentrations of starch tested were 1%, 2%, 3% and 4%. These were prepared to give gel consistency. Surface sterilized papaya fruits were inoculated with conidia of Colletotrichum gloeosporioides and incubated for 48 h in a moisture chamber. The were then treated with cassava fruit gels and dried. During the following 14 d storage period, fruit maturation and anthracnose on the fruits were assessed, and electron microscopy was used to examine fruit epicarps. All cassava starch coating concentrations reduced fruit maturation and anthracnose, with the 2%, 3% or 4% coatings giving 100% disease control. The 2% starch coating is likely to be optimum, considering the lower cost efficiency of disease control. The mechanism of disease control provided by the coating is likely to be related to delay of ripening and the formation of a protective layer over the fruit

Hallucinations in Large Multilingual Translation Models

Large-scale multilingual machine translation systems have demonstrated remarkable ability to translate directly between numerous languages, making them increasingly appealing for real-world applications. However, when deployed in the wild, these models may generate hallucinated translations which have the potential to severely undermine user trust and raise safety concerns. Existing research on hallucinations has primarily focused on small bilingual models trained on high-resource languages, leaving a gap in our understanding of hallucinations in massively multilingual models across diverse translation scenarios. In this work, we fill this gap by conducting a comprehensive analysis on both the M2M family of conventional neural machine translation models and ChatGPT, a general-purpose large language model~(LLM) that can be prompted for translation. Our investigation covers a broad spectrum of conditions, spanning over 100 translation directions across various resource levels and going beyond English-centric language pairs. We provide key insights regarding the prevalence, properties, and mitigation of hallucinations, paving the way towards more responsible and reliable machine translation systems

Radiative Transfer in Prestellar Cores: A Monte Carlo Approach

We use our Monte Carlo radiative transfer code to study non-embedded prestellar cores and cores that are embedded at the centre of a molecular cloud. Our study indicates that the temperature inside embedded cores is lower than in isolated non-embedded cores, and generally less than 12 K, even when the cores are surrounded by an ambient cloud of small visual extinction (Av~5). Our study shows that the best wavelength region to observe embedded cores is between 400 and 500 microns, where the core is quite distinct from the background. We also predict that very sensitive observations (~1-3 MJy/sr) at 170-200 microns can be used to estimate how deeply a core is embedded in its parent molecular cloud. Finally, we present preliminary results of asymmetric models of non-embedded cores.Comment: 8 pages, 15 figures, to appear in the conference proceedings of "Open Issues in Local Star Formation and Early Stellar Evolution", held in Ouro Preto (Brazil), April 5-10, 200

Heptamethine Cyanine-Loaded Nanomaterials for Cancer Immuno-Photothermal/Photodynamic Therapy: A Review

The development of strategies capable of eliminating metastasized cancer cells and preventing tumor recurrence is an exciting and extremely important area of research. In this regard, therapeutic approaches that explore the synergies between nanomaterial-mediated phototherapies and immunostimulants/immune checkpoint inhibitors have been yielding remarkable results in pre-clinical cancer models. These nanomaterials can accumulate in tumors and trigger, after irradiation of the primary tumor with near infrared light, a localized temperature increase and/or reactive oxygen species. These effects caused damage in cancer cells at the primary site and can also (i) relieve tumor hypoxia, (ii) release tumor-associated antigens and danger-associated molecular patterns, and (iii) induced a pro-inflammatory response. Such events will then synergize with the activity of immunostimulants and immune checkpoint inhibitors, paving the way for strong T cell responses against metastasized cancer cells and the creation of immune memory. Among the different nanomaterials aimed for cancer immuno-phototherapy, those incorporating near infrared-absorbing heptamethine cyanines (Indocyanine Green, IR775, IR780, IR797, IR820) have been showing promising results due to their multifunctionality, safety, and straightforward formulation. In this review, combined approaches based on phototherapies mediated by heptamethine cyanine-loaded nanomaterials and immunostimulants/immune checkpoint inhibitor actions are analyzed, focusing on their ability to modulate the action of the different immune system cells, eliminate metastasized cancer cells, and prevent tumor recurrence.info:eu-repo/semantics/publishedVersio

A multi-scale, multi-wavelength source extraction method: getsources

We present a multi-scale, multi-wavelength source extraction algorithm called getsources. Although it has been designed primarily for use in the far-infrared surveys of Galactic star-forming regions with Herschel, the method can be applied to many other astronomical images. Instead of the traditional approach of extracting sources in the observed images, the new method analyzes fine spatial decompositions of original images across a wide range of scales and across all wavebands. It cleans those single-scale images of noise and background, and constructs wavelength-independent single-scale detection images that preserve information in both spatial and wavelength dimensions. Sources are detected in the combined detection images by following the evolution of their segmentation masks across all spatial scales. Measurements of the source properties are done in the original background-subtracted images at each wavelength; the background is estimated by interpolation under the source footprints and overlapping sources are deblended in an iterative procedure. In addition to the main catalog of sources, various catalogs and images are produced that aid scientific exploitation of the extraction results. We illustrate the performance of getsources on Herschel images by extracting sources in sub-fields of the Aquila and Rosette star-forming regions. The source extraction code and validation images with a reference extraction catalog are freely available.Comment: 31 pages, 27 figures, to be published in Astronomy & Astrophysic

Helping WWTP managers to address the volatile methylsiloxanes issue-Behaviour and complete mass balance in a conventional plant

Volatile methylsiloxanes (VMSs) are a group of additives employed in different consumer products that can affect the quality of the biogas produced in wastewater treatment plants (WWTPs). The main objective of this study is to understand the fate of different VMSs along the treatment process of a WWTP located in Aveiro (Portugal). Thus, wastewater, sludge, biogas, and air were sampled in different units for two weeks. Subsequently, these samples were extracted and analyzed by different environment-friendly protocols to obtain their VMS (L3-L5, D3-D6) concentrations and profiles. Finally, considering the different matrix flows at every sampling moment, the mass distribution of VMSs within the plant was estimated. The levels of ∑VMSs were similar to those showed in the literature (0.1-50 μg/L in entry wastewater and 1-100 μg/g dw in primary sludge). However, the entry wastewater profile showed higher variability in D3 concentrations (from non detected to 49 μg/L) than found in previous studies (0.10-1.00 μg/L), likely caused by isolated releases of this compound that could be related to industrial sources. Outdoor air samples showed a prevalence of D5, while indoor air locations were characterized by a predominance of D3 and D4. Differences in sources and the presence of an indoor air filtration system may explain this divergence. Biogas was characterized by ∑VMSs concentrations (8.00 ± 0.22 mg/m3) above the limits recommended by some engine manufacturers and mainly composed of D5 (89%). Overall, 81% of the total incoming mass of VMSs is reduced along the WWTP, being the primary decanter and the secondary treatment responsible for the highest decrease (30.6% and 29.4% of the initial mass, respectively). This reduction, however, is congener dependant. The present study demonstrates the importance of extending sampling periods and matrices (i.e., sludge and air) to improve sample representativity, time-sensitivity, and the accuracy of mass balance exercises.This work was financially supported by: (i) Projects LA/P/0045/2020 (ALiCE – Associated Laboratory in Chemical Engineering) and UIDB/00511/2020 and UIDP/00511/2020 (LEPABE – Laboratory for Process Engineering, Environment, Biotechnology and Energy), funded by national funds through FCT/MCTES (PIDDAC); (ii) Project LANSILOT (PTDC/CTA-AMB/32084/2017; POCI-01–0145-FEDER-032084), funded by FEDER through COMPETE2020—Programa Operacional Competitividade e Internacionalizaçao(POCI) and by national funds (PIDDAC) through FCT/MCTES; (iii) Project “HealthyWaters – Identification, Elimination, Social Awareness and Education of Water Chemical and Biological Micropollutants with Health and Environmental Implications” (NORTE-01-0145-FEDER-000069), co-financed by Programa Operacional Regional do Norte (NORTE 2020), through Portugal 2020 and FEDER; (iv) N. Ratola thanks FCT for the financial support of his work contract through the Scientific Employment Stimulus -Institutional Call - [CEECINST/00049/2018]; (v) G. Pantuzza thanks FCT PhD programme for Grant 2020.07815.BD, supported under the Portugal 2020 Partnership Agreement and European Social Fund (ESF); (vi) V. Homem thanks national funds through FCT, under the Scientific Employment Stimulus—Individual Call - CEECIND/00676/2017. The authors wish to thank the help of the staff at the WWTP in the design of the sampling strategy and the collection of the samples.S

Injecção de Falhas por Varrimento Periférico em Processadores

As técnicas de injecção de falhas mais utilizadas podem ser classificadas em técnicas de indução, técnicas de injecão por hardware e técnicas de injecção por software. Dentro das técnicas de injecção por hardware surgem as técnicas de injecção de falhas recorrendo à tecnologia de teste por varrimento periférico. Esta encontra-se fortemente implantada nos processadores mais recentes, fornecendo um método de acesso ao seu interior de forma a permitir operações de teste e depuração. A sua utilização para a injecção de falhas é um passo lógico e tem sido estudada desde os anos 90. Os trabalhos desenvolvidos nesta área são diversos e incluem soluções que não exigem qualquer alteração à infraestrutura normalizada e soluções que modificam as células e a infraestrutura de controlo de forma a suportarem esta funcionalidade. Estas alterações implicam atrasos temporais acrescidos e um aumento da área de silício destinada a funções de teste, tornando-se importante uma preocupação com a optimização para que a inclusão de capacidades de injecção de falhas não afecte significativamente o desempenho e o custo dos componentes onde são implementadas.info:eu-repo/semantics/publishedVersio

The Pipe Nebula as seen with Herschel: Formation of filamentary structures by large-scale compression ?

A growing body of evidence indicates that the formation of filaments in interstellar clouds is a key component of the star formation process. In this paper, we present new Herschel PACS and SPIRE observations of the B59 and Stem regions in the Pipe Nebula complex, revealing a rich, organized network of filaments. The asymmetric column density profiles observed for several filaments, along with the bow-like edge of B59, indicates that the Pipe Nebula is being compressed from its western side, most likely by the winds from the nearby Sco OB2 association. We suggest that this compressive flow has contributed to the formation of some of the observed filamentary structures. In B59, the only region of the entire Pipe complex showing star formation activity, the same compressive flow has likely enhanced the initial column density of the clump, allowing it to become globally gravitationally unstable. Although more speculative, we propose that gravity has also been responsible for shaping the converging filamentary pattern observed in B59. While the question of the relative impact of large-scale compression and gravity remains open in B59, large-scale compression appears to be a plausible mechanism for the initial formation of filamentary structures in the rest of the complexComment: 9 pages, 9 figures, accepted for publication in A&