Lunar far-side radio arrays: a preliminary site survey

The origin and evolution of structure in the Universe could be studied in the Dark Ages. The highly redshifted H I signal between 30 30 MHz. To observe the low-frequency window with research from compact steep spectrum sources, pulsars, and solar activity, a 200 km baseline lunar far-side radio interferometer has been much discussed. This paper conducts a preliminary site survey of potential far-side craters, which are few in number on the mountainous lunar far-side. Based on LRO LOLA data, 200 m resolution topographic maps of eight far-side sites were produced, and slope and roughness maps were derived from them. A figure of merit was created to determine the optimum site. Three sites are identified as promising. There is a need to protect these sites for astronomy

Catalytic activity towards hydrogen evolution dependent of the degree of conjugation and absorption of six organic chromophores

Conjugated materials can, in many cases, absorb visible light because of their delocalized π electron system. Such materials have been widely used as a photoactive layers in organic photovoltaic devices and as photosensitizers in dye‐sensitized solar cells. Additionally, these materials have been reported for applications in solar fuel production, working as photocatalysts for the hydrogen evolution reaction (HER). The synthesis of three flexible vinyl groups‐containing chromophores is reported. The catalytic activity towards hydrogen evolution of these chromophores has been investigated and compared to their non‐vinyl‐containing analogues. The catalytic effect was confirmed using two different approaches: electrochemical, using the chromophores to modify a working electrode, and photocatalytic, using the chromophores combined with platinum nanoparticles. A relationship between the degree of conjugation and the catalytic activity of the chromophores has been observed with the electrochemical method, while a relationship between the UV absorption in the solid state and the photocatalytic effect with platinum nanoparticles was observed

How Research Data Management Plans Can Help in Harmonizing Open Science and Approaches in the Digital Economy

Within this perspective article, we intend to summarise definitions and terms that are often used in the context of open science and data-driven R&D and we discuss upcoming European regulations concerning data, data sharing and handling. With this background in hand, we take a closer look at the potential connections and permeable interfaces of open science and digital economy, in which data and resulting immaterial goods can become vital pieces as tradeable items. We believe that both science and the digital economy can profit from a seamless transition and foresee that the scientific outcomes of publicly funded research can be better exploited. To close the gap between open science and the digital economy, and to serve for a balancing of the interests of data producers, data consumers, and an economy around services and the public, we introduce the concept of generic research data management plans (RDMs), which have in part been developed through a community effort and which have been evaluated by academic and industry members of the NFDI4Cat consortium. We are of the opinion that in data-driven research, RDMs do need to become a vital element in publicly funded projects

Unusual features of long-range density fluctuations in glass-forming organic liquids : a Rayleigh and Rayleigh-Brillouin light scattering in study

A new feature of glass-forming liquids, i.e., long-range density fluctuations of the order of 100 nm, has been extensively characterized by means of static light scattering, photon correlation spectroscopy and Rayleigh-Brillouin spectroscopy in orthoterphenyl (OTP) and 1,1-di(4'-methoxy-5' methyl-phenyl)-cyclohexane (BMMPC). These long-range density fluctuations result in the following unusual features observed in a light scattering experiment. which are not described by the existing theories: (i) strong q-dependent isotropic excess Rayleigh intensity, (ii) additional slow component in the polarized photon correlation function, and (iii) high Landau-Placzek ratio. These unusual features are equilibrium properties of the glass-forming liquids and depend only on temperature, provided that the sample has been equilibrated long enough. The temperature-dependent equilibration times were measured for BMMPC and are about 11 orders of magnitude longer than the a process. It was found that the glass-forming liquid OTP may occur in two states: with and without long-range density fluctuations (''clusters"). We have characterized the two states by static and dynamic light scattering in the temperature range from T-g to T-g + 200 K. The relaxation times of the a process as well as the parameters of the Brillouin line are identical in both OTP with and without clusters. The a process (density fluctuations) in OTP was characterized by measuring either the polarized (VV) or depolarized (VH) correlation function, which are practically identical and a-independent. This feature, which is commonly observed in glass-forming liquids, is not fully explained by the existing theories

Identifying Overlapping and Hierarchical Thematic Structures in Networks of Scholarly Papers: A Comparison of Three Approaches

We implemented three recently proposed approaches to the identification of overlapping and hierarchical substructures in graphs and applied the corresponding algorithms to a network of 492 information-science papers coupled via their cited sources. The thematic substructures obtained and overlaps produced by the three hierarchical cluster algorithms were compared to a content-based categorisation, which we based on the interpretation of titles and keywords. We defined sets of papers dealing with three topics located on different levels of aggregation: h-index, webometrics, and bibliometrics. We identified these topics with branches in the dendrograms produced by the three cluster algorithms and compared the overlapping topics they detected with one another and with the three pre-defined paper sets. We discuss the advantages and drawbacks of applying the three approaches to paper networks in research fields.Comment: 18 pages, 9 figure

Light-triggered CO release from nanoporous non-wovens

The water insoluble and photoactive CO releasing molecule dimanganese decacarbonyl (CORM-1) has been non-covalently embedded into poly(l-lactide-co-d/ l-lactide) fibers via electrospinning to enable bioavailability and water accessibility of CORM-1. SEM images of the resulting hybrid non-wovens reveal a nanoporous fiber morphology. Slight CO release from the CORM-1 in the electrospinning process induces nanoporosity. IR spectra show the same set of carbonyl bands for the CORM-1 precursor and the non-woven. When the material was exposed to light (365-480 nm), CO release from the incorporated CORM-1 was measured via heterogeneous myoglobin assay, a portable CO electrode and an IR gas cuvette. The CO release rate was wavelength dependent. Irradiation at 365 nm resulted in four times faster release than at 480 nm. 3.4 μmol of CO per mg non-woven can be generated. Mouse fibroblast 3T3 cells were used to show that the hybrid material is non-toxic in the darkness and strongly photocytotoxic when light is applied

Применение тонкослойной хроматографии для индентификации дифенгидрамина гидрохлорида и прокаина гидрохлорида при их совместном присутствии

ТЕХНОЛОГИЯ ФАРМАЦЕВТИЧЕСКАЯДИМЕДРОЛНОВОКАИНХРОМАТОГРАФИЯ ТОНКОСЛОЙНАЯ /ИС