562 research outputs found
Monovalent counterion distributions at highly charged water interfaces: Proton-transfer and Poisson-Boltzmann theory
Surface sensitive synchrotron-X-ray scattering studies reveal the
distributions of monovalent ions next to highly charged interfaces. A lipid
phosphate (dihexadecyl hydrogen-phosphate) was spread as a monolayer at the
air-water interface, containing CsI at various concentrations. Using anomalous
reflectivity off and at the Cs resonance, we provide, for the first
time, spatial counterion distributions (Cs) next to the negatively charged
interface over a wide range of ionic concentrations. We argue that at low salt
concentrations and for pure water the enhanced concentration of hydroniums
HO at the interface leads to proton-transfer back to the phosphate
group by a high contact-potential, whereas high salt concentrations lower the
contact-potential resulting in proton-release and increased surface
charge-density. The experimental ionic distributions are in excellent agreement
with a renormalized-surface-charge Poisson-Boltzmann theory without fitting
parameters or additional assumptions
Surface and interface study of pulsed-laser-deposited off-stoichiometric NiMnSb thin films on Si(100) substrate
We report a detailed study of surface and interface properties of
pulsed-laser deposited NiMnSb films on Si (100) substrate as a function of film
thickness. As the thickness of films is reduced below 35 nm formation of a
porous layer is observed. Porosity in this layer increases with decrease in
NiMnSb film thickness. These morphological changes of the ultra thin films are
reflected in the interesting transport and magnetic properties of these films.
On the other hand, there are no influences of compositional in-homogeneity and
surface/interface roughness on the magnetic and transport properties of the
films.Comment: 13 pages, 7 figures, Submitted to Phys. Rev.
Microstructure formation in electrodeposited Co-Cu/Cu multilayers with GMR effect: influence of current density during the magnetic layer deposition
The influence of the current density applied during the deposition of the magnetic layers on the microstructure formation in electrodeposited Co-Cu/Cu multilayers and on their giant magnetoresistance (GMR) was investigated using a combination of magnetoresistance measurements, wide-angle and small-angle X-ray scattering, high-resolution transmission electron microscopy, atomic force microscopy and chemical analysis. The magnetoresistance measurements revealed that a reduction of the current density stimulates a transition from the formation of the magnetic layers with predominantly ferromagnetic character to the formation of superparamagnetic regions. As based on electrochemical considerations, it was supposed that such a change in the magnetic properties can be caused by an increased amount of Cu codeposited with Co at low current densities. It turned out from the structural studies that a pronounced segregation of Co and Cu occurs at low current densities. In accordance with their very low mutual solubility at room temperature, no atomic scale intermixing of Co and Cu could be detected. The segregation of Cu and Co was related to the fragmentation of the magnetic layers, to the enhancement of the local lattice strains, to the increase of the interface corrugations, to the partial loss of the multilayer periodicity and finally to the formation of Co precipitates in the Cu matrix
Post-traumatic stress disorder following childbirth: an update of current issues and recommendations for future research
Objective:
This paper aimed to report the current status of research in the field of post-traumatic stress disorder following childbirth (PTSD FC), and to update the findings of an earlier 2008 paper.
Background:
A group of international researchers, clinicians and service users met in 2006 to establish the state of clinical and academic knowledge relating to PTSD FC. A paper identified four key areas of research knowledge at that time.
Methods:
Fourteen clinicians and researchers met in Oxford, UK to update the previously published paper relating to PTSD FC. The first part of the meeting focused on updating the four key areas identified previously, and the second part on discussing new and emerging areas of research within the field.
Results:
A number of advances have been made in research within the area of PTSD FC. Prevalence is well established within mothers, several intervention studies have been published, and there is growing interest in new areas: staff and pathways; prevention and early intervention; impact on families and children; special populations; and post-traumatic growth.
Conclusion:
Despite progress, significant gaps remain within the PTSD FC knowledge base. Further research continues to be needed across all areas identified in 2006, and five areas were identified which can be seen as ‘new and emerging’. All of these new areas require further extensive research. Relatively little is still known about PTSD FC
The Ages, Metallicities and Alpha Element Enhancements of Globular Clusters in the Elliptical NGC 5128: A Homogeneous Spectroscopic Study with Gemini/GMOS
We present new integrated light spectroscopy of globular clusters (GCs) in
NGC 5128 in order to measure radial velocities and derive ages, metallicities,
and alpha-element abundance ratios. Using Gemini-S 8-m/GMOS, we obtained
spectroscopy in the range of ~3400-5700 AA for 72 GCs with S/N > 30 /AA and we
have also discovered 35 new GCs within NGC 5128 from our radial velocity
measurements. We measured and compared the Lick indices from HdeltaA through
Fe5406 with the single stellar population (SSP) models of Thomas et
al.(2003,2004). We also measure Lick indices for 41 Milky Way GCs from Puzia et
al. (2002) and Schiavon et al. (2005) with the same methodology for direct
comparison. Our results show that 68% of the NGC 5128 GCs have old ages (> 8
Gyr), 14% have intermediate ages (5-8 Gyr), and 18% have young ages (< 5 Gyr).
However, when we look at the metallicity of the GCs as a function of age, we
find 92% of metal-poor GCs and 56% of metal-rich GCs in NGC 5128 have ages > 8
Gyr, indicating that the majority of both metallicity subpopulations of GCs
formed early, with a significant population of young and metal-rich GCs forming
later. Our metallicity distribution function generated directly from
spectroscopic Lick indices is clearly bimodal, as is the color distribution of
the same set of GCs. Thus the metallicity bimodality is real and not an
artifact of the color to metallicity conversion. The [alpha/Fe] values are
supersolar with a mean value of 0.14pm0.04, indicating a fast formation
timescale. However, the GCs in NGC 5128 are not as [alpha/Fe] enhanced as the
Milky Way GCs also examined in this study. Our results support a rapid, early
formation of the GC system in NGC 5128, with subsequent major accretion and/or
GC and star forming events in more recent times (abridged).Comment: Accepted to The Astrophysical Journal, 36 pages, 14 figures, 7 table
Determination of total x-ray absorption coefficient using non-resonant x-ray emission
An alternative measure of x-ray absorption spectroscopy (XAS) called inverse partial fluorescence yield (IPFY) has recently been developed that is both bulk sensitive and free of saturation effects. Here we show that the angle dependence of IPFY can provide a measure directly proportional to the total x-ray absorption coefficient, µ(E). In contrast, fluorescence yield (FY) and electron yield (EY) spectra are offset and/or distorted from µ(E) by an unknown and difficult to measure amount. Moreover, our measurement can determine µ(E) in absolute units with no free parameters by scaling to µ(E) at the non-resonant emission energy. We demonstrate this technique with measurements on NiO and NdGaO3. Determining µ(E) across edge-steps enables the use of XAS as a non-destructive measure of material composition. In NdGaO3, we also demonstrate the utility of IPFY for insulating samples, where neither EY or FY provide reliable spectra due to sample charging and self-absorption effects, respectively
Asymmetric magnetization reversal in exchange-biased hysteresis loops
This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.Polarized neutron reflectometry is used to probe the in-plane projection of the net-magnetization vector M of polycrystalline Fe films exchange coupled to twinned (110) MnF2 or FeF2 antiferromagnetic (AF) layers. The magnetization reversal mechanism depends upon the orientation of the cooling field with respect to the twinned microstructure of the AF, and whether the applied field is increased to (or decreased from) a positive saturating field; i.e., the magnetization reversal is asymmetric. The reversal of the sample magnetization from one saturated state to the other occurs via either domain wall motion or magnetization rotation on opposite sides of the same hysteresis loop
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