Emergent structural correlations in dense liquids

The complete quantitative description of the structure of dense and supercooled liquids remains a notoriously difficult problem in statistical physics. Most studies to date focus solely on two-body structural correlations, and only a handful of papers have sought to consider additional three-body correlations. Here, we go beyond the state of the art by extracting many-body static structure factors from molecular dynamics simulations and by deriving accurate approximations up to the six-body structure factor via density functional theory. We find that supercooling manifestly increases four-body correlations, akin to the two- and three-body case. However, at small wave numbers, we observe that the four-point structure of a liquid drastically changes upon supercooling, both qualitatively and quantitatively, which is not the case in two-point structural correlations. This indicates that theories of the structure or dynamics of dense liquids should incorporate many-body correlations beyond the two-particle level to fully capture their intricate behavior.</p

Generalized mode-coupling theory for mixtures of Brownian particles

Generalized mode-coupling theory (GMCT) has recently emerged as a promising first-principles theory to study the poorly understood dynamics of glass-forming materials. Formulated as a hierarchical extension of standard mode-coupling theory (MCT), it is able to systematically improve its predictions by including the exact dynamics of higher-order correlation functions into its hierarchy. However, in contrast to Newtonian dynamics, a fully generalized version of the theory based on Brownian dynamics is still lacking. To close this gap, we provide a detailed derivation of GMCT for colloidal mixtures obeying a many-body Smoluchowski equation. We demonstrate that a hierarchy of coupled equations can again be established and show that these, consistent with standard MCT, are identical to the ones obtained from Newtonian GMCT when taking the overdamped limit. Consequently, the nontrivial similarity between Brownian and Newtonian MCT is maintained for our multicomponent GMCT. As a proof of principle, we also solve the generalized mode-coupling equations for the binary Kob-Andersen Lennard-Jones mixture undergoing Brownian dynamics and confirm the improved predictive power of the theory upon using more levels of the GMCT hierarchy of equations. </p

Nuclear dependence coefficient α(A,qT)\alpha(A,q_T) for the Drell-Yan and J/ψ\psi production

Define the nuclear dependence coefficient $\alpha(A,q_T)$ in terms of ratio of transverse momentum spectrum in hadron-nucleus and in hadron-nucleon collisions: $\frac{d\sigma^{hA}}{dq_T^2}/ \frac{d\sigma^{hN}}{dq_T^2}\equiv A^{\alpha(A,q_T)}$. We argue that in small $q_T$ region, the $\alpha(A,q_T)$ for the Drell-Yan and J/$\psi$ production is given by a universal function:\ $a+b q_T^2$, where parameters a and b are completely determined by either calculable quantities or independently measurable physical observables. We demonstrate that this universal function $\alpha(A,q_T)$ is insensitive to the A for normal nuclear targets. For a color deconfined nuclear medium, the $\alpha(A,q_T)$ becomes strongly dependent on the A. We also show that our $\alpha(A,q_T)$ for the Drell-Yan process is naturally linked to perturbatively calculated $\alpha(A,q_T)$ at large $q_T$ without any free parameters, and the $\alpha(A,q_T)$ is consistent with E772 data for all $q_T$.Comment: latex, 28 pages, 10 figures, updated two figures, and add more discussion

Low-lying meson spectrum of large NCN_C strongly coupled lattice QCD

We compute the low energy mass spectrum of lattice QCD in the large $N_C$ limit. Expanding around a gauge-invariant ground state, which spontaneously breaks the discrete chiral symmetry, we derive an improved strong-coupling expansion and evaluate, for any value of $N_C$, the masses of the low-lying states in the unflavored meson spectrum. We then take the 't Hooft limit by rescaling $g^2 N_C\to g^2$; the 't Hooft limit is smooth and no arbitrary parameters are needed. We find, already at the fourth order of the strong coupling perturbation theory, a very good agreement between the results of our lattice computation and the known continuum values.Comment: 43 pages, 1 figure. Minor corrections. One reference added in section

Tri-Bimaximal Mixing from Twisted Friedberg-Lee Symmetry

We investigate the Friedberg-Lee (FL) symmetry and its promotion to include the $\mu - \tau$ symmetry, and call that the twisted FL symmetry.Based on the twisted FL symmetry, two possible schemes are presented toward the realistic neutrino mass spectrum and the tri-bimaximal mixing.In the first scheme, we suggest the semi-uniform translation of the FL symmetry.The second one is based on the $S_3$ permutation family symmetry.The breaking terms, which are twisted FL symmetric, are introduced.Some viable models in each scheme are also presented.Comment: 14 pages, no figure. v2: 16 pages, modified some sentences, appendix added, references added. v3: 14 pages, composition simplified, accepted version in EPJ

Use of the osmotic membrane bioreactor for the management of tannery wastewater using absorption liquid waste as draw solution

[EN] The performance of an osmotic membrane bioreactor (OMBR) for treating tannery wastewater at laboratory scale has been evaluated in this study. The forward osmosis (FO) membrane tested was CTA-NW from HTI. As draw solution, actual waste water from an absorption column for ammonia separation, which consists mainly of ammonium sulphate was used. The study was focused on the salt reverse flux during the OMBR operation, membrane water flux, biomass characteristics and membrane fouling. Regarding membrane water flux change with the time, the measured values diminished from 3.44 to 0.72 LMH due to the membrane fouling and the salt accumulation in the biological reactor. The stable mixed liquor conductivity value at the end of the experiment was 29.8 mS·cm¿1. The chemical oxygen demand (COD) removal efficiencies were maintained near 80% until the first 50 days of operation, considering the soluble COD in the reactor instead of the COD in the membrane permeate for the performance calculation. Thence, COD removal efficiencies decreased progressively due to the accumulation of non degradable COD coming from the tannery wastewater. Concerning to the membrane fouling, FESEM/EDX analysis corroborated that organic fouling was predominant on the membrane active layer.This study was supported by the Spanish Ministry of Economy and Competitiveness through the project RTC-2015-3582-5-AR.Lujan Facundo, MJ.; Mendoza Roca, JA.; Soler Cabezas, JL.; Bes-Piá, M.; Vincent Vela, MC.; Pastor Alcañiz, L. (2019). Use of the osmotic membrane bioreactor for the management of tannery wastewater using absorption liquid waste as draw solution. Process Safety and Environmental Protection. 131:292-299. https://doi.org/10.1016/j.psep.2019.09.024S29229913

Alteration layer formation of Ca- and Zn-oxide bearing alkali borosilicate glasses for immobilisation of UK high level waste: A vapour hydration study

The UK high level nuclear waste glass modified with CaO/ZnO was investigated using the vapour phase hydration test, performed at 200 °C, with the aim of understanding the impact of the modification on the chemical composition and microstructure of the alteration layer. Experiments were undertaken on non-modified and CaO/ZnO-modified base glass, with or without 25 wt% of simulant Magnox waste calcine. The modification resulted in a dramatic reduction in gel layer thickness and also a reduction in the reaction rate, from 3.4 ± 0.3 g m−2 d−1 without CaO/ZnO modification to 0.9 ± 0.1 g m−2 d−1 with CaO/ZnO. The precipitated phase assemblage for the CaO/ZnO-modified compositions was identified as hydrated Ca- and Zn-bearing silicate phases, which were absent from the non-modified counterpart. These results are in agreement with other recent studies showing the beneficial effects of ZnO additions on glass durability

Nuclear effects in the Drell-Yan process at very high energies

We study Drell-Yan (DY) dilepton production in proton(deuterium)-nucleus and in nucleus-nucleus collisions within the light-cone color dipole formalism. This approach is especially suitable for predicting nuclear effects in the DY cross section for heavy ion collisions, as it provides the impact parameter dependence of nuclear shadowing and transverse momentum broadening, quantities that are not available from the standard parton model. For p(D)+A collisions we calculate nuclear shadowing and investigate nuclear modification of the DY transverse momentum distribution at RHIC and LHC for kinematics corresponding to coherence length much longer than the nuclear size. Calculations are performed separately for transversely and longitudinally polarized DY photons, and predictions are presented for the dilepton angular distribution. Furthermore, we calculate nuclear broadening of the mean transverse momentum squared of DY dileptons as function of the nuclear mass number and energy. We also predict nuclear effects for the cross section of the DY process in heavy ion collisions. We found a substantial nuclear shadowing for valence quarks, stronger than for the sea.Comment: 46 pages, 18 figures, title changed and some discussion added, accepted for publication in PR

Geochronological and geochemical constraints on Late Cryogenian to Early Ediacaran magmatic rocks on the northern Tarim Craton:implications for tectonic setting and affinity with Gondwana

The Tarim Craton provides a geologic record of both the fragmentation of the Rodinian supercontinent and the subsequent assembly of Gondwana. However, the timing and interactions of these radically different tectonic processes remain contested. A critical part of this debate revolves around the Late Cryogenian-Ediacaran igneous rocks along the Craton’s northern margin, specifically, whether they record super-plume related Rodinian breakup or Gondwanan orogeny. To address this issue, we present zircon U-Pb-Hf isotopic data and whole rock geochemistry from Late Cryogenian to Early Ediacaran granitoids of the northern Tarim Craton. U-Pb zircon ages reveal three magmatic periods along the northern Tarim margin: ca. 660–640 Ma, 635–625 Ma and 620–600 Ma, associated with small scale felsic and mafic magmas. These granitoids have an A2-type affinity and are enriched in alkalines, but are depleted in Nb, Ta, Sr, P and Ti. Elemental data and generally negative εHf(t) values (−13.96 to 1.65) suggest that they were mainly derived from partial melting of enriched, subduction-modified lithospheric mantle triggered by upwelling of the asthenospheric mantle along the active continental margin of northern Tarim. We suggest that the Tarim Craton travelled as an isolated plate for much of the Late Neoproterozoic, near the outer part of Rodinia and subsequently Gondwana. During this time it was affected by localized and periodic subduction-related intrusion and eruption. However, within the samples of this study, there is no U-Pb-Hf isotopic and whole-rock geochemical evidence to support either super-plume-related rifting (i.e. Rodinian breakup) or Pan-African orogeny (i.e. Gondwanan assembly).</p

Corrosion behaviour of Mg–Zn–Y–Mischmetal alloys in phosphate buffer saline solution

The influence of the processing route and chemical composition in the corrosion behaviour of two Mg-Zn-Y-Mischmetal alloys has been evaluated in phosphate buffer saline solution. The corrosion resistance of the alloy processed by conventional techniques was substantially higher than that found for the same alloy processed from atomised powders. Fine homogeneous distribution of the second-phase particles promoted severe attack due to the enhanced number of galvanic microcells. A higher concentration of zinc and a lower content of rare earth additions improved the corrosion resistance of the alloys due to the lower volume fraction of second-phase particles. © 2012 Elsevier Ltd.Peer Reviewe